WITHSTAND LATEX FLOOR ENAMEL BASE 1, Z 5191 040992 A
CAS
:
107-21-1 13463-67-7 1317-95-9 14808-60-7
NAME
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ethylene glycol (sara 313) (cercla). vp:1 @ 20c. lel:3%. uel:15%. titanium oxide; (titanium dioxide) silica, crystalline - tripoli silica, crystalline - quartz; (silica, crystalline) volatile organic compounds: less water & nprs - 2.04 lbs/gal (245 supdat:w/rats revealed significant incr in benign & malignant lung ing 6:tio2 dust. at lower expos levels, this significant eft was not ing 7:lungs may have been overwhelmed of 250 mg/m3 expos level & this ing 8:rslts may not be directly relevant to workplace where occup expos ing 9:concludes that there is no significant hazard for man. first aid proc:md:the principal tox efts of ethylene glycol, when ing 11:acidosis. ethanol is antidotal, & its early admin may block ing 12:glycol in liver. ethanol should be given intravenously, as 5% soln ing 13:about 10 ml ethanol per hr. a desired therapeutic level of ethanol ing 14:may be reqd. pulm edema w/hypoxemia has been described in a number ing 15:glycol. the mechanism of production has not been determined, but ing 16:origin in several cases. niosh approved resp support w/mech vent
PRATT & LAMBERT -- WITHSTAND LATEX FLOOR ENAMEL BASE 1, Z 5191 0
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Material Safety Data Sheet
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MSDS Num: CGFYP
MSDS NAME: WITHSTAND LATEX FLOOR ENAMEL BASE 1, Z 5191 040992 A
Responsible Party
Name: PRATT & LAMBERT
Box: 22
City: BUFFALO NY 14240
Info Phone: 718-873-8000
Emergency Phone Number: 718-873-8000
Published: Y
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Contractor Summary
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Name: PRATT & LAMBERT
Address: UNKNOWN
City: BUFFALO NY 14240
Phone: 716-873-6000
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Ingredients
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Cas: 107-21-1
RTECS #: KW2975000
Name: ETHYLENE GLYCOL (SARA 313) (CERCLA). VP:1 @ 20C. LEL:3%. UEL:15%.
% Wt: 5
OSHA PEL: 50 PPM (MFR)
ACGIH TLV: 50 PPM, VAPOR, C
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 20
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
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Cas: 1317-95-9
RTECS #: VV7336000
Name: SILICA, CRYSTALLINE - TRIPOLI
% Wt: 5
OSHA PEL: 0.1 MG/M3 (MFR)
ACGIH TLV: 0.1 MG/M3 RDUST
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Cas: 14808-60-7
RTECS #: VV7330000
Name: SILICA, CRYSTALLINE - QUARTZ; (SILICA, CRYSTALLINE)
% Wt: <1
OSHA PEL: 0.1 MG/M3 (MFR)
ACGIH TLV: 0.1 MG/M3 RDUST
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RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: LESS WATER & NPRS - 2.04 LBS/GAL (245
G/L); SOLIDS - 2.67 LBS/GAL (320 G/L).
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Name: SUPDAT:W/RATS REVEALED SIGNIFICANT INCR IN BENIGN & MALIGNANT LUNG
TUMORS IN GRP EXPOS TO 250 MG/M3 RESPIRABLE
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Name: ING 6:TIO2 DUST. AT LOWER EXPOS LEVELS, THIS SIGNIFICANT EFT WAS NOT
OBSERVED. NORMAL CLEARANCE MECHANISMS OF THE
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Name: ING 7:LUNGS MAY HAVE BEEN OVERWHELMED OF 250 MG/M3 EXPOS LEVEL & THIS
MAY HAVE CONTRIBUTED TO TUMOR FORM. THESE
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Name: ING 8:RSLTS MAY NOT BE DIRECTLY RELEVANT TO WORKPLACE WHERE OCCUP EXPOS
LIMS ARE OBSERVED. AT TLV, THE TIO2 MFR
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Name: ING 9:CONCLUDES THAT THERE IS NO SIGNIFICANT HAZARD FOR MAN.
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Name: FIRST AID PROC:MD:THE PRINCIPAL TOX EFTS OF ETHYLENE GLYCOL, WHEN
SWALLOWED, ARE KIDNEY DMG & METABOLIC
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Name: ING 11:ACIDOSIS. ETHANOL IS ANTIDOTAL, & ITS EARLY ADMIN MAY BLOCK
FORM OF NEPHROTOXIC METABOLITES OF ETHYLENE
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Name: ING 12:GLYCOL IN LIVER. ETHANOL SHOULD BE GIVEN INTRAVENOUSLY, AS 5% SOLN
IN SODIUM BICARBONATE, AT RATE OF
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Name: ING 13:ABOUT 10 ML ETHANOL PER HR. A DESIRED THERAPEUTIC LEVEL OF ETHANOL
IN BLOOD IS 100 MG/DL. HEMODIALYSIS
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Name: ING 14:MAY BE REQD. PULM EDEMA W/HYPOXEMIA HAS BEEN DESCRIBED IN A NUMBER
OF PATIENTS FOLLOWING POIS W/ETHYLENE
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Name: ING 15:GLYCOL. THE MECHANISM OF PRODUCTION HAS NOT BEEN DETERMINED, BUT
IT APPEARS TO BE NON-CARDIOGENIC IN
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Name: ING 16:ORIGIN IN SEVERAL CASES. NIOSH APPROVED RESP SUPPORT W/MECH VENT
& POS END-EXPIRATORY PRESSURE MAY BE REQUIRED.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:INGEST:SWALLOWING OF ETHYLENE GLYCOL MAY CAUSE ABDOM
DISCOMFORT/PAIN, DIZZ, MALAISE, LUMBAR PAIN, OILGURIA, UREMIA & CNS
DEPRESS. SEV KIDNEY DMG FOLLOWS SWALLOWING OF LG VOLS OF ETHYLENE GLYCOL.
MAY BE FATAL. INHAL:MAY CAUSE RESP IRRIT. EYE:MAY CAUSE IRRIT. SKIN:MAY CAUSE
DEFAT & IRRIT. CHRONIC: (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-TRIPOLI & QUARTZ:IARC
MONOGRAPHS, VOL 68, 1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ:RPTD & PRLNG OCCUP OVEREXP TO
CRYSTALLINE SILICA MAY CAUSE SILICOSIS, A PROGRESSIVELY DISABLING LUNG
DISEASE. ETHYLENE GLYCOL HAS BEEN SHOWN TO PRDCE DOSE-RELATED BIRTH DEFECTS
IN RATS & MICE WHEN GIVEN BY MOUTH AT HIGH CONCS. BECAUSE THERE IS NO
CURRENTLY AVAIL INFO TO SUGGEST THAT ETHYLENE GLYCOL (SUPP DATA)
Medical Cond Aggravated By Exposure: PREEXISTING RESPIRATORY CONDITIONS MAY BE
AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
First Aid: INGEST:IMMED GIVE 1-2 GLASSES OF WATER & CALL POIS CTL CTR,
HOSPITAL EMER ROOM/MD FOR WAY TO INDUCE VOMIT. (NEVER GIVE ANYTHING BY MOUTH
TO UNCON PERS). INHAL:REMOVE TO FRESH AIR. EYES:FLUSH W/LG AMTS OF WATER,
LIFTING UPPER & LOWER LIDS OCCAS. CONTINUE FOR AT LST 15 MINS. GET MED
ATTN. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/SOAP & WATER. OBTAIN
MED ATTN IF IRRIT PERSISTS. NOTES TO
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Handling and Disposal
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Spill Release Procedures: CONFINE IN SMALL AREA; USE ABSORBENT TO CLEAN UP.
PLACE IN CONTAINER FOR DISPOSAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE I/A/W FEDERAL, STATE & LOCAL LAWS. AS
PRODUCED, THIS PRODUCT IS NOT A WASTE. IF DISCARDED AS IS, IT IS NOT
CLASSIFIED A HAZARDOUS WASTE UNDER RCRA.
Handling And Storage Precautions: PROTECT FROM FREEZING OR EXTREMELY HIGH
TEMPERATURES. DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH USE. KEEP
AWAY FROM CHILDREN.
Other Precautions: DO NOT BREATHE SANDING DUST.
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Fire and Explosion Hazard Information
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Lower Limits: SEE ING 1
Upper Limits: SEE ING 1
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). WILL NOT BURN.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
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Control Measures
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Respiratory Protection: IF APPLIED BY SPRAYING, USE AN APPROPRIATE, PROPERLY
FITTED NIOSH APPROVED RESPIRATOR TO REMOVE SPRAY MIST. REFER TO OSHA 29 CFR
1910.134 "RESPIRATORY PROTECTION".
Ventilation: PROVIDE LOC EXHST VENT IN SUFFICIENT VOL & PATTERN SO AS TO
MAINTAIN EXPOS BELOW NUISANCE DUST LIMS & PELS WHICH(SUPDAT)
Protective Gloves: IMPERMEABLE GLOVES (NEOPRENE).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). NOT LIKELY TO BE NEEDED.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLAN OF CARCIN:ANTIC TO BE CARCIN. TARGET
ORGS:LUNGS. VENT:MAY BE LISTED IN INGS SECTION, REFER TO "INDUS VENT-A MANUAL
FOR REC PRACTICE" - ACGIH. EYE PROT:FULL LGTH FSHLD (FP N). EFTS OF
OVEREXP:CA USES BIRTH DEFECTS IN HUMANS, IT IS CONSIDERED AN ANIMAL
TERATOGEN. DRY TITANIUM DIOXIDE IN 24-MONTH INHAL STUDY
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Physical/Chemical Properties
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B.P. Text: >-28F,>-33C
Vapor Pres: SEE ING 1
Vapor Density: HVR/AIR
Spec Gravity: 1.3
Evaporation Rate & Reference: SLOWER THAN DIETHYL ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 68
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: BURNING, INCLUDING WHEN HEATED BY
WELDING/CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: WITHSTAND LATEX FLOOR ENAMEL BASE 1, Z 5191 040992 A
Company: PRATT & LAMBERT
Street: UNKNOWN
City: BUFFALO NY
Zipcode: 14240
Health Emergency Phone: 718-873-8000
Label Required IND: Y
Date Of Label Review: 08/19/1997
Status Code: C
Label Date: 08/19/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INGESTION:SWALLOWING OF ETHYLENE GLYCOL MAY CAUSE
ABDOMINAL DISCOMFORT OR PAIN, DIZZINESS, MALAISE, LUMBAR PAIN, OILGURIA,
UREMIA AND CENTRAL NERVOUS SYSTEM DEPRESSION. SEVERE KIDNEY DAMAGE FOLL OWS
SWALLOWING OF LARGE VOLUMES OF ETHYLENE GLYCOL. MAY BE FATAL. INHALATION:MAY
CAUSE RESPIRATORY IRRITATION. EYE:MAY CAUSE IRRITATION. SKIN:MAY CAUSE
DEFATTING AND IRRITATION. CHRONIC:CANCER HAZARD. CONTAINS CRYSTALLINE
SILICA-QUARTZ AND TRIPOLI WHICH ARE LISTED AS HUMAN LUNG CARCINOGENS (FP N).
ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
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of Defense or other government situation.