TROY CHEMICAL -- TROYMAX COBALT 6%
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Material Safety Data Sheet
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MSDS Num: CJHZJ
MSDS NAME: TROYMAX COBALT 6%
Responsible Party
Name: TROY CHEMICAL
Address: ONE AVENUE L
City: NEWARK NJ 07105
Info Phone: 973-589-2500
Emergency Phone Number: (800)424-9300
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: TROY CHEMICAL
Address: ONE AVENUE L
City: NEWARK NJ 07105
Phone: 973-589-2500
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Item Description Information
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: INGEST: SINGLE DOSE ORAL TOX LOW. SWALLOWING SM AMTS
DURING NORM HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS. INGEST OF EXCESS QTYS
MAY CAUSE GI IRRIT (NAUS, VOMIT & DIARR). ASPIR OF MATL INTO LUNGS CAN
CAUSE LUNG DMG. VENTRICULAR FIBRILATION MAY OCCUR. SKIN: DIRECT CNTCT MAY
CAUSE MOD TO SEV IRRIT & POSS BURNS. SOLVS MAY BE ABSORBED THRU SKIN
& MAY CONTRIBUTE TO SYMPS OF TOXICITY FROM OTHER ROUTES OF EXPOS. SENSIT
DERM MAY OCCUR IN PERS WHO HAVE BEEN PREVIOUSLY EXPOS TO COBALT CMPDS. EYE
CNTCT: EXPOS TO LIQ/VAPS MAY CAUSE SEV IRRIT, REDNESS, PAIN & TEARING.
MAY CAUSE CORNEAL INJURY UNLESS WASHE D FROM EYES PROMPTLY. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: COBALT: IARC MONOGRAPHS, VOL 52, PG 363,
1991:GROUP 2B.
Signs And Symptions Of Overexposure: HLTH HAZS: SHORT-TERM INHAL TOX IS LOW.
BRTHG SMALL AMTS DURING NORM HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS.
EXCESS INHAL MAY BE HARMFUL & MAY CAUSE RESP IRRIT, NAUS, VOMIT,
DRUNKENNESS & LUNG DMG. VENTRICULAR FILBRATION MAY OCCUR. SYMPS ARE MORE
TYPICALLY SEEN AT AIR CONCS EXCEEDING RECOM EXPOS LIMS. COBALT CMPDS MAY
CAUSE UPPER RESP TRACT IRRIT. SENSIT RXNS MAY OCCUR IN PREVIOUSLY EXPOSED PER
S. CHRONIC: OVEREXP TO MATL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS CAUSE
OF FOLLOWING EFTS IN LAB ANIMALS & MAY AGGRAVATE PRE-EXISTING DISORDERS
OF THESE ORGANS IN HUMANS. (SUPDAT)
Medical Cond Aggravated By Exposure: PRE-EXISTING SKIN DISORDERS &
ALLERGIES, PRE-EXISTING RESPIRATORY PROBLEMS. MAY AGGRAVATE EXISTING KIDNEY,
URETHRA OR BLOOD DISEASE.
First Aid: INGEST: GET MED ATTN IMMED. DO NOT INDUCE VOMIT. IF VOMIT OCCURS,
KEEP HEAD LOWER THAN HIPS TO PVNT ASPIR. SKIN: REMOVE CONTAM CLTHG &
SHOES IMMED. WASH AFFECTED AREAS W/SOAP OR MILD DETERGENT & LARGE AMTS
OF WATER UNTIL NO EVID OF CHEM REMAINS (APPROX 15 MIN). IF IRRIT/REDNESS
PERSISTS, GET MED ATTN. WASH CLTHG BEFORE REUSE. EYES: WASH IMMED W/LARGE
AMTS OF WATER FOR AT LST 15 MIN. GET MED ATTN I MMED. INHAL: REMOVE FROM
EXPOS TO FRESH AIR PROMPTLY. IF BRTHG IS DFCLT, OXYG SHOULD BE ADMIN BY
QUALIFIED PERS. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. KEEP WARM & AT
REST. TREAT SYMP & SUPPORTIVELY . GET MED ATTN. NOTES TO MD: NONE.
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Handling and Disposal
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Spill Release Procedures: KEEP UNNEC PEOPLE AWAY; ISOLATE HAZ AREA & DENY
ENTRY. STAY UPWIND; KEEP OUT OF LOW AREAS. NIOSH APPRVD POS PRESS SCBA &
STRUCTURAL FIREFIGHTER'S PROT CLTHG WILL PROVIDE LIMITED PROT. SHUT OFF IGNIT
S OURCES; NO FLARES, SMKNG OR FLAMES IN HAZ AREA. STOP LEAK IF YOU CAN DO IT
W/OUT RISK. USE WATER SPRAY TO REDUCE VAP, BUT IT MAY NOT PVNT IGNIT IN CLSD
SPACES. FOR SM SPILLS, (SUP DAT)
Waste Disposal Methods: THIS PRODUCT IS A RCRA HAZARDOUS WASTE BASED ON ITS
FLASH POINT (<60C) THEREFORE MEETING THE CHARACTERISTIC OF IGNITABILITY.
DISPOSAL PROCEDURES MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REG
ULATIONS.
Handling And Storage Precautions: AVOID CNTCT W/SKIN, EYES OR CLTHG. AVOID
BRTHG VAPOR OR MIST. WASH THOROUGHLY AFTER HANDLING. KEEP CNTNR TIGHTLY
CLOSED. USE ONLY W/ADEQ VENT. "EMPTY" CNTNRS RETAIN PROD RESIDUE (LIQUID
&/OR VAPOR) & CAN BE DANGEROUS.
Other Precautions: DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR
EXPOSE SUCH CNTNRS TO HEAT, FLAMES, SPKS, STATIC ELEC/OTHER SOURCES OF IGNIT.
THEY MAY EXPLODE & CAUSE INJURY OR DEATH. EMPTY DRUMS SHOULD BE
COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY RETURNED TO DRUM
RECONDITIONER OR PROPERLY DISPOSE D OF. (OTHER INFO)
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point: =39.C, 102.2F
Lower Limits: SEE INGREDS
Upper Limits: SEE INGREDS
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL FOAM
Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. APPLY COOLING WATER TO
SIDES OF CNTNRS THAT ARE EXPOS TO FLAMES UNTIL WELL AFTER FIRE IS OUT. AVO ID
BRTHG VAPS, KEEP UPWIND.
Unusual Fire/Explosion Hazard: SOLV VAPS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/BE MOVED BY VENT & IGNITED BY FLAMES & IGNIT SOURCES. RUNOFF
TO SEWER MAY CREATE FIRE/EXPLO HAZ. NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPT Y) - PROD (EVEN RESIDUE) CAN IGNITE EXPLO. NFPA RATING: HLTH:
2; FLAM: 2; REACTIVITY: 0 (0-MINIMAL HAZ; 2-MOD HAZ).
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Control Measures
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Respiratory Protection: IF EXPOSURE MAY EXCEED RRECOMMENDED LIMITS, A NIOSH
APPROVED RESPIRATOR SHOULD BE USED BASED ON EXPOSURE LEVELS FOUND IN THE
WORKPLACE AND IN COMPLIANCE WITH OSHA'S 29 CFR 1910.134.
Ventilation: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET
PUBLISHED EXPOSURE LIMITS.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGHT
FACESHIELD (FP N)
Other Protective Equipment: ANSI APPROVED EYE WASH AND DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING TO PREVENT SKIN CONTACT.
Supplemental Safety and Health: EFTS OF OVEREXP: CNS, SKIN, LUNGS, BLOOD,
IMMUNE SYSTEM (SENSITIZER), LIVER & KIDNEYS. SPILL PROC: ABSORB
W/VERMICULITE OR OTHER NONCOMBUST ABSORB MATL & PLACE INTO CNTNRS FOR
LATER DISP. FOR LG SPILL S, DIKE FAR AHEAD OF LIQ SPILL FOR LATER DISP. IF
WATER POLLUTION OCCURS, NOTIFY APPROP AUTHS (OTHER INFO)
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Physical/Chemical Properties
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Boiling Point: =150.C, 302.F
B.P. Text: (INITIAL)
Vapor Pres: SEE INGREDS
Spec Gravity: 0.89 (H*2O=1)
PH: NOT DETERMINED
Solubility in Water: INSOLUBLE
Appearance and Odor: BLUE-VIOLET LIQUID; SOLVENT ODOR.
Percent Volatiles by Volume: 65WT NOMINAL
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID HEAT OR SOURCES OF IGNITION.
Materials To Avoid: AVOID CONTACT WITH STRONG ACIDS, BASES AND OXIDIZERS.
Hazardous Decomposition Products: DECOMPOSITION MAY RELEASE CARBON MONOXIDE AND
CARBON DIOXIDE, COBALT OXIDES AND VARIOUS HYDROCARBONS.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: NO DATA AVAIL ON PROD, HOWEVER, TOXICOLOGICAL DATA
IS INCLUDED ON HAZ INGREDS. FOR ADDN INFO, CNTCT TROY CHEM CORP. SUBCHRONIC
EFTS & OTHER STUDIES: PETRO NAPHTHA: WORKERS RPTDLY EXPOS TO PETRO DISTIL
S COMPLAINED OF VISUAL DISTURBS. STUDYOF WRKERS RPTDLY EXPOS TO ALIPHATIC
& AROMATIC HYDROCARBS FOUND PSYCHOLOGICAL & NEUROPHYSICAL DIFFERENCES
BETWEEN EXPOS & NONEXPOS WORKERS. IN ANIMAL STUDIES, 2 S AMPLES OF
HYDROTREATED LIGHT PETRO DISTILS PRDCED SKIN TUMORS IN MICE AFTER RPTD
APPLICATN FOR 79 WK AVERAGE. GLYCOL ETHER: IN 90-DAY SKIN CNTCT STUDY, DOSAGE
LEVELS OF 5-10 MG/KG (ECOLOGICAL INFO)
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Ecological Information
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Ecological: ECOTOXICITY: METAL CMPDS ARE KNOWN TO HAVE DETRIMENTAL EFTS ON
AQUATIC ORGANISMS. ENVIRONMENTAL FATE: METAL CMPDS ARE KNOWN TO PERSIST IN
ENVIRONMENT. TOXICOLOGICAL INFO: CAUSED NARCOSIS & KIDNEY INJU RY.
NARCOSIS WAS NOT OBSERVED AT LOWER LEVELS, BUT SOME KIDNEY INJURY SEEN AT
LOWEST LEVEL, 1 MG/KG/DAY. TRADE SECRET INGRED: ORAL DOSES GIVEN TO PREGNANT
ANIMALS PRDCED SOME MINOR ABNORMS IN THEIR OF FSPRING. RSLTS OF PRELIMINARY
STUDIES SUGGEST THESE ABSORMS ARE NOT DIRECT EFTS BUT ARE CAUSED BY DISTURBS
IN METABOLISM IN PREGNANT ANIMALS. CNTCT NEHC FOR MORE TOXICOLOGICAL INFO
(FP N).
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MSDS Transport Information
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Transport Information: DOT: SHIPPING NAME: COMBUST LIQ, N.O.S. (CNTNS: PETRO
NAPHTHA). HAZ CLASS: COMBUST LIQ. UN/NA NUMBER: NA1993. PACKING GROUP: PG
III. LABELS REQD: NONE. IATA: SHIPPING NAME: FLAM LIQ, N.O.S. (CNTNS PET RO
NAPHTHA). HAZ CLASS: 3-FLAM LIQ. UN/NA NUMBER: UN1993. PACKING GROUP: PG III.
LABELS REQD: FLAM LIQ. IMO: SHIPPING NAME: FLAM LIQ, N.O.S. (CNTNS: PETRO
NAPHTHA). HAZ CLASS: 3.3-FLAM LIQ. UN NUMBER: UN1993. PAGE: PG 3345. EMS#:
3-07. MGAF#: 311. LABELS REQD: FLAM LIQ.
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Regulatory Information
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Sara Title III Information: SARA 302 (40 CFR 355.30), SARA SECTON 304 (40 CFR
355.40): THIS PROD CNTNS FOLLOWING TOX CHEMS THAT REQ EMER PLANNING BASED ON
THRESHOLD PLANNING QTYS (TPQ) & RELEASE REPORTING BASED ON RQ: NONE. SARA
HAZ CATEGORIES, SARA 311/312 (40 CFR 370.21): ACUTE, CHRONIC, FIRE. SARA 313
(40 CFR 372.65): THIS PROD CNTNS FOLLOWING TOX CHEMS SUBJECT TO REPORTING
REQS OF EMER PLANNING & COMMUNITY RIGHT-TO-KNOW ACT OF 1986. THIS INFO
MUST BE INCLUDED IN ALL MSDS'S THAT ARE COPIED & DISTRIBUTED FOR THIS
MATL: COBALT COMPOUND, PROPRIETARY CAS #, 25-35%.
Federal Regulatory Information: INGREDS OF THIS PROD ARE ON FOLLOWING CHEM
SUBSTANCE INVENTORIES: TSCA, EINECS, DSL. THIS PROD CNTNS FOLLOWING TOX CHEMS
THAT REQ NOTIFICATION OF NRC OF RELEASE OF QTYS OF HAZ SUBSTANCES EQUAL TO OR
G REATER THAN RQ: NONE. STATE INFO: CORR. FOLLOWING ARE ON WORKPLACE HAZ
SUBSTANCE LIST OF PA RIGHT-TO-KNOW REGS: PETRO DISTILS; 55-65%. COBALT CMPD
(TSR 222-306831-5312P; 25-35%. GLYCOL ETHER TSR (2220 306831)-541P.
State Regulatory Information: FOLLOWING COMPONENTS OF PROD ARE KNOWN BY STATE
OF CA TO CAUSE CANCER/REPRO TOX: BENZENE: <65 PPM; CANCER HAZ. COBALT:
TRACE; CANCER HAZ. FOLLOWING COMPONENTS ARE ON MA SUBSTANCE LIST & REQ
REPORING U NDER REG: PETRO DISTILS; 55-65%. GLYCOL ETHER TSR
(222-306831)-541P; <5%. BENZENE: <65 PPM; EXTRAORDINARILY HAZ
SUBSTANCE, CARCIN. NJ RIGHT-TO-KNOW: FOLLOWING ARE REQD TO BE LISTED FOR
COMPLIANCE W/LA BELING REQS OF NJ RIGHT-TO-KNOW REGS: PETRO DISTILS; 55-65%.
COBALT CMPD TSR (222-306831)-5312P; 25- 35%. GLYCOL ETHER TSR
(222-306831)-541F; <5; F3-FLAMMABLE. TSR (222-306831)-5069P, <5%. AMYL
ACID PHOSPHATE: (FED REGS)
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Other Information
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Other Information: RATING: HLTH: 2; FLAM: 2; REACTIVITY: 0 (0=MINIMAL HAZ; 2:
MOD HAZ). SUPDAT: (1996 NORTH AMERICAN EMER RESPONSE GUIDEBOOK-GUIDE 128).
OBSERVE ALL FED, STATE & LOC REGS REGARDING NOTIFICATIONS OF ACCIDENTAL
RELS. OTHER PRECS: STORE AWAY FROM INCOMP SUBSTANCES IN COOL, DRY, VENTD
AREA. STORE I/A/W 29CFR1910.106. SUBSTANCES W/LOW ELECTROCONDUCTIVITY, WHICH
MAY BE IGNITED BY SPKS, SHOULD BE STORE IN CNTNRS WHICH MEET BONDING &
GROUNDING GUIDELINES IN NFPA77, RECOM PRACT ON STATIC ELEC. OBSERVE ALL FED,
STATE & LOCAL REGS WHEN STORING OR DISPOSING OF SUBSTANCE.
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HAZCOM Label
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MSDS NAME: TROYMAX COBALT 6%
Assigned IND: Y
Company: TROY CHEMICAL
Street: ONE AVENUE L
City: NEWARK NJ
Zipcode: 07105
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 07/20/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE! ACUTE: INGEST: GI IRRIT (NAUS, VOMIT
& DIARR). ASPIR OF MATL CAN CAUSE LUNG DMG. VENTRICULAR FIBRILATION MAY
OCCUR. SKIN: IRRIT & BURNS. MAY BE ABSORBED THRU SKIN & CONTRIBUTE
TO SYMP S OF TOXICITY. SENSIT DERM MAY OCCUR IN PERSONS WHO HAVE BEEN
PREVIOUSLY EXPOS TO COBALT CMPDS. EYE CNTCT: SEV IRRIT, REDNESS, PAIN &
TEARING. MAY CAUSE CORNEAL INJURY. INHAL: EXCESSIVE INHALATION MAY BE
HARMFUL & CAUSE RESP IRRIT, NAUS, VOMIT, DRUNKENNNESS & LUNG DAMAGE.
VENTRICULAR FIBRILATION MAY OCCUR. CHRONIC: CANCER HAZ. CONTAINS MATERAL
LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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