HARCROS CHEMICALS INC -- 09178 BAG 50 SODIUM BISULFITE TECH GR
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Material Safety Data Sheet
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MSDS Num: CCFSV
MSDS NAME: 09178 BAG 50 SODIUM BISULFITE TECH GR
Responsible Party
Name: HARCROS CHEMICALS INC
Address: 5200 SPEAKER RD
Box: 2930
City: KANSAS CITY KS 66106-5000
Info Phone: 913-321-3131
Emergency Phone Number: 913-321-3131
Review Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Name: HARCROS CHEMICALS INC.
Address: 5200-SPEAKER ROAD
Box: 2383
City: KANSAS CITY KS 66106-1095
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Contractor Summary
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Name: HARCROS CHEMICALS INC.
Address: 5200-SPEAKER ROAD
Box: 2383
City: KANSAS CITY KS 66106-1095
Phone: 913-321-3131
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Ingredients
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Cas: 7631-90-5
RTECS #: VZ2000000
Name: SODIUM BISULFITE
% Wt: 100
ACGIH TLV: 5 MG/CUM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7681-57-4
RTECS #: UX8225000
Name: SODIUM METABISULFITE, SODIUM METABISULPHITE
ACGIH TLV: 5 MG/CUM
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MILD IRRITATION. SKIN: MILD IRRITATION. INHALATION:
MILD IRRITATION, CNS DEPRESSION, DEATH. INGESTION: MILD IRRITATION, CNS
DEPRESSION.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, NAUSEA, VOMITING, DIARRHEA,
SWELLING, BREATHING DIFFICULTY, UNCONSCIOUSNESS, GIDDINESS, DIZZINESS,
CONFUSION, DRUNKEN BEHAVIOR, HEADACHE, TIREDNESS, DROWSINESS, STUPOR,
CONVULSIONS, COMA.
First Aid: EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
CPR. IF BREATHING IS DIFFICULT GIVE OXYGEN. INGESTION: INDU CE VOMITING
IMMEDITELY BY GIVING TWO GLASSES OF WATER & STICKING FINGER DOWN THROAT.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
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Handling and Disposal
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Spill Release Procedures: SWEEP, SHOVEL/PICK UP & RETURN TO DRY, CLEAN
CONTAINER. FLUSH AREA W/WATER.
Waste Disposal Methods: MATERIAL THAT CAN'T BE USED/CHEMICALLY REPROCESSED
SHOULD BE DISPOSED OF AT AN APPROVED FACILITY. DISPOSE OF IAW/LOCAL, STATE
& FEDERAL REGULATIONS. LOCAL REGULATIONS MAY BE MORE STRINGENT THAN
FEDERA L/STATE.
Handling And Storage Precautions: WEAR PROTECTIVE EQUIPMENT WHEN HANDLING. USE
ONLY W/ADEQUATE VENTILATION. STORE IN A COOL DRY PLACE AWAY FROM
OXIDIZERS.KEEP OUT OF REACH OF CHILDREN.
Other Precautions: KEEP AWAY FROM WATER/ACID. LOOSEN CLOSURES CAREFULLY.
CONTAINER HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINER CONTAINS PRODUCT
RESIDUES ALL LABELED HAZARD PRECAUTIONS MUST BE OBSERVED. KEEP CONTAINE R
CLOSED WHEN NOT IN USE.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures: AVOID EXPOSURE TO FIRE, FUMES, SMOKE & COMBUSTION
PRODUCTS. EVACUATE NON-ESSENTIAL PERSONNEL. WEAR FULL FACE, SCBA &
IMPERVIOUS CLOTHING.
Unusual Fire/Explosion Hazard: DUST CAN BE AN EXPLOSION HAZARD. PREVENT BUILDUP
OF DUST ON WALLS, FLOORS & EQUIPMENT. TOXIC FUMES MAY BE RELEASED.
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Control Measures
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Respiratory Protection: USE A NIOSH/MSHA RESPIRATOR APPROVED FOR YOUR
CONDITIONS OF EXPOSURE.
Ventilation: ADEQUATE: LOCAL MECHANICAL.
Protective Gloves: IMPERVIOUS
Eye Protection: SAFTEY GLASSES W/SIDE SHIELD
Other Protective Equipment: CHEMICAL GOGGLES, CLEAN BODY COVERING CLOTHING,
SAFETY SHOWER, EYE WASH FOUNTAIN, WASHING FACILITIES SHOULD BE AVAILABLE
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: IF USED IMPROPERLY IN THE PRESENCE OF
WATER/UNDER ACIDIC CONDITIONS, CAN RELEASE SULFUR DIOXIDE GAS, WHICH IS TOXIC
& CAN CAUSE DEATH IN POORLY VENTILATED AREAS. MATERIALS TO AVOID:
PERCARBONATES/PERO XIDES/CHROMATES/HYPOCHLORITES/NITRIC ACID/SULFURIC ACID.
DON'T GET IN EYES/SKIN/CLOTHING & DON'T SWALLOW.
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Physical/Chemical Properties
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Spec Gravity: 1.48
PH: 4.3
Solubility in Water: APPRECIABLE
Appearance and Odor: SOLID POWDER, CRYSTAL, FLAKE, GRANULE TABLET,
PRILL/BRIQUETTE W/MILD ODOR
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: BLEACHING AGENTS (OXIDIZERS) INORGANIC ACIDS, CHLORINE,
OXYGEN, PERMANGANATES, PERCHLORATES, PERCARBONATES(SEE SUPP)
Hazardous Decomposition Products: CO, CO2, OXIDES OF SULFUR
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: 09178 BAG 50 SODIUM BISULFITE TECH GR
Company: HARCROS CHEMICALS INC.
Street: 5200-SPEAKER ROAD
PO Box: 2383
City: KANSAS CITY KS
Zipcode: 66106-1095
Health Emergency Phone: 913-321-3131
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: G
Hazard And Precautions: EYES: MILD IRRITATION. SKIN: MILD IRRITATION.
INHALATION: MILD IRRITATION, CNS DEPRESSION, DEATH. INGESTION: MILD
IRRITATION, CNS DEPRESSION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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