LIQUID CARBONIC INDUSTRIES COR -- CARBON DIOXIDE,REFRIGERATED LIQUID
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Material Safety Data Sheet
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NIIN: 00-682-6842
MSDS Num: CCLSQ
MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
Responsible Party
Name: LIQUID CARBONIC INDUSTRIES CORP
Address: 810 JORIE BLVD
City: HINSDALE IL 60521
Info Phone: 708-572-7000
Emergency Phone Number: 504-673-8831/800-424-9300(CHEMTREC)
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LIQUID CARBONIC INDUSTRIES CORP
Address: 810 JORIE BLVD
City: HINSDALE IL 60521-2216
Phone: 708-572-7000
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Item Description Information
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Item Name: CARBON DIOXIDE,TECHNICAL
Specification Number: BB-C-101
Type/Grade/Class: B GRADE
Unit of Issue: LB
UI Container Qty: 0
Type of Container: CYLINDER
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE
% Wt: 99.5+
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 5000 PPM
ACGIH TLV: 5000PPM/30000STEL;96
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: 2-3%CONC SYMPT OF SIMPLE ASPHYXIA OCCUR;3-5% CAUSES INCR
RESP/HEADACHE;UP TO 15% CAUSES HEAD,NAU,VOMIT,UNCONSC.HIGHER CONC CAUSE RAPID
CIRCULATORY INSUFFICIENCY LEADING TO COMA,DEATH.CO2 IS MOST POWER FUL
CEREBERAL VASODILATOR KNOWN.SIN:PROL CONTACT COULD RESULT IN CRYOGENIC
BURN/FROSTBITE.
Explanation Of Carcinogenicity: PER MSDS:CARCINOGENICITY:NTP/IARC/
OSHA:NO.
Signs And Symptions Of Overexposure: SIMPLE ASPHYXIA, INCREASED
RESPIRATORY,HEADACHE, NAUSEA, VOMITING, UNCONSCIOUSNESS. RAPID CIRCULATORY
INSUFFICIENCY LEADING TO COMA AND DEATH. MOST POWERFUL CEREBERAL VASODILATOR.
CYROGENIC SKIN BURN/ FORSTBITE.
Medical Cond Aggravated By Exposure: PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO LIQUID CARBON DIOXIDE SHOULD NOT BE
ALLOWED TO WORK W/OR HANDLE PRODUCT.
First Aid: INHAL:CONSC ASSIST TO UNCONTAMIN AREA/INHAL FRESH AIR.UNCONSC
PROVIDE ASSISTED RESPIRATION/SUPPLEMENTAL OXY.FURTHER TREATMENT SHOULD BE
SYMPTOMATIC/SUPPORTIVE.SELF-CONTAINED BREATHING APPARATUS SHOULD BE
AVAILABLE FOR RESCUE PERSONNEL.SKIN:FROSTBITE-FLUSH AREA W/LUKEWARM WATER.DO
NOT USE HOT WATER.PHYSICIAN SHOULD SEE PATIENT PROMPTLY IF CRYOGENIC BURN HAS
BLISTER/DEEP TISSUE FREEZING.
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Handling and Disposal
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Spill Release Procedures: LIQUID CARBON DIOXIDE WILL NOT SPILL BUT FORMS SNOW
AT PRESSURE BELOW 67PSIG.LEAKS SHOULD BE VENTED TO ATMOSPHER OUTSIDE IN SAFE
AREA.FOLLOW ALL LOCAL, STATE AND FEDERAL REGULATIONS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: NONE SPECIFIED BY MANUFACTURER. :FOLLOW ALL LOCAL,
STATE AND FEDERAL REGULATIONS.CYLINDERS MAY NOT BE REFILLED EXCEPT BY OR
W/CONSENT OF LIQ CARBONIC.
Handling And Storage Precautions: STAIONARY CUSTOMER SITE VESSELS SHOULD BE
OPERATED IAW MFG/SUPPLIER'S INSTRUCTIONS.DO NOT ATTEMPT TO REPAIRN/ADJUST/IN
ANY OTHE RWAY MODIFY OPERATION.
Other Precautions: IF THERE'S MALFUNCTION/OTHER TYPE OF OPERATION PROBLEM
W/VESSEL CONTACT SUPPLIER IMMED.LIQ CYL KEPT IN WELL VENTI AREA,IAW
MFG/SUPPLIER'S INSTRUCTIONS.ALWAYS KEEP UPRIGHT POSITION/FIRMLY SECURED.FOR M
OVEMENT USE SPEC HAND TRUCKS.(SUPPLEMEN)
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Fire and Explosion Hazard Information
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Flash Point Text: NA
Autoignition Temp Text: NA
Lower Limits: NA
Upper Limits: NA
Extinguishing Media: NON-FLAMMABLE GAS. CARBON DIOXIDE IS USED AS AN
EXTINGUISHING MEDIA.
Fire Fighting Procedures: IF CYLINDERS ARE INVOLVED IN FIRE, SAFELY RELOCATE OR
KEEP COOL WITH WATER SPRAY. DO NOT SPRAY WATER DIRECTLY ON SAFETY RELIEF
DEVISES.
Unusual Fire/Explosion Hazard: NONE.
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Control Measures
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Respiratory Protection: IN EVENT OF MAJOR LEAK SELF-CONTAINED BREATHING
APPARATUS MAY BE REQUIRED.
Ventilation: LOCAL EXHAUST/MECHANICAL (GENERAL):TO PREVENT ACCUMULATION ABOVE
TWA,STEL OR PEL.
Protective Gloves: LOOSE FITTING,INSULATED GLOVES.
Eye Protection: SAF GOGG/GLASSES,TRANSP FULL FCSHIELD.
Other Protective Equipment: SAFETY SHOES, PORTABLE CO2 ANALYZER.
Work Hygienic Practices: REFER TO CGA PAMPHLETS/SAF
BULLETINS:P-1,SB-2,G-6,G-6.1,G-6.3.
Supplemental Safety and Health: APPEARANCE:PARTICLES(SNOW)WHEN DISCHARGED FROM
CYL/VESSEL.SUBLIMATION PT:-109.3F. OTHER PRECAUT:PROTECT FROM PHYS DMG.STORE
IN COOL/DRY/WELL VENTI AREA AWAY FROM HEAT SOURCES/DIRECT SUNLIGHT/TEMPS
>12 5F.PREVENT BACKFLOW W/CHECK VALVE/TRAP IN CYL DISCHARGE LINE.CLOSE
VALVE AFT EA USE/WHEN EMTPY.
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Physical/Chemical Properties
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HCC: G3
Vapor Pres: 856PSIG
Vapor Density: 1.65
Spec Gravity: 1.014 @2F
Evaporation Rate & Reference: NA
Solubility in Water: SOLUBLE.
Appearance and Odor: COLOLRLESS GAS W/SLIGHT PUNGENT ODOR.LIQ CONVERTS TO WHITE
CRYSTALLINE (SUPPLEM
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: REACTS W/ALKALINE MATLS TO FORM CARBONATES/BICARBONATES.CAN
BE EXPLO W/REACTIVE METALS(NA,K,MG)/& THEIR HYDRIDES.
Hazardous Decomposition Products: CARBON MONOXIDE AT HIGH TEMPERATURES.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 82201
MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
MSDS Prepared Date: 04/01/1994
Review Date: 01/15/1997
Net Unit Weight: 50LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: LB
Container QTY: 0
Type Of Container: CYLINDER
Additional Data: PER MSDS:DOT UN 2187, 2.2,NON-FLAMM GAS LABEL.
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Detail DOT Information
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DOT PSN Code: CVK
DOT Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
Hazard Class: 2.2
UN ID Num: UN2187
Label: NONFLAMMABLE GAS
Special Provision: B43
Non Bulk Pack: 304
Bulk Pack: 314,315
Max Qty Pass: 50 KG
Max Qty Cargo: 500 KG
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: DOJ
IMO Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
IMDG Page Number: 2111
UN Number: 2187
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-12
MED First Aid Guide NUM: 615
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Detail IATA Information
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IATA PSN Code: FHM
IATA UN ID Num: 2187
IATA Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 202
Max Quant Pass: 50KG
Max Quant Cargo: 500KG
Packaging Note Cargo: 202
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Detail AFI Information
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AFI PSN Code: FHM
AFI Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
AFI PSN Modifier: ,(CRYOGENIC LIQUID)
AFI Hazard Class: 2.2
AFI UN ID NUM: UN2187
Special Provisions: P5
Back Pack Reference: A6.3, A6.11
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
Company: LIQUID CARBONIC INDUSTRIES CORP
Street: 810 JORIE BLVD
City: HINSDALE IL
Zipcode: 60521-2216
Health Emergency Phone: 504-673-8831/800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 01/15/1997
Status Code: C
Label Date: 01/15/1997
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: 2-3%CONC SYMPT OF SIMPLE ASPHYXIA OCCUR;3-5% CAUSES
INCR RESP/HEADACHE;UP TO 15% CAUSES HEAD,NAU,VOMIT,UNCONSC.HIGHER CONC CAUSE
RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA,DEATH.CO2 IS MOST POWER FUL
CEREBERAL VASODILATOR KNOWN.SKIN:PROL CONTACT COULD RESULT IN CRYOGENIC
BURN/FROSTBITE.TARGET ORGANS:RESPIRATORY,BODY TISSUE.1STAID:INHAL:CONSC
ASSIST TO UNCONTAM AREA/INHAL FRESH AIR.UNCONSC PROV IDE ASSISTED
RESP/SUPPLEM OXY.FURTHER TREATMENT-SYMPT/SUPPORT.SCBA AVAILABLE FOR RESCUE
PERSONNEL.SKIN:FROSTBITE-FLUSH AREA W/LUKEWARM WATER.DO NOT USE HOT WATER.DR
SHOULD SEE PATIENT PROMPTLY IF CRYO GENIC BURN HAS BLISTER/DEEP TISSUE
FREEZING.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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