SOLUTIA INC. -- SKYDROL 500B-4 FIRE RESISTANT HYDRAULIC FLUID
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Material Safety Data Sheet
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NIIN: 01-056-4883
MSDS Num: CJDFJ
MSDS NAME: SKYDROL 500B-4 FIRE RESISTANT HYDRAULIC FLUID
Responsible Party
Name: SOLUTIA INC.
Address: 10300 OLIVE BLVD
Box: 66760
City: ST LOUIS MO 63166-6760
Info Phone: 800-426-7022/314-694-6661
Emergency Phone Number: 314-674-6661
Resp. Party Other MSDS No.: M00006729
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Item Description Information
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Item Manager: S9G
Item Name: HYDRAULIC FLUID,FIRE RESISTANT
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: QT
UI Container Qty: G
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL, RAT) 2,200 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONTACT: THIS PRODUCT CAUSES SEVERE PAIN WITHOUT EYE
DAMAGE BASED ON HUMAN EXPERIENCE. SKIN CONTACT: THIS MATERIAL REMOVES OILS
FROM SKIN CAUSING DRYING AND CRACKING FOLLOWING REPEATED AND PROLONG ED
CONTACT. INHALATION: EXPOSURE TO AEROSOLIZED FLUID OR VAPORS (PRODUCED AT
HIGH TEMPERATURES) MAY CAUSE NOSE AND THROAT IRRITATION, COUGHING AND
WHEEZING. INHALATION OF TRIBUTYL PHOSPHATE MAY CAUSE NAUSEA AND HEADACHE.
INGESTION: THIS PRODUCT IS NO MORE THAN SLIGHTLY TOXIC BASED ON TOXICITY
STUDIES. SIGNIFICANT ADVERSE HEALTH EFFECTS ARE NOT EXPECTED TO DEVELOP IF
ONLY SMALL AMOUNTS (LESS THAN A MOUTHFUL) ARE SWALLOWED.
Explanation Of Carcinogenicity: NOT PROVIDED.
Signs And Symptions Of Overexposure: EYE CONTACT: THIS PRODUCT CAUSES SEVERE
PAIN WITHOUT EYE DAMAGE BASED ON HUMAN EXPERIENCE. SKIN CONTACT: THIS
MATERIAL REMOVES OILS FROM SKIN CAUSING DRYING AND CRACKING FOLLOWING
REPEATED AND PROLONG ED CONTACT. INHALATION: EXPOSURE TO AEROSOLIZED FLUID OR
VAPORS (PRODUCED AT HIGH TEMPERATURES) MAY CAUSE NOSE AND THROAT IRRITATION,
COUGHING AND WHEEZING. INHALATION OF TRIBUTYL PHOSPHATE MAY CAUSE NAUSEA AND
HEADACHE.
Medical Cond Aggravated By Exposure: NOT PROVIDED.
First Aid: IF IN EYES, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. REMOVE MATERIAL FROM SKIN AND CLOTHING. IF ON
SKIN, IMMEDIATELY FLUSH WITH PLENTY OF WATER. REMOVE CO NTAMINATED CLOTHING.
GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. GET MEDI CAL ATTENTION. REMOVE MATERIAL FROM EYES,
SKIN AND CLOTHING. IF SWALLOWED, IMMEDIATE FIRST AID IS NOT LIKELY TO BE
REQUIRED. A PHYSICIAN OR POISON CONTROL CENTER CAN BE CONTACTED FOR ADVICE.
WASH CONT AMINATED CLOTHING BEFORE REUSE
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Handling and Disposal
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Spill Release Procedures: CONTAIN LARGE SPILLS WITH DIKES AND TRANSFER THE
MATERIAL TO APPROPRIATE CONTAINERS FOR RECLAMATION OR DISPOSAL. ABSORB
REMAINING MATERIAL OR SMALL SPILLS WITH AN INERT MATERIAL AND THEN PLACE IN A
CH EMICAL WASTE CONTAINER.
Neutralizing Agent: NOT RELEVANT.
Waste Disposal Methods: THIS PRODUCT AS SOLD, WOULD NOT BE CONSIDERED
"HAZARDOUS WASTE" AND MEETS CRITERIA FOR A SYNTHETIC USED OIL UNDER THE EPA.
DISCARDED PRODUCT SHOULD BE INCINERATED IN ACCORDANCE WITH ALL LOCAL, STATE,
AND FEDERAL LAWS AND REGULATIONS. THIS PRODUCT SHOULD NOT BE DUMPED,
SPILLED, RINSED, OR WASHED INT O SEWERS OR PUBLIC WATERWAYS.
Handling And Storage Precautions: AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID BREATHING VAPOR OR MIST. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER
CLOSED. WASH THOROUGHLY AFTER HANDLING. PRODUCT IS STABLE UNDER ORDINARY
COND ITIONS OF HANDLING & STORAGE AND UNDER CONTINUED USE UP TO
APPROXIMATELY 250-275F.
Other Precautions: EMPTIED CONTAINER RETAINS VAPOR AND PRODUCT RESIDUE. OBSERVE
ALL LABELLED SAFEGUARDS UNTIL CONTAINER IS DESTROYED. DO NOT REUSE THIS
CONTAINER.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: =160.C, 320.F
Autoignition Temp: =398.9C, 750.F
Extinguishing Media: IN CASE OF FIRE, USE WATER SPRAY (FOG), FOAM, DRY
CHEMICAL, OR CARBON DIOXIDE.
Fire Fighting Procedures: FIRE IFGHTERS AND OTHERS EXPOSED TO PRODUCTS OF
COMBUSTION SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. EQUIPMENT SHOULD
BE THRORUGHLY DECONTAMINATED AFTER USE.
Unusual Fire/Explosion Hazard: PRODUCTS OF COMBUSTION INCLUDE HAZARDOUS CARBON
MONOXIDE, CARBON DIOXIDE AND OXIDES OF PHOSPHORUS.
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Control Measures
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Respiratory Protection: IF EXPOSURE MAY OR DOES EXCEED OCCUPATION EXPOSURE
LIMITS USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD
WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AI
R-PURIFYING RESPIRATOR. IF USED, FULL FACEPIECE REPLACES NEED FOR CHEMICAL
GOGGLES AND/OR FACE SHIELD.
Ventilation: USE NATURAL/ MECHANICAL VENTILATION TO CONTROL EXPOSURE LEVELS
BELOW AIRBORNE EXPOSURE LIMITS. USE LOCAL MECHANICAL VENTILATION AT SOURCE
OF AIR CONTAMINATION
Protective Gloves: CHEMICAL RESISANT/CONSULT SOLUTIA GLOVE FACTS TO DETERMINE
APPROPRIATE TYPE.
Eye Protection: CHEMICAL GOGGLES, SAFETY GLASSES WITH SIDES, FACE SHIELD.
Other Protective Equipment: WEAR APPROPRIATE PROTECTIVE CLOTHING AS NECESSARY
TO PREVENT SKIN CONTACT, RUBBER APRON. AN EMERGENCY EYEWASH AND SHOWER SHOULD
BE AVAILABLE.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED
CLOTHING AND CLEAN PROTECTIVE EQUIPMENT BEFORE REUSE.
Supplemental Safety and Health: NOTE TO MEDICAL PERSONNEL: AFTER FLUSHING EYES
FOR AT LEAST 15 MINUTES, OPHTHALMIC PREPARATIONS OF STERILE MINERAL OR CASTOR
OIL MAY BE INSTILLED ONE TIME IN THE EXPOSED EYE FOR RELIEF OF PAIN.
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Physical/Chemical Properties
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HCC: V6
NRC/State LIC No: NOT RELEVANT.
B.P. Text: NOT PROVIDED.
Melt/Freeze Pt: <-62.2C, -80.F
M.P/F.P Text: MAXIMUM, POUR POINT
Decomp Text: NOT PROVIDED.
Spec Gravity: 1.052-1.060 @ 25/25 C
Viscosity: 11.3-12.4 CST @ 100F
Appearance and Odor: CLEAR, PURPLE OILY LIQUID; NO ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: PRODUCT IS STABLE UNDER ORDINARY CONDITIONS OF
HANDLING AND STORAGE AND UNDER CONDITIONS OF USE UP TO APPROXIMATELY
250-275F..
Materials To Avoid: EXPOSURE TO STRONG OXIDIZING AGENTS MAY RESULT IN
GENERATION OF HEAT AND COMBUSTION PRODUCTS.
Hazardous Decomposition Products: PRODUCTS OF COMBUSTION INCLUDE HAZARDOUS
CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF PHOSPHORUS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: DOES NOT OCCUR.
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Toxicological Information
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Toxicological Information: DATA FROM SOLUTIA SINGLE-DOSE (ACUTE) ANIMAL STUDIES
WITH THIS MATERIAL FOLLOW: ORAL-SLIGHTLY TOXIC (RAT LD50 - 2200 MG/KG).
DERMAL-PRACTICALLY NONTOXIC (RABBIT LD50 - >7940 MG/KG). INHALATION-(RAT
LC 50 - >4.5 MG/L) NO MORTALITY OBSERVED AT 5.8 G/L, THE HIGHEST
ATMOSPHERIC CONCENTRATION ACHIEVABLE IN THIS STUDY. EYE IRRITATION-SLIGHTLY
IRRITATING, (RABBIT, 2.4/110.0, 24-HR. EXP). SKIN IRRITATION-S LIGHTLY
IRRITATING, (RABBIT, 2.5/8.0, 24-HR EXP.). NO ALLERGIC SKIN REACTION OBSERVED
IN CONTROLLED HUMAN CONTACT STUDIES WITH HUMAN VOLUNTEERS. TRIBUTYL PHOSPHATE
MAY CAUSE UNINARY BLADDER DAMAGE.
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Ecological Information
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Ecological: THE FOLLOWING DATA HAVE BEEN CLASSIFIED USING THE CRITERIA ADOPTED
BY THE EUROPEAN ECONOMIC COMMUNITY (EEC) FOR AQUATIC ORGANISM TOXICITY.
BIODEGRADATION TESTS CONDUCTED WITHA SIMILAR PRODUCT SUGGEST THAT THIS
MATERIAL WOULD MEET THE OECD GUIDELINES FOR CLASSIFICATION AS "READILY
BIODEGRADABLE. 48-HR EC50 DAPHNIA MAGNA:6.5 MG/L; TOXIC. 96-HR LC50 FATHEAD
MINNOW:3.0 MG/L; TOXIC. 96-HR LC50 RAINBOW TROUT:2.5 MG/L;TOXIC. 96-HR EC50
ALGAE (CHLOROPHYLL):7.1 MG/L; TOXIC. 96-HR EC50ALGAE (CELL COUNT):8.4 MG/L;
TOXIC.
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MSDS Transport Information
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Transport Information: THIS PRODUCT IS NOT HAZARDOUS UNDER THE APPLICABLE DOT,
ICAO/IATA, OR IMDG REGULATIONS.
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Regulatory Information
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Federal Regulatory Information: TSCA INVENTORY: ALL COMPONENTS ARE LISTED.
CERCLA REPORTABLE QUANTITY: NONE. PRODUCT MEETS THE CRITERIA FOR A SYNTHETIC
USED OIL UNDER US EPA STANDARDS FOR THE MANAGEMENT OF USED OIL (40CFR 279).
PRO DUCT AS SOLD IS NOT CONSIDERED A HAZARDOUS WASTE AS DEFINED IN 40 CFR
261. SPILLED PRODUCTS OR SPILLS ABSORBED INTO SOLID MEDIA SHOULD BE ANALIZED
IAW THE CRITERIA OF 40 CFR 261.24 AND/OR EPA METHOD 1 311, TOXICITY
CHARACTERISTIC LEACHING PROCEDURE (TCLP).
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Other Information
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Other Information: REASON FOR REVISION: ROUTINE REVIEW AND COMPANY NAME CHANGE
TO SOLUTIA. SUPERCEDES MSDS DATED 07/17/95.
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Transportation Information
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Trans ID NO: 138897
MSDS NAME: SKYDROL 500B-4 FIRE RESISTANT HYDRAULIC FLUID
MSDS Prepared Date: 06/18/1998
Review Date: 02/23/2000
Net Unit Weight: 2.2 LBS
Multiple KIT Number: 0
Unit Of Issue: QT
Container QTY: G
Additional Data: NOT REGULATED FOR TRANSPORTATION, PER MSDS.
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: SKYDROL 500B-4 FIRE RESISTANT HYDRAULIC FLUID
Company: SOLUTIA INC.
Street: 10300 OLIVE BLVD
City: ST LOUIS MO
Zipcode: 63166-6760
Health Emergency Phone: 314-674-6661
Label Required IND: Y
Date Of Label Review: 02/23/2000
Status Code: C
MFG Label NO: UNKNOWN.
Label Date: 06/18/1998
Year Procured: 2000
Origination
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: NO
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: SKIN, EYES, RESPIRATORY SYSTEM ().
WARNING: CAUSES EYE, SKIN AND RESPIRATORY IRRITATION. FIRST AID: IF IN EYES,
IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATT ENTION.
IF ON SKIN, IMMEDIATELY FLUSH WITH PLENTY OF WATER. REMOVE CONTAMINATED
CLOTHING. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. IF INHALED,
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ART IFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. REMOVE MATERIAL
FROM EYES, SKIN AND CLOTHING. IF SWALLOWED, IMMEDIATE FIRST AID IS NOT LIKELY
TO BE REQUIRED. A PHYS ICIAN/POISON CONTROL CENTER CAN BE CONTACTED.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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