ing 12:may be susceptible to hydrogen embrittlement from h*2s. compressed ing 13:by qualified producers of compressed gases. shipment of compressed ing 14:owner/with his (written) consent is violation of federal law ing 15:position before transporting them. never transport cyls in trunks ing 16:or in passenger compartments. transport cyls secured in open vent:in air to less than 18 molar percent. ing 7:must remain in place unless cntnr is secured w/valve outlet piped hydrogen sulfide with (sara 302/313) (cercla). bp:-76f,-60c. vp:267 ing 1:sol in h*2o:soluble nitrogen. bp:-320f,-195c. vp:above critical temperature of -232.51f ing 3:sol in h*2o:relatively insoluble. supdat:assistance should be sought immediately. waste disp meth:for emergency disposal, contact the closest liquid air other prec:full cyls being stored for excess periods of time. use only in msds toxicity property">
ing 9:lower press (<3,000 psig) piping/sys. do not heat cyl by any ing 10:cyl. do not tamper with (valve) sfty device. close valve after ing 11:rapidly if expos to hydrogen sulfide in "wet" atm. also avoid ing 12:may be susceptible to hydrogen embrittlement from h*2s. compressed ing 13:by qualified producers of compressed gases. shipment of compressed ing 14:owner/with his (written) consent is violation of federal law ing 15:position before transporting them. never transport cyls in trunks ing 16:or in passenger compartments. transport cyls secured in open vent:in air to less than 18 molar percent. ing 7:must remain in place unless cntnr is secured w/valve outlet piped hydrogen sulfide with (sara 302/313) (cercla). bp:-76f,-60c. vp:267 ing 1:sol in h*2o:soluble nitrogen. bp:-320f,-195c. vp:above critical temperature of -232.51f ing 3:sol in h*2o:relatively insoluble. supdat:assistance should be sought immediately. waste disp meth:for emergency disposal, contact the closest liquid air other prec:full cyls being stored for excess periods of time. use only in msds toxicity property">
MSDS
:
10-100 PPM HYDROGEN SULFIDE IN NITROGEN
CAS
:
7783-06-4 7727-37-9
NAME
:
ing 8:roll cyls. use suitable hand truck for cyl movement. use press ing 9:lower press (<3,000 psig) piping/sys. do not heat cyl by any ing 10:cyl. do not tamper with (valve) sfty device. close valve after ing 11:rapidly if expos to hydrogen sulfide in "wet" atm. also avoid ing 12:may be susceptible to hydrogen embrittlement from h*2s. compressed ing 13:by qualified producers of compressed gases. shipment of compressed ing 14:owner/with his (written) consent is violation of federal law ing 15:position before transporting them. never transport cyls in trunks ing 16:or in passenger compartments. transport cyls secured in open vent:in air to less than 18 molar percent. ing 7:must remain in place unless cntnr is secured w/valve outlet piped hydrogen sulfide with (sara 302/313) (cercla). bp:-76f,-60c. vp:267 ing 1:sol in h*2o:soluble nitrogen. bp:-320f,-195c. vp:above critical temperature of -232.51f ing 3:sol in h*2o:relatively insoluble. supdat:assistance should be sought immediately. waste disp meth:for emergency disposal, contact the closest liquid air other prec:full cyls being stored for excess periods of time. use only in
LIQUID AIR CORP -- 10-100 PPM HYDROGEN SULFIDE IN NITROGEN
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGFRT
MSDS NAME: 10-100 PPM HYDROGEN SULFIDE IN NITROGEN
Responsible Party
Name: LIQUID AIR CORP
Address: 2121 N CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Info Phone: 415-977-6500
Emergency Phone Number: 800-231-366;800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA 94596
Phone: 415-977-6500
=======================================================
Ingredients
=======================================================
Name: ING 8:ROLL CYLS. USE SUITABLE HAND TRUCK FOR CYL MOVEMENT. USE PRESS
REDUCING REGULATOR WHEN CONNECTING CYL TO
-----------------------------
Name: ING 9:LOWER PRESS (<3,000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY
MEANS TO INCR DISCHARGE RATE OF PROD FROM
-----------------------------
Name: ING 10:CYL. DO NOT TAMPER WITH (VALVE) SFTY DEVICE. CLOSE VALVE AFTER
EACH USE & WHEN EMPTY. MANY METALS CORRODE
-----------------------------
Name: ING 11:RAPIDLY IF EXPOS TO HYDROGEN SULFIDE IN "WET" ATM. ALSO AVOID
USING HARD/HIGHLY STRESSED STEELS WHICH
-----------------------------
Name: ING 12:MAY BE SUSCEPTIBLE TO HYDROGEN EMBRITTLEMENT FROM H*2S. COMPRESSED
GAS CYLS SHOULD NOT BE REFILLED EXCEPT
-----------------------------
Name: ING 13:BY QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENT OF COMPRESSED
GAS CYL WHICH HAS NOT BEEN FILLED BY
-----------------------------
Name: ING 14:OWNER/WITH HIS (WRITTEN) CONSENT IS VIOLATION OF FEDERAL LAW
(49CFR). ALWAYS SECURE CYLS IN UPRIGHT
-----------------------------
Name: ING 15:POSITION BEFORE TRANSPORTING THEM. NEVER TRANSPORT CYLS IN TRUNKS
OF VEHICLES, ENCLOSED VANS, TRUCK CABS
-----------------------------
Name: ING 16:OR IN PASSENGER COMPARTMENTS. TRANSPORT CYLS SECURED IN OPEN
FLATBED/IN OPEN PICK-UP VEHICLES.
-----------------------------
Name: VENT:IN AIR TO LESS THAN 18 MOLAR PERCENT.
-----------------------------
Name: ING 7:MUST REMAIN IN PLACE UNLESS CNTNR IS SECURED W/VALVE OUTLET PIPED
TO USE POINT. DO NOT DRAG, SLIDE, DROP/
-----------------------------
Cas: 7783-06-4
RTECS #: MX1225000
Name: HYDROGEN SULFIDE WITH (SARA 302/313) (CERCLA). BP:-76F,-60C. VP:267
PSIA. MP:-117F,-83C.
OSHA PEL: C, 20 PPM
ACGIH TLV: 10 PPM/15 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Name: ING 1:SOL IN H*2O:SOLUBLE
-----------------------------
Cas: 7727-37-9
RTECS #: QW9700000
Name: NITROGEN. BP:-320F,-195C. VP:ABOVE CRITICAL TEMPERATURE OF -232.51F
(-146.95C) @ 70F. MP:-346F,-210C.
OSHA PEL: N/K (FP N)
ACGIH TLV: ASPHYXIANT
------------------------------
Name: ING 3:SOL IN H*2O:RELATIVELY INSOLUBLE.
-----------------------------
Name: SUPDAT:ASSISTANCE SHOULD BE SOUGHT IMMEDIATELY.
-----------------------------
Name: WASTE DISP METH:FOR EMERGENCY DISPOSAL, CONTACT THE CLOSEST LIQUID AIR
CORPORATION LOCATION.
-----------------------------
Name: OTHER PREC:FULL CYLS BEING STORED FOR EXCESS PERIODS OF TIME. USE ONLY IN
WELL-VENTILATED AREAS. VALVE PROT CAPS
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHAL OF THESE MIXTURES FOR SHORT PERIODS OF TIME
SHOULD NOT CAUSE IRREVERSIBLE EFTS. (OSHA IDLH FOR H*2S=300 MOLAR PPM).
CONTINUOUS EXPOS TO THESE MIX, PARTICULARLY HIGHER CONCS, SHOULD CAUSE I RRIT
TO MUC MEMB & CONJUCTIVAE OF EYES.IT COULD ALSO CAUSE HDCH, DIZZ/NAUS.
SHARP PUNGENT ODOR OF H*2S(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:IN NITROGEN SHOULD PRECLUDE
CONCERN FOR POTNTL OF ASPHYXIATION DUE TO NITROGEN DISPLACING AMT OF OXYG IN
AIR NEC TO SUPPORT LIFE. TOX PROPERTIES:INHAL OF HYDROGEN SULFIDE IS HIGHLY
TOX. IT RE ACTS W/ENZYMES IN BLOODSTREAM INHIBITING CELL RESP. CONTINUOUS
EXPOS RENDERS OLFACTORY SENSORS INOPERATIVE WHICH(SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP TO THESE MIX.
RESCUE PERS SHOULD BE EQUIPPED W/NIOSH APPRVD SCBA. INGEST:CALL MD IMMED (FP
N). EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF 15 MINS, SEEK ASSISTANCE
FROM MD (FP N). SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD (FP N).
INHAL:CONSCIOUS PERSONS SHOULD BE ASSISTED TO UNCONTAMD AREA & INAHLE
FRESH AIR. QUICK REMOVAL FROM CONTAMD(SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROP
PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE, CONTACT
CLOSEST LIQUID AIR CORPORATION LOCATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISP MUST BE I/A/W FED, STATE & LOC REGS (FP N). DO
NOT ATTEMPT TO DISPOSE OF WASTE/UNUSED QTYS. RETURN SHIPPING CNTNR PROPERLY
LBLD, W/ANY VALVE OUTLET PLUGS/CAPS SECURED & VALVE PROT CAP IN PLACE TO
LIQ AIR CORPORATION FOR PROPER DISP.
Handling And Storage Precautions: PROTECT CYLS FROM PHYSICAL DMG. STORE IN
COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAVILY TRAFFICKED AREAS AND
EMERGENCY EXITS.
Other Precautions: DO NOT ALLOW TEMP WHERE CYLS ARE STORED TO EXCEED 130F
(54C). CYLS SHOULD BE STORED UPRIGHT & FIRMLY SECURED TO PVNT
FALLING/BEING KNOCKED OVER. FULL & EMPTY CYLS SHOULD BE SEGREGATED. USE
"FIRST IN-F IRST OUT" INVENTORY SYS TO PVNT
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NONFLAMMABLE GAS MIXTURE. MEDIA SUITABLE FOR SURROUNDING
FIRE (FP N).
Unusual Fire/Explosion Hazard: CYLS CNTN HIGH PRESS GAS. IF CYL IS IN FIRE,
COOL IT & SURROUNDING CYLS W/WATER SPRAY TO CONTROL RISE OF INTERNAL
PRESS. CYL VALVE PRESS RELIEF DEVICE (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED POSITIVE PRESSURE AIR LINE WITH MASK OR
NIOSH APPRVD SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR
EMERGENCY USE.
Ventilation: LOC EXHAUST:TO PVNT ACCUM ABOVE TWA FOR H*2S & TO PVNT ACCUM
OF HIGH CONCS OF GASES SO AS TO REDUCE OXYG LEVEL
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). SAFETY
SHOES.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLO HAZ:MAY FUNC TO RELIEVE INTERNAL PRESS.
EFTS OF OVEREXP:COULD RESULT IN NITROGEN ACTING AS SIMPLE ASPHYXIANT BY
EXCLUDING ADEQ SUPPLY OF OXYGEN TO SUPPORT LIFE. FIRST AID PROC:AREA IS MOST
IMPOR TANT. UNCON PERSONS SHOULD BE MOVED TO UNCONTAMD AREA, GIVEN
MOUTH-TO-MOUTH RESUSCITATION & SUPP OXYG. MED
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: SEE INGS
M.P/F.P Text: SEE INGS
Vapor Pres: SEE INGS
Spec Gravity: 0.97 @ 70F
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: SEE INGREDIENTS
Appearance and Odor: COLORELSS GAS WITH PUNGENT (ROTTEN EGG) ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: NONE.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: 10-100 PPM HYDROGEN SULFIDE IN NITROGEN
Company: LIQUID AIR CORP ONE CALIFORNIA PLAZA
Street: 2121 N. CALIFORNIA BLVD
City: WALNUT CREEK CA
Zipcode: 94596
Health Emergency Phone: 800-231-366;800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 08/12/1997
Status Code: C
Label Date: 08/12/1997
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHALATION OF THESE MIXTURES FOR SHORT PERIODS OF
TIME SHOULD NOT CAUSE IRREVERSIBLE EFFECTS. (OSHA IDLH FOR H*2S=300 MOLAR
PPM). CONTINUOUS EXPOSURE TO THESE MIXTURES, PARTICULARLY HIGHER CONCE
NTRATIONS, SHOULD CAUSE IRRITATION TO MUCOUS MEMBRANES & CONJUCTIVAE OF
EYES. IT COULD ALSO CAUSE HEADACHE, DIZZINESS OR NAUSEA. CHRONIC:NONE LISTED
BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.