2-propenoic acid, 2-cyano-, ethyl ester; (ethyl cyanoacrylate) polymethylmethacrylate; (poly (methyl methacrylate)) hydroquinone (sara 302/313) (cercla) supp data: avoid cont w/clothes, fabrics, rags/tiss. cont w/matls may ing 5: will gen heat causing smoke, skin burns, & strong, irrit vaps. ing 6: when hndlg lrg amts of adhesive. skin adhesion: first immerse ing 7:surfs apart w/aid of blunt edge, e.g. spatula/teaspoon hndl; then ing 8: do not try to pull surf apart with direct opposing action. burns: ing 9: solidification. in rare cases lrg drop will incr in temp enough to ing 10: normally after lump of cyanoacrylate is rels from tiss as ing 11:use such drastic meth to separate accidentally bonded skin. eye: ing 12:to eyelid/eyeball adhesion: in event that eyelids are stuck ing 13: water & apply gauze patch. eye will open w/out further ing 14: residual dmg. do not try to open eyes by manipulation. adhesive ing 15: into eyes will attach itself to eye protein & will ing 16: generally covering several hrs. will cause periods of weeping ing 17: of contam, double vision may be experienced together ing 18: cause & realize that disassociation will normally occur
LOCTITE CORP -- PRISM 401 SURF-INSENSITIVE INST ADH, 40161
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGBMR
MSDS NAME: PRISM 401 SURF-INSENSITIVE INST ADH, 40161
Responsible Party
Name: LOCTITE CORP
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Info Phone: 860-571-5100
Emergency Phone Number: 860-571-5100
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORP
Address: 705 N MT RD
City: NEWINGTON CT 06111
Phone: 312-689-6200
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
RTECS #: UD3330000
Name: 2-PROPENOIC ACID, 2-CYANO-, ETHYL ESTER; (ETHYL CYANOACRYLATE)
% Wt: 90-95
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY (METHYL METHACRYLATE))
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA 302/313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Name: SUPP DATA: AVOID CONT W/CLOTHES, FABRICS, RAGS/TISS. CONT W/MATLS MAY
CAUSE POLYM. POLYM OF LRG AMTS OF AHESIVE
-----------------------------
Name: ING 5: WILL GEN HEAT CAUSING SMOKE, SKIN BURNS, & STRONG, IRRIT VAPS.
WEAR NITRILE/POLYETHYLENE GLOVES & APRON
-----------------------------
Name: ING 6: WHEN HNDLG LRG AMTS OF ADHESIVE. SKIN ADHESION: FIRST IMMERSE
BONDED SURFS IN WARM, SOAPY WATER. PEEL/ROLL
-----------------------------
Name: ING 7:SURFS APART W/AID OF BLUNT EDGE, E.G. SPATULA/TEASPOON HNDL; THEN
REMOVE ADHESIVE FROM SKIN W/SOAP & WATER.
-----------------------------
Name: ING 8: DO NOT TRY TO PULL SURF APART WITH DIRECT OPPOSING ACTION. BURNS:
CYANOACRYLATES GIVE OFF HEAT ON
-----------------------------
Name: ING 9: SOLIDIFICATION. IN RARE CASES LRG DROP WILL INCR IN TEMP ENOUGH TO
CAUSE BURN. BURNS SHOULD BE TREATED
-----------------------------
Name: ING 10: NORMALLY AFTER LUMP OF CYANOACRYLATE IS RELS FROM TISS AS
DESCRIBED. SURGERY: IT SHOULD NEVER BE NEC TO
-----------------------------
Name: ING 11:USE SUCH DRASTIC METH TO SEPARATE ACCIDENTALLY BONDED SKIN. EYE:
FLUSH W/WATER FOR AT LST 15 MINS. EYELID
-----------------------------
Name: ING 12:TO EYELID/EYEBALL ADHESION: IN EVENT THAT EYELIDS ARE STUCK
TOGETHER/BONDED TO EYEBALL, WASH THORO W/WARM
-----------------------------
Name: ING 13: WATER & APPLY GAUZE PATCH. EYE WILL OPEN W/OUT FURTHER
ACTION, TYPICALLY IN 1-4 DAYS. THERE WILL BE NO
-----------------------------
Name: ING 14: RESIDUAL DMG. DO NOT TRY TO OPEN EYES BY MANIPULATION. ADHESIVE
ON EYEBALL: CYANOACRYLATE INTRODUCED
-----------------------------
Name: ING 15: INTO EYES WILL ATTACH ITSELF TO EYE PROTEIN & WILL
DISASSOCIATE FROM IT OVER INTERMITTENT PERIODS,
-----------------------------
Name: ING 16: GENERALLY COVERING SEVERAL HRS. WILL CAUSE PERIODS OF WEEPING
UNTIL CLEARANCE IS ACHIEVED. DURING PERIOD
-----------------------------
Name: ING 17: OF CONTAM, DOUBLE VISION MAY BE EXPERIENCED TOGETHER
W/LACHRYMATORY EFT, & IT IS IMPORTANT TO UNDERSTAND
-----------------------------
Name: ING 18: CAUSE & REALIZE THAT DISASSOCIATION WILL NORMALLY OCCUR
WITHIN MATTER OF HRS, EVEN WITH GROSS CONTAMINATION.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY AND
STRONGLY. SKIN AND EYE IRRITANT. VAPOR IS IRRITATING TO EYES AND MUCOUS
MEMBRANES ABOVE TLV. PROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY PROD
UCE SYMPTOMS OF NON-ALLERGIC ASTHMA IN SENSITIVE INDIVIDUALS.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INGEST: INGEST IS NOT LIKELY. IF LIPS ARE ACCIDENTALLY STUCK
TOGETHER, APPLY LOTS OF WARM WATER TO LIPS & ENCOURAGE MAX WETTING &
PRESS FROM SALIVA INSIDE MOUTH. PEEL/ROLL LIPS APART. DO NOT TRY TO PU LL
LIPS W/DIRECT OPPOSING ACTION. IT ISALMOST IMPOSSIBLE TO SWALLOW
CYANOACRYLATE. ADHESIVE SOLIDIFIES & ADHERES IN MOUTH. SALIVA WILL LIFT
ADHESIVE IN ONE HALF-2 DAYS. IN CASE LUMP FORMS (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE. SOAK UP WITH AN INERT
ABSORBENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE FOLLOWING EPA, FEDERAL, STATE, AND LOCAL
REGULATIONS.
Handling And Storage Precautions: STORE BELOW 75F. AVOID CONTACT WITH SKIN AND
EYES. AVOID BREATHING VAPOR.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE/POLYETHYLENE GLOVES. DO (SUPDAT)
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
NITRILE OR POLYETHYLENE APRONS. DO NOT USE COTTON.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: PROT GLOVES: NOT USE COTTON. FIRST AID PROC: IN
MOUTH, POSITION PATIENT TO PVNT INGEST OF LUMP WHEN IT DETACHES. INHAL:
REMOVE TO FRESH AIR. IF SYMPS PERSIST, OBTAIN MED ATTN. SKIN: SOAK IN WARM
WATER . REMOVE EXCESS ADHESIVE. SOAK IN WARM SOAPY WATER. ADHESIVE DOES NOT
PRESENT HLTH HAZ EVEN WHEN BONDED TO SKIN.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2
Vapor Density: APPROX 3
Spec Gravity: 1.05
VOC Grams/Liter: 714
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: WATER WHITE TO STRAW COLORED LIQUID. SHARP IRRITATING
ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES,
ALKALIES.
Hazardous Decomposition Products: IRRITATING ORGANIC FRAGMENTS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOLATILE ORGANIC COMPOUNDS (EPA METHOD 24): 68%; 714 G/L.
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PRISM 401 SURF-INSENSITIVE INST ADH, 40161
Company: LOCTITE CORP
Street: 705 N MT RD
City: NEWINGTON CT
Zipcode: 06111
Health Emergency Phone: 860-571-5100
Label Required IND: Y
Date Of Label Review: 01/20/1998
Status Code: C
Label Date: 01/20/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE. AVOID WATER. ACUTE: SKIN CONTACT MAY CAUSE
BURNS. BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE IRRITANT. VAPOR IS
IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE TLV. CHRONIC: PROLONGED AN D
REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE SYMPTOMS OF NON-ALLERGIC ASTHMA
IN SENSITIVE INDIVIDUALS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.