LIQUID AIR CORP INDUSTRIAL GAS -- CARBON DIOXIDE,REFRIGERATED LIQUID
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Material Safety Data Sheet
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NIIN: 00-245-0199
MSDS Num: BJHTR
MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
Responsible Party
Name: LIQUID AIR CORP INDUSTRIAL GASES DIV
Address: 2121 N CALIFORNIA BLVD SUITE 350
City: WALNUT CREEK CA 94596-5000
Info Phone: 415-977-6500
Emergency Phone Number: 415-977-6500
Review Ind: Y
Published: Y
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Preparer Co. when other than Responsible Party Co.
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Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
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Contractor Summary
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Name: IWECO INC
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Phone: 415-977-6500
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Item Description Information
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Item Name: CARBON DIOXIDE,TECHNICAL
Specification Number: BB-C-101
Type/Grade/Class: B GRADE
Unit of Issue: LB
UI Container Qty: 0
Type of Container: CYLINDER
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Ingredients
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Cas: 124-38-9
RTECS #: FF6400000
Name: CARBON DIOXIDE *96-1*
Other REC Limits: 10000 PPM
OSHA PEL: 5000 PPM
ACGIH TLV: 9000 MG/CUM
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INCREASED EXPOSURE TO CO2 RESULTS IN INCREASED RESPIRATORY
VOLUME. BY REDUCING OXYGEN LEVEL IN AIR, CO2 CAN CAUSE SUFFACATION. NOSE
& THROAT IRRITATION MAY BE CAUSED BY FORMATION OF CARBONIC ACID. HIG H
CONCENTRATION CAN CAUSE PARALYSIS OF BREATHING CONTROL CENTERS OF NERVOUS
SYSTEM. CO2 IS A POWERFUL CEREBRAL (SUPP)
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: COMA, BLISTERING, GRAY/WHITE COLORED SKIN.
INCREASED BREATHING RATE, HEADACHES, DIZZINESS, SHORTNESS OF BREATH, MUSCULAR
WEAKNESS, DROWSINESS, RINGING IN EARS. CARBONIC ACID: IRRITATION, FAINT ACID
TA STE & WATERY EYES.
Medical Cond Aggravated By Exposure: RESPIRATORY DISEASE/HEART DISORDERS.
First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. ASSURE
THAT VOMITED MATERIAL DOESN'T OBSTRUCT AIRWAY BY USE OF POSITIONAL DRAINAGE.
SKIN: FROSTBITE-IMMERSE AFFECTED AREAS IN LUKE-WARM WATE R. DON'T USE HOT
WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
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Handling and Disposal
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Spill Release Procedures: EVACUATE AREA. PROVIDE VENTILATION. WEAR RESPIRATORY
PROTECTION & PROTECTIVE CLOTHING. ALLOW GAS TO BLEED OFF AT A MODERATE
RATE/SOLID TO SUBLIME TO A WELL VENTILATED AREA.
Waste Disposal Methods: DISPOSE OF IAW/FEDERAL,S TATE & LOCAL REGULATIONS.
NONFLAMMABLE GAS UN2187. GAS CYLINDERS SHOULDN'T BE REFILLED EXCEPT BY
QUALIFIED PRODUCERS OF COMPRESSED GASES.
Handling And Storage Precautions: DON'T STORE CYLINDERS IN SUBSURFACE AREAS.
CO2 >AIR & LEAKING GAS COULD ACCUMULATE IN LOW AREAS & CAUSE
SUFFOCATION.
Other Precautions: DON'T ATTEMPT TO REPAIR, ADJUST/IN ANY OTHER WAY MODIFY
OPERATION OF STATIONARY CUSTOMER SITE VESSELS. AVOID BREATHING EXCESSIVE CO2.
AT NORMAL TEMPS, CO2 IS COMPATIBLE W/MOST PLASTICS & ELASTOMERS.
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Fire and Explosion Hazard Information
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Flash Point Text: NONFLAMMABLE
Fire Fighting Procedures: USE WATER SPRAY TO COOL CONTAINERS. MAY BE USED AS A
FIRE EXTINGUISHERS PRIMARILY FOR ITS SMOTHERING EFFECT. INEFFECTIVE FOR FIRES
INVOLVING CHEMICALS (SUPP)
Unusual Fire/Explosion Hazard: CO2 EXTINGUISHERS PRODUCE HIGHLY INCENDIDARY
SPARKS OF 5-15 MJ @ 10-20 KV BY ELECTROSTATIC DISCHARGE.
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Control Measures
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Respiratory Protection: SUPPLIED AIR/SCBA W/FULL FACE MASK OPERATED IN POSITIVE
PRESSURE MODE FOR EMERGENCY SITUATION. FULL FACE-PIECE FOR CONCENTRATIONS
>10%.
Ventilation: LOCAL EXHAUST REQUIRED TO PREVENT ACCUMULATION >TWAS.
Protective Gloves: LOOSE FITTING, INSULATED
Eye Protection: SAFETY GLASSES W/SIDE SHIELDS
Other Protective Equipment: SAFETY GOGGLES, SAFETY TOE SHOES
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Physical/Chemical Properties
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B.P. Text: (SEE SUPP)
M.P/F.P Text: -69.83F
Decomp Text: >3092F
Vapor Pres: 844.7 PSIA
Solubility in Water: SLIGHT
Appearance and Odor: COLORLESS, ODORLESS GAS.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: TEMPS >3092F.
Materials To Avoid: ALKALINE MATERIALS, SODIUM PEROXIDE W/ALUMINUM/MAGNESIUM,
REACTIVE METALS & THEIR HYDRIDES, DRY ICE.
Hazardous Decomposition Products: CO & CO2 WHEN HEATED >3092F. FORMS CARBONIC
ACID IN PRESENCE OF WATER. REACTS W/ALKALINE MATERIALS TO FORM (SEE SUPP)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: IT DOES CAUSE VIOLENT POLYMERIZATION OF
ACRYLADEHYDE/ETHYLENEIMINE.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: CARBON DIOXIDE,REFRIGERATED LIQUID
Company: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Street: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA
Zipcode: 94596
Health Emergency Phone: (800) 231-1366
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: INHALATION: HEADACHE, DIZZINESS, SHORTNESS OF BREATH,
MUSCULAR WEAKNESS, DROWSINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS, RAPID
CIRCULATORY INSUFFICIENCY, COMA/DEATH. SKIN: FROSTBITE/CRYOGENIC FREEZE BU
RNS.
INHALATION: HEADACHE, DIZZINESS, SHORTNESS OF BREATH, MUSCULAR
WEAKNESS, DROWSINESS, NAUSEA, VOMITING, UNCONSCIOUSNE SS, RAPID CIRCULATORY
INSUFFICIENCY, COMA/DEATH. SKIN: FROSTBITE, CRYOGENIC FREEZE, BURNS,
BLISTERING OF THE DERMAL SURFACE OR DEEP TISSUE FREEZING.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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