| MSDS | : | UNOCAL UNAX AW 100, 04644 | | CAS | : | 64742-54-7
64742-65-0
64742-56-9
64742-57-0
64742-62-7 | | NAME | : | ing 12:pneumonia) that may progress to pulm fibrosis. symps often are
ing 13:than clinical abnormal. occasnly, persistent cough, irrit of upper
ing 14:exertion, fever, & bloody sputum occur. inhal expos to oil
ing 15:is unlikely to cause pulmonary abnormalities.
spill proc:equip incl resp prot as cndtns warrant. pvnt spilled matl from
ing 17:other unauthorized treatment drainage sys, & natural
waste disp meth:completely drained, properly bunged, & promptly
ing 19:reconditioner. all other cntnrs should be disposed of in envir
ing 20:may be considered rcra haz waste & must be disposed of w/care.
ing 21:may be more restrictive/otherwise different from fed regs. consult
other prec:advised when concs exceed any established expos limits.
ing 23:& may be dangerous. for more information cont nehc (fp n).
vent:or exhaust systems may be required.
oil mist, if generated
mineral oil, petroleum distillates, hydrotreated (severe) heavy
mineral oil, petroleum distillates, solvent-dewaxed heavy paraffinic;
mineral oil, petroleum distillates, solvent-dewaxed light paraffinic
solvent refined hydrotreated residual oil
solvent dewaxed residual oil (petroleum)
supdat:risk. avoid spreading burning liquid w/water used for cooling
first aid proc:develop, move into fresh air. if symps persist, seek med
ing 8:artf resp. if brthg dfcltys develop, oxyg should be admin by
ing 9:if swallowed & symps develop, seek med attn. note to phys:acute
ing 10:prdce serious aspir pneumonia. patients who aspirate these oils
ing 11:long-term sequelae. rptd aspir of sm qtys of mineral oil may prdce
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UNION OIL OF CALIFORNIA -- UNOCAL UNAX AW 100, 04644
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CFLNT
MSDS NAME: UNOCAL UNAX AW 100, 04644
Responsible Party
Name: UNION OIL CO OF CALIFORNIA
Address: 1201 WEST 5TH STREET
City: LOS ANGELES CA 90017
Info Phone: 202-483-7616
Emergency Phone Number: 800-356-3129;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: 76 PRODUCTS CO
Address: 1201 W 5TH ST
City: LOS ANGELES CA 90017
Phone: 213-977-7589
=======================================================
Ingredients
=======================================================
Name: ING 12:PNEUMONIA) THAT MAY PROGRESS TO PULM FIBROSIS. SYMPS OFTEN ARE
SUBTLE & RADIOLOGICAL CHANGES APPEAR WORSE
-----------------------------
Name: ING 13:THAN CLINICAL ABNORMAL. OCCASNLY, PERSISTENT COUGH, IRRIT OF UPPER
RESP TRACT, SHORTNESS OF BREATH WITH
-----------------------------
Name: ING 14:EXERTION, FEVER, & BLOODY SPUTUM OCCUR. INHAL EXPOS TO OIL
MISTS BELOW CURRENT WORKPLACE EXPOSURE LIMITS
-----------------------------
Name: ING 15:IS UNLIKELY TO CAUSE PULMONARY ABNORMALITIES.
-----------------------------
Name: SPILL PROC:EQUIP INCL RESP PROT AS CNDTNS WARRANT. PVNT SPILLED MATL FROM
ENTERING SEWERS, STORM DRAINS,
-----------------------------
Name: ING 17:OTHER UNAUTHORIZED TREATMENT DRAINAGE SYS, & NATURAL
WATERWAYS. FOR MORE SPECIFIC INFO CONT NEHC (FP N).
-----------------------------
Name: WASTE DISP METH:COMPLETELY DRAINED, PROPERLY BUNGED, & PROMPTLY
RETURNED TO SUPPLIER/SHIPPED TO DRUM
-----------------------------
Name: ING 19:RECONDITIONER. ALL OTHER CNTNRS SHOULD BE DISPOSED OF IN ENVIR
SAFE MANNER & I/A/W GOVT REGS. ANY RINSATE
-----------------------------
Name: ING 20:MAY BE CONSIDERED RCRA HAZ WASTE & MUST BE DISPOSED OF W/CARE.
STATE & LOC REQUIREMENTS FOR WASTE DISP
-----------------------------
Name: ING 21:MAY BE MORE RESTRICTIVE/OTHERWISE DIFFERENT FROM FED REGS. CONSULT
STATE & LOC REGS REGARDING PROPER DISP OF MATL
-----------------------------
Name: OTHER PREC:ADVISED WHEN CONCS EXCEED ANY ESTABLISHED EXPOS LIMITS.
"EMPTY" CNTNRS RETAIN RESIDUE (LIQ &/OR VAP)
-----------------------------
Name: ING 23:& MAY BE DANGEROUS. FOR MORE INFORMATION CONT NEHC (FP N).
-----------------------------
Name: VENT:OR EXHAUST SYSTEMS MAY BE REQUIRED.
-----------------------------
Name: OIL MIST, IF GENERATED
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 64742-54-7
RTECS #: PY8035501
Name: MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE) HEAVY
PARAFFINIC
% Wt: 0-99
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 64742-65-0
RTECS #: PY8038501
Name: MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC;
(SEVERE SOLVENT-REFINING AND/OR HYDROTREATMENT)
% Wt: 0-99
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 64742-56-9
RTECS #: PY8039500
Name: MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED LIGHT PARAFFINIC
(SEVERE SOLVENT-REFINING AND/OR HYDROTREATMENT)
% Wt: 0-50
OSHA PEL: 300 PPM
ACGIH TLV: 300 PPM
------------------------------
Cas: 64742-57-0
Name: SOLVENT REFINED HYDROTREATED RESIDUAL OIL
% Wt: 0-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 64742-62-7
Name: SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM)
% Wt: 0-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Name: SUPDAT:RISK. AVOID SPREADING BURNING LIQUID W/WATER USED FOR COOLING
PURPOSES.
-----------------------------
Name: FIRST AID PROC:DEVELOP, MOVE INTO FRESH AIR. IF SYMPS PERSIST, SEEK MED
ATTN. IF VICTIM IS NOT BRTHG, IMMED BEGIN
-----------------------------
Name: ING 8:ARTF RESP. IF BRTHG DFCLTYS DEVELOP, OXYG SHOULD BE ADMIN BY
QUALIFIED PERS. SEEK IMMED MED ATTN. INGEST:
-----------------------------
Name: ING 9:IF SWALLOWED & SYMPS DEVELOP, SEEK MED ATTN. NOTE TO PHYS:ACUTE
ASPIR OF LG AMTS OF OIL-LADEN MATL MAY
-----------------------------
Name: ING 10:PRDCE SERIOUS ASPIR PNEUMONIA. PATIENTS WHO ASPIRATE THESE OILS
SHOULD BE FOLLOWED FOR DEVELOPMENT OF
-----------------------------
Name: ING 11:LONG-TERM SEQUELAE. RPTD ASPIR OF SM QTYS OF MINERAL OIL MAY PRDCE
CHRONIC INFLAMM OF LUNG(I.E. LIPOID
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYE: MAY CAUSE MILD IRRITATION INCLUDING STINGING,
WATERING, & REDNESS. SKIN: MAY CAUSE MILD IRRITATION INCLUDING REDNESS,
BURNING, & DRYING & CRACKING OF SKIN. NO HARMFUL EFTS FROM SKIN
ABSORP TION HAVE BEEN REPORTED. INHAL: NO INFORMATION AVAILABLE. STUDIES BY
OTHER EXPOSURE ROUTES SUGGEST LOW (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: DEGREE OF TOXICITY BY
INHALATION. INGEST: NO HARMFUL EFFECTS REPORTED. SIGNS & SYMPTOMS:
EFFECTS OF OVEREXPOSURE MAY INCLUDE IRRITATION OF NOSE AND THROAT AND
IRRITATION OF DIGESTIVE TRACT. CANCER:INADEQ DATA AVAIL TO EVAL CANCERHAZ OF
MATL. TARGET ORGANS:INADEQ DATA AVAIL FOR THIS MATERIAL.
Medical Cond Aggravated By Exposure: CONDITIONS AGGRAVATED BY EXPOSURE MAY
INCLUDE SKIN DISORDERS.
First Aid: EYE: IF IRRIT/REDNESS DEVELOPS, MOVE VICTIM AWAY FROM EXPOS &
INTO FRESH AIR. FLUSH EYES W/CLEAN WATER FOR @ LST 15 MINS. IF SYMPS PERSIST,
SEEK MED ATTN. SKIN: WIPE MATL FROM SKIN & REMOVE CONTAMD SH OES &
CLTHG. CLEANSE AFFECTED AREA(S) THORO BY WASHING W/MILD SOAP & WATER AND,
IF NEC, WATERLESS SKIN CLEANSER. IF IRRIT/REDNESS DEVELOPS & PERSISTS,
SEEK MED ATTN. INHAL: IF RESP SYMPS
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: MAY IGNITE. KEEP ALL SOURCES OF IGNIT AWAY FROM
SPILL/RELEASE. USE EXPLO-PROOF EQUIP. STAY UPWIND & AWAY FROM
SPILL/RELEASE. ISOLATE DANGER AREA & KEEP UNAUTHORIZED PERS OUT. STOP
SPILL/RELEASE IF CAN BE DONE W/MINIMAL RISK. WEAR APPROP PROT
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: MATL, AS PRDECED, IS NOT EPA "LISTED" HAZ WASTE, BUT
HAS NOT BEEN EVAL USING TOX CHARACT LEACHING PROCEDURE. EPA HAZ WASTE
CLASSIFICATION HAS NOT BEEN DETERM. EMPTY CNTNRS MUST BE HNDLD W/CARE DUE TO
MATL RESIDUE. EMPTY DRUMS SHOULD BE
Handling And Storage Precautions: KEEP CNTNR(S) TIGHTLY CLSD. USE & STORE
MATL IN COOL, DRY, WELL-VENTILATED AREAS AWAY FROM HEAT & ALL SOURCES OF
IGNIT. STORE ONLY IN APPRVD CNTNRS.
Other Precautions: KEEP AWAY FROM ANY INCOMPAT MATL. PROTECT CNTNR(S) AGAINST
PHYSICAL DMG. DO NOT ENTER CONFINED SPACES SUCH AS TANKS/PITS W/OUT FOLLOWING
PROPER ENTRY PROCEDURES SUCH AS ASTM D-4276 & 29CFR 1910.146. U SE OF
NIOSH APPRVD RESP PROT IS
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: COC
Flash Point Text: 442F,228C
Extinguishing Media: DRY CHEM, CO*2, HALON, FOAM/WATER SPRAY IS REC. WATER/FOAM
MAY CAUSE FROTHING OF MATLS HEATED >212F. HALON MAY (SUPDAT)
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
ISOLATE DMG AREA, KEEP UNAUTHORIZED PERS OUT. STOP SPILL/RELEASE IF CAN BE
DONE W/MINIMAL RISK. MOVE (SUPDAT)
Unusual Fire/Explosion Hazard: MATL MAY BURN, BUT WILL NOT IGNITE READILY. VAPS
ARE HVR/AIR & CAN ACCUMULATE IN LOW AREAS. IF CONTAINER IS NOT PROPERLY
COOLED, IT CAN EXPLODE IN HEAT OF FIRE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE OF RESP PROT IS ADVISED WHEN CONCS ARE EXPECTED TO
EXCEED ESTABLISHED EXPOS LIMITS. DEPENDING ON AIRBORNE CONC, USE RESPIRATOR
W/APPROPRIATE CARTRIDGES (NIOSH APPROVED, IF AVAIL) OR SUPPLIED-AIR E
QUIPMENT.
Ventilation: IF CURRENT VENT PRACTICES ARE NOT ADEQ TO MAINTAIN AIRBORNE CONCS
BELOW ESTABLISHED EXPOS LIMITS, ADDNL VENT
Protective Gloves: IMPERMEABLE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: EXTING MEDIA:DECOMPOSE INTO TOX MATLS. CO*2 CAN
DISPLACE OXYG. USE CAUTION WHEN APPLYING HALON/CO*2 IN CONFINED SPACES. FIRE
FIGHT PROC:UNDAMAGED CNTNRS FROM DANGER AREA IF CAN BE DONE W/MINIMAL RISK.
WATER SPRAY MAY BE USEFUL IN MINIMIZING/DISPERSING VAPS. COOL EQUIP EXPOSED
TO FIRE W/WATER, IF DONE W/MINIMAL
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >555F,>291C
Vapor Density: >1
Spec Gravity: 0.88-0.89
Solubility in Water: NEGLIGIBLE
Appearance and Odor: CLEAR BROWN LIQUID, CHARACTERISTIC PETROLEUM ODOR.
Percent Volatiles by Volume: NEGLIG
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXTENDED EXPOSURE TO HIGH TEMPERATURES CAN CAUSE
DECOMPOSITION.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: COMBUST CAN YIELD MAJOR AMTS OF OXIDES OF
CARBON & MINOR AMTS OF OXIDES OF NITROGEN, PHOSPHORUS, SULFUR, AND ZINC.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
=======================================================
MSDS NAME: UNOCAL UNAX AW 100, 04644
Company: 76 PRODUCTS CO
Street: 1201 W 5TH ST
City: LOS ANGELES CA
Zipcode: 90017
Health Emergency Phone: 800-356-3129;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 10/08/1997
Status Code: C
Label Date: 10/08/1997
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: EYE: MAY CAUSE MILD IRRITATION
INCLUDING STINGING, WATERING, & REDNESS. SKIN: MAY CAUSE MILD IRRITATION
INCLUDING REDNESS, BURNING, & DRYING & CRACKING OF SKIN. CHRONIC:
NONE LISTE D BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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