LABCHEM INC -- NITRIC ACID SOLUTIONS, LC17870
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Material Safety Data Sheet
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MSDS Num: CGDBZ
MSDS NAME: NITRIC ACID SOLUTIONS, LC17870
Responsible Party
Name: LABCHEM INC
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Info Phone: 412-826-5230
Emergency Phone Number: 412-826-5230
Preparer's Name: AL BERANEK
Published: Y
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Contractor Summary
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Name: LABCHEM INC
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Phone: 412-826-5230
Name: LABCHEM, INC.
Address: 200 WILLIAM PITT WAY
City: PITTSBURGH PA 15238
Phone: 412-826-5230
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Ingredients
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Cas: 7697-37-2
RTECS #: QU5775000
Name: NITRIC ACID (SARA 302/313) (CERCLA)
% Wt: <50
OSHA PEL: 2 PPM
ACGIH TLV: 2 PPM/4 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: BALANCE
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: SUP DAT: OTHER ORG/INORG ACIDS, FLUORINES, CHLORINES, KETONES & MANY
OTHER ORG/CYCLIC CMPDS, HALIDES, ALDEHYDES, ETC.
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Name: EFTS OF OVEREXP: CHRONIC: DERM, CONJUNCTIVITIS, DENTAL EROSION, CHRONIC
COUGH, BRONCH, CHEM PNEUMIT, GI DISTURBANCES.
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Name: FIRST AID PROC: LIDS OCCAS UNTIL CHEM IS GONE (15-20 MIN). APPLY LOOSE
STERILE NON-MEDICATED BANDAGES OVER BURNS.
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Name: ING 5: GET MED AID IMMED. INGEST: GIVE CONSCIOUS VICTIM LGE QTYS OF WATER
TO DILUTE ACID. DO NOT INDUCE VOMIT.
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Name: ING 6: GIVE 1 OZ (30 ML) MILD OF MAGNESIA. GET MEDICAL AID AT ONCE.
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Name: EYE PROTECTION: AND FULL LENGTH FACESHIELD (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TOXICITY: SEV EYE, MUC MEMB, & SKIN IRRIT. ACUTE:
INHAL: COUGHING, DIZZ, WEAK, DRY THROAT/CHEST, CHEST PAIN, DYSPNEA, FROTHY
SPUTUM, HYPOTENSION, CYANOSIS, PNEUMIT, FATAL PULM EDEMA. PERM SCAR TISS MA Y
FORM, SKIN: YELLOWISH BROWN STAINS, PENETRATING BURNS. EYES: PAIN,
PHOTOPHOBIA, TEARING, EDEMA, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: CORNEAL ULCERATION, SEV BURNS,
NECROSIS OF DEEP TISS W/PERM DMG & BLINDNESS. INGEST: PAIN IN MOUTH,
THROAT, STOM FOLLOWED BY VOMIT, BLOODY DIARR, HYPOTENSION, OLIGURIA, ANURIA,
POSS FATAL CI RCULATORY COLLAPSE, ASPHYXIA FROM GLOTTAL EDEMA. PERFORATION
BURNS OF GI TRACT POSS W/FEVER & PERITONITIS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: MOVE TO FRESH AIR. GIVE ARTF RESP IF NEC. MAINTAIN AIRWAY
& BLOOD PRESS. MED PERS MAY GIVE OXYGEN. KEEP WARM, AT REST. GET MED AID
IMMED. SKIN: IMMED REMOVE CONTAM CLTHG & WASH AFFECTED AREA W/ SOAP &
WATER, FLUSHING UNTIL CHEM IS GONE (15-20 MIN). COVER BURNS W/DRY STERILE
DRESSING (SECURE, NOT TIGHT). GET MED AID IMMED. EYES: FLUSH IMMED W/LGE AMTS
OF WATER, LIFTING UPPER/LOWER
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Handling and Disposal
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Spill Release Procedures: VENTILATE AND WEAR PROTECTIVE CLOTHING. NEUTRALIZE
WITH SODA ASH OR USE SUITABLE INERT ABSORBENT. SCOOP INTO SUITABLE (PLASTIC)
DISPOSAL CONTAINERS, LABEL "CORROSIVE". KEEP OUT OF SEWERS, WATER SOURCE S.
Neutralizing Agent: SODA ASH.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: STORE AT ROOM TEMPERATURE, PROTECT FROM HEAT,
INCOMPATIBLES. STORE IN GLASS OR APPROVED PLASTIC CONTAINERS ONLY, KEEP
CAPPED.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
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Fire and Explosion Hazard Information
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Flash Point Text: NON-FLAMMABLE
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). AVOID BREATHING TOXIC AND CORROSIVE VAPORS. MOVE CONTAINER
IF POSSIBLE, COOL WITH WATER.
Unusual Fire/Explosion Hazard: NEGLIG FIRE/EXPLO HAZ FOR SOLNS <5%. AT
HIGHER CONCS, INCRD FLAMMABILITY OF COMBUSTS, READILY OXIDIZABLE MATLS. SEV
EXPLO HAZ BY RXN W/INCOMPATIBLES (SUP DAT)
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED RESPIRATORS FOR EXPOSURE OF CONCERN
(FP N). DO NOT USE OXIDIZABLE SORBENTS IN RESPIRATORS.
Ventilation: PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION TO MEET PEL.
Protective Gloves: IMPERVIOUS GLOVES (VITON, SARANEX).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGG
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: DO NOT WEAR CONTACT LENSES WHEN WORKING WITH
CHEMICALS.
Supplemental Safety and Health: EXPLO HAZ: (METALLIC POWDERS, CARBIDES,
HYDROGEN SULFIDE, TURPENTINE). IN/NEAR FIRE MATL EMITS TOX & REACTIVE
NITROGEN OXIDES OF GASES. MATLS TO AVOID: OTHER ANHYDRIDES, ACRYLONITRILES,
ALCOHOLS, ARSI NE, VARIOUS METALS (EASILY POWDERS, ALLOYS), PERCHLORATES,
CARBIDES, PHOSPHIDES, DIOXIDES, THIOCYANATES,
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Physical/Chemical Properties
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B.P. Text: >181F,>83C
M.P/F.P Text: >-44F,>-42C
Vapor Pres: 14-62@25C
Vapor Density: 0.7-2.2
Spec Gravity: 1.0-1.5
Evaporation Rate & Reference: >1 (ETHER=1)
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR, COLORLESS LIQUID; ACRID ODOR
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID ACID VAPORS. NITRIC OXIDES QUIETLY
EVOLVED-SUNLIGHT CATALYSES OXIDE FORMATION (YELLOW COLOR, AGING).
Materials To Avoid: EASILY OXIDIZED SUBSTANCES. VIOLENT/EXPLO RXN CAN OCCUR
W/ACETONITRILE, ACETONE, ACETIC ACID, ACETIC ANHYDRIDE,(SUP DAT)
Hazardous Decomposition Products: NITRIC ACID VAPORS AND NITRIC OXIDES ARE
QUIETLY EVOLVED - THIS REACTION IS CATALYZED BY SUNLIGHT.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: NITRIC ACID SOLUTIONS, LC17870
Assigned IND: Y
Company: LABCHEM INC
Street: 200 WILLIAM PITT WAY
City: PITTSBURGH PA
Zipcode: 15238
Health Emergency Phone: 412-826-5230
Label Required IND: Y
Date Of Label Review: 01/28/1998
Status Code: C
Label Date: 01/28/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TOXICITY: SEV EYE, MUC MEMB, & SKIN IRRIT. ACUTE:
INHAL: COUGHING, DIZZ, WEAK, DRY THROAT/CHEST, CHEST PAIN, DYSPNEA, FROTHY
SPUTUM, HYPOTENSION, CYANOSIS, PNEUMIT, FATAL PULM EDEMA. PERM SCAR TISS MA Y
FORM, SKIN: YELLOWISH BROWN STAINS, PENETRATING BURNS. EYES: PAIN,
PHOTOPHOBIA, TEARING, EDEMA, CORNEAL ULCERATION, SEV BURNS, NECROSIS OF DEEP
TISS W/PERM DMG & BLINDNESS. INGEST: PAIN, VOMIT, BLOO DY DIARR,
HYPOTENSION, OLIGURIA, ANURIA, POSS FATAL CIRCULATORY COLLAPSE, ASPHYXIA.
PERFORATION BURNS OF GI TRACT POSS W/FEVER & PERITONITIS. CHRONIC: DERM,
CONJUNCTIVITIS, DENTAL EROSION, CHRONIC COU GH, BRONCHITIS, CHEM PNEUMIT, GI
DISTURBANCES.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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