LIQUID CARBONIC INDUSTRIES -- CARBON DIOXIDE, LIQUID
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Material Safety Data Sheet
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MSDS Num: BGWWY
MSDS NAME: CARBON DIOXIDE, LIQUID
Responsible Party
Name: LIQUID CARBONIC INDUSTRIES
Address: 810 JORIE BLVD
City: OAK BROOK IL 60521-2216
Info Phone: 708-572-7500
Emergency Phone Number: 504-673-8831;800-424-9300(CHEMTREC)
Published: Y
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Contractor Summary
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Name: LIQUID CARBONIC CORP
Address: 135 S LA SALLE STREET
City: CHICAGO IL 60603-4101
Phone: 312-855-2500
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE
% Wt: 99.5+
OSHA PEL: 5000 PPM
ACGIH TLV: 5000 PPM; 30000 STEL
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION: AT 2 TO 3% CONCENTRATION, SYMPTOMS OF SIMPLE
ASPHYXIA OCCUR; 3 TO 5% CAUSES INCREASED RESPIRATION & HEADACHE; UP TO
15% CAUSES HEADACHE, NAUSEA, VOMITING & UNCONSCIOUSNESS. HIGHER CONCENTR
ATIONS CAUSE RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA & DEATH.
CARBON DIOXIDE IS THE MOST (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: POWERFUL CEREBRAL VASODILATOR
KNOWN. SKIN: PROLONGED CONTACT W/CARBON DIOXIDE "SNOW" (SOLID) COULD RESULT
IN CRYOGENIC "BURN" OR FROSTBITE. PERSONS IN ILL HEALTH WHERE SUCH ILLNESS
WOULD BE AGGRAVATED BY EXPOSURE TO LIQUID CARBONDIOXIDE SHOULD NOT BE
ALLOWED TO WORK WITH OR HANDLE THIS PRODUCT.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:CALL MD IMMED(FP N). EYES:IMMED FLUSH W/POTABLE WATER FOR AT
LEAST 15 MIN, SEEK ASSISTANCE FROM MD(FP N). INHAL:CONSCIOUS PERS SHOULD BE
ASSISTED TO UNCONTAMD AREA & INHALE FRESH AIR. IF UNCON, PROVIDE
ASSISTED RESPIRATION & SUPPLEMENTAL O*2. FURTHER TREATMENT SHOULD BE
SYMPTOMATIC & SUPPORTIVE. NIOSH/MSHA APPRVD SCBA SHOULD BE AVAIL FOR
RESCUE PERS. SKIN: (FROSTBITE) FLUSH AFFECTED(SUPDAT)
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Handling and Disposal
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Spill Release Procedures: LIQUID CARBON DIOXIDE WILL NOT SPILL, BUT FORMS SOLID
"SNOW" AT PRESSURES BELOW 67 PSIG. LEAKS SHOULD BE VENTED TO THE ATMOSPHERE
"OUTSIDE" IN A SAFE AREA. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULAT IONS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: FOR BULK SYS: CARBON DIOXIDE, REFRIGERATED
LIQ IS DELIVERED TO CUSTOMER INTO STATIONARY, INSULATED VESSELS AT CUSTOMER'S
LOCATION. THESE
Other Precautions: USE ONLY DOT OR ASME CODED CNTNRS. USE PRESS REDUCING
REGULATOR WHEN CONNECTING CYL TO LOWER PRESS PIPING OR SYS. CLOSE VALVE AFTER
EACH USE & WHEN EMPTY. CYLS MAY NOT BE REFILLED EXCEPT BY/WITH CONSE NT
OF LIQ CARBONIC. FOR MORE
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Fire and Explosion Hazard Information
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Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). NONFLAMMABLE
GAS. CARBON DIOIXDE IS USED AS AN EXTINGUISHING MEDIA.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP N).
IF CYLS ARE INVOLVED IN FIRE, SAFELY RELOCATE OR KEEP COOL W/WATER SPRAY. DO
NOT SPRAY WATER DIRECTLY (SUPDAT)
Unusual Fire/Explosion Hazard: NONE.
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Control Measures
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Respiratory Protection: IN EVENT OF MAJOR LEAK, NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED.
Ventilation: LOCAL EXHAUST, MECHANICAL (GENERAL) VENTILATION TO PREVENT
ACCUMULATION ABOVE THE TWA, STEL OR PEL.
Protective Gloves: LOOSE FITTING, INSULATED GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: SAFETY SHOES; PORTABLE CARBON DIOXIDE ANALYZER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: APPEAR/ODOR: PARTICLES (SNOW) WHEN DISCHARGED
FROM CYL/VESSEL. FIRE FIGHT PROC:ON SFTY RELIEF DEVICES. MATLS TO
AVOID:MAGNESIUM) & THEIR HYDRIDES. FIRST AID PROC: AREAS W/LUKEWARM
WATER. DO NOT USE HO T WATER. MD SHOULD SEE PATIENT PROMPTLYIF CRYOGENIC
"BURN" HAS RSLTD IN BLISTERING OF DERMAL SURF/DEEP TISS FREEZING.
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Physical/Chemical Properties
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B.P. Text: N//K
Vapor Pres: 856 PSIA
Vapor Density: 1.65 @ 70F
Spec Gravity: 1.014 @ 2F
Solubility in Water: SOLUBLE
Appearance and Odor: COLORLESS GAS W/SLIGHT PUNGENT ODOR. LIQ CONVERTS TO WHITE
CRYSTALLINE (SUPDAT)
Percent Volatiles by Volume: 100
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Reactivity Data
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Stability Indicator: YES
Materials To Avoid: REACTS W/ALAKLINE MATLS TO FORM CARBONATES & BICARBONATES.
CAN BE EXPLO W/REACTIVE METALS (SODIUM, POTASSIUM, (SUPDAT)
Hazardous Decomposition Products: CARBON MONOXIDE AT HIGH TEMPERATURES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 15480
MSDS NAME: CARBON DIOXIDE, LIQUID
MSDS Prepared Date: 04/01/1994
Review Date: 03/22/1989
Multiple KIT Number: 0
Review IND: Y
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Detail DOT Information
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DOT PSN Code: CVK
DOT Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
Hazard Class: 2.2
UN ID Num: UN2187
Label: NONFLAMMABLE GAS
Special Provision: B43
Non Bulk Pack: 304
Bulk Pack: 314,315
Max Qty Pass: 50 KG
Max Qty Cargo: 500 KG
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: DOJ
IMO Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
IMDG Page Number: 2111
UN Number: 2187
UN Hazard Class: 2(2.2)
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-12
MED First Aid Guide NUM: 615
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Detail IATA Information
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IATA PSN Code: FHM
IATA UN ID Num: 2187
IATA Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
Packing Note Passenger: 202
Max Quant Pass: 50KG
Max Quant Cargo: 500KG
Packaging Note Cargo: 202
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Detail AFI Information
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AFI PSN Code: FHM
AFI Proper Shipping Name: CARBON DIOXIDE, REFRIGERATED LIQUID
AFI PSN Modifier: ,(CRYOGENIC LIQUID)
AFI Hazard Class: 2.2
AFI UN ID NUM: UN2187
Special Provisions: P5
Back Pack Reference: A6.3, A6.11
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE, LIQUID
Company: LIQUID CARBONIC CORP
Street: 135 S LA SALLE STREET
City: CHICAGO IL
Zipcode: 60603-4101
Health Emergency Phone: 504-673-8831;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 08/07/1995
Status Code: C
Label Date: 08/07/1995
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: CAN EXPLODE WITH REACTIVE METALS (SODIUM, POTASSIUM,
ETC). ACUTE: INHALATION: AT 2 TO 3% CONCENTRATION, SYMPTOMS OF SIMPLE
ASPHYXIA OCCUR; 3 TO 5% CAUSES INCREASED RESPIRATION & HEADACHE; UP TO
15% CA USES HEADACHE, NAUSEA, VOMITING & UNCONSCIOUSNESS. HIGHER
CONCENTRATIONS CAUSE RAPID CIRCULATORY INSUFFICIENCY LEADING TO COMA &
DEATH. CARBON DIOXIDE IS THE MOST POWERFUL CEREBRAL VASODILATOR KNOWN. SKIN:
PROLONGED CONTACT WITH CARBON DIOXIDE SOLID COULD RESULT IN CRYOGENIC BURN OR
FROSTBITE. CHRONIC: NONE LISTED BY MANUFACTURER.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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