2-propenoic acid, 2-cyano-, ethyl ester; (ethyl cyanoacrylate) polymethylmethacrylate; (poly (methyl methacrylate)) hydroquinone (sara 302/313) (cercla) first aid proc:should be treated normally after lump of cyanoacrylate is ing 5:should never be nec to use such drastic meth as surgery to separate ing 6:that eyelids are stuck together/bonded to eyeball, wash thoro ing 7:patch. eye will open w/out further action, typically in 1-4 days. ing 8:to open eyes by manipulation. cyanoacrylate introduced into eyes ing 9:disassociate from it over intermittent periods, generally covering ing 10:weeping until clearance is achieved. ingest:if lips are ing 11:water to lips & encourage max wetting & press from saliva ing 12:to pull lips w/direct opposing action. it is almost imposs to ing 13:& adheres in mouth. saliva will lift adhesive in one half to ing 14:position patient to pvnt ingest of lump when it detaches. ing 15:cyanoacrylates are handled best by passive nonsurgical first aid.
LOCTITE CORP -- PRISM 401 SURF-INSENSITIVE INST-ADH, 40140
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGBMQ
MSDS NAME: PRISM 401 SURF-INSENSITIVE INST-ADH, 40140
Responsible Party
Name: LOCTITE CORP
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Info Phone: 860-571-5100
Emergency Phone Number: 860-571-5100
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORP
Address: 705 N MT RD
City: NEWINGTON CT 06111
Phone: 312-689-6200
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
Name: 2-PROPENOIC ACID, 2-CYANO-, ETHYL ESTER; (ETHYL CYANOACRYLATE)
% Wt: 90-95
Other REC Limits: 2 PPM (MFR)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY (METHYL METHACRYLATE))
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA 302/313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Name: FIRST AID PROC:SHOULD BE TREATED NORMALLY AFTER LUMP OF CYANOACRYLATE IS
RELS FROM TISS AS DESCRIBED. NOTE:IT
-----------------------------
Name: ING 5:SHOULD NEVER BE NEC TO USE SUCH DRASTIC METH AS SURGERY TO SEPARATE
ACCIDENTALLY BONDED SKIN. EYES:IN EVENT
-----------------------------
Name: ING 6:THAT EYELIDS ARE STUCK TOGETHER/BONDED TO EYEBALL, WASH THORO
W/WARM WATER FOR AT LST 15 MINS & APPLY GAUZE
-----------------------------
Name: ING 7:PATCH. EYE WILL OPEN W/OUT FURTHER ACTION, TYPICALLY IN 1-4 DAYS.
THERE WILL BE NO RESIDUAL DMG. DO NOT TRY
-----------------------------
Name: ING 8:TO OPEN EYES BY MANIPULATION. CYANOACRYLATE INTRODUCED INTO EYES
WILL ATTACH ITSELF TO EYE PROTEIN & WILL
-----------------------------
Name: ING 9:DISASSOCIATE FROM IT OVER INTERMITTENT PERIODS, GENERALLY COVERING
SEVERAL HRS. THIS WILL CAUSE PERIODS OF
-----------------------------
Name: ING 10:WEEPING UNTIL CLEARANCE IS ACHIEVED. INGEST:IF LIPS ARE
ACCIDENTALLY STUCK TOGETHER, APPLY LOTS OF WARM
-----------------------------
Name: ING 11:WATER TO LIPS & ENCOURAGE MAX WETTING & PRESS FROM SALIVA
INSIDE MOUTH. PEEL/ROLL LIPS APART. DO NOT TRY
-----------------------------
Name: ING 12:TO PULL LIPS W/DIRECT OPPOSING ACTION. IT IS ALMOST IMPOSS TO
SWALLOW CYANOACRYLATE. ADHESIVE SOLIDIFIES
-----------------------------
Name: ING 13:& ADHERES IN MOUTH. SALIVA WILL LIFT ADHESIVE IN ONE HALF TO
TWO DAYS. IN CASE LUMP FORMS IN MOUTH,
-----------------------------
Name: ING 14:POSITION PATIENT TO PVNT INGEST OF LUMP WHEN IT DETACHES.
NOTE:EXPER HAS SHOWN THAT ACCIDENTS DUE TO
-----------------------------
Name: ING 15:CYANOACRYLATES ARE HANDLED BEST BY PASSIVE NONSURGICAL FIRST AID.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50:(ORAL) >5000 MG/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN CONT MAY CAUSE BURNS. BONDS SKIN RAPIDLY &
STRONGLY. SKIN & EYE IRRIT. VAP IS IRRIT TO EYES & MUC MEMBS ABOVE
TLV. PRLNG & RPTD OVEREXP TO VAPS MAY PRDCE SYMPS OF NON-ALLERGIC ASTHMA
IN SENSITIVE INDIVIDUALS. CYANOACRYLATE ADHESIVE ISVERY FAST SETTING &
STRONG ADHESIVE. IT BONDS HUMAN TISS INCL (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:SKIN IN SECS. CURED ADHESIVE DOES
NOT PRESENT HLTH HAZ EVEN WHEN BONDED TO SKIN. ADHESIVE ON EYEBALL:DURING
PERIOD OF CONTAM, DOUBLE VISION MAY BE EXPER TOGETHER W/LACHRYMATORY EFT
& IT IS IM PORTANT TO UNDERSTAND CAUSE & REALIZE THAT DISASSOCIATION
WILL NORMALLY OCCUR W/IN MATTER OF HRS, EVEN W/GROSS (SUPDAT)
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHAL:REMOVE TO FRESH AIR. IF SYMPS PERSIST, OBTAIN MED ATTN.
SKIN:CONT-REMOVE EXCESS ADHESIVE. SOAK IN WARM, SOAPY WATER. ADHESIVE WILL
COME LOOSE IN SEVERAL HRS. ADHESION-FIRST IMMERSE BONDED SURFS IN WARM,
SOAPY WATER. PEEL/ROLL SURFS APART W/AID OF BLUNT EDGE, E.G., SPATULA/TSP
HANDLE; THEN REMOVE ADHESIVE W/SOAP & WATER. DO NOT TRY TO PULL SURFS
APART W/DIRECT OPPOSING ACTION. BURNS-
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD W/WATER TO POLYMERIZE. SOAK UP W/INERT
ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). POLYMERIZE AS IN SPILL PROCEDURES. INCINERATE FOLLOWING
EPA & LOCAL REGULATIONS. NOT A RCRA HAZARDOUS WASTE MATERIAL.
Handling And Storage Precautions: STORE <75F. (CONT LOCTITE CUSTOMER SERVICE
1-800-243-4874 FOR SHELF LIFE INFO). AVOID CONT W/SKIN & EYES. AVOID
BRTHG VAPOR. COMBUSTIBLE LIQUID.
Other Precautions: AVOID CONTACT W/CLOTHES, FABRICS, RAGS OR TISSUE. CONTACT
W/THESE MATLS MAY CAUSE POLYMERIZATION. POLYMERIZATION OF LARGE AMOUNTS OF
ADHESIVE WILL GENERATE HEAT CAUSING SMOKE, SKIN BURNS & STRONG, IRR
ITATING VAPORS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF
CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE OR POLYETHYLENE GLOVES.
Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER (FP
N). WEAR NITRILE/POLYETHYLENE APRON WHEN HNDLG LG AMTS OF ADHESIVE.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EFTS OF OVEREXP:CONTAM. CYANOACRYLATES GIVE OFF
HEAT ON SOLIDIFICATION. IN RARE CASES LG DROP WILL INCR IN TEMP ENOUGH TO
CAUSE BURN. TARGET ORG & OTHER HLTH EFTS:ETHYL CYANOACRYLATE:ALLERGEN,
IRRIT, RESP. POLY (METHYL METHACRYLATE):IRRIT.HYDROQUINONE:BLOOD, BONE
MARROW, CNS, EYE, IMMUNE SYS, IRRIT, MUTAGEN, SKIN.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2
Vapor Density: 3
Spec Gravity: 1.05
VOC Grams/Liter: 714
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: WATER WHITE TO STRAW COLORED LIQUID; SHARP, IRRITATING
ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY CONTACT W/WATER, ALCOHOLS, AMINES, ALKALIES.
Hazardous Decomposition Products: IRRITATING ORGANIC FRAGMENTS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOLATILE ORGANIC COMPOUNDS (EPA METHOD 24): 68%; 714 G/L.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PRISM 401 SURF-INSENSITIVE INST-ADH, 40140
Company: LOCTITE CORP
Street: 705 N MT RD
City: NEWINGTON CT
Zipcode: 06111
Health Emergency Phone: 860-571-5100
Label Required IND: Y
Date Of Label Review: 01/07/1998
Status Code: C
Label Date: 01/07/1998
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: ACUTE:SKIN:MAY CAUSE BURNS. SKIN AND EYE IRRITANT.
VAPOR IS IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE TLV. PROLONGED AND
REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE SYMPTOMS OF NON-ALLERGIC ASTHMA
IN SENSITIVE INDIVIDUALS. BONDS HUMAN TISSUE INCLUDING SKIN IN SECONDS. MAY
CAUSE DOUBLE VISION, LACHRYMATORY EFFECT IF ENTERS EYE. CHRONIC:NONE LISTED
BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.