ICI DULUX/DEVOE COATINGS -- CATHA-COAT 304V LIQUID, 304E0200
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Material Safety Data Sheet
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MSDS Num: CKFSG
MSDS NAME: CATHA-COAT 304V LIQUID, 304E0200
Responsible Party
Name: ICI DULUX/DEVOE COATINGS
Address: 4000 DUPONT CIR
City: LOUISVILLE KY 40207
Info Phone: 502-897-9861
Emergency Phone Number: 800-545-2643
Resp. Party Other MSDS No.: 304V
Review Ind: Y
Published: Y
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Contractor Summary
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Name: GLIDDEN PAINT, ICI PAINTS NORTH AMERICA
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643/216-344-8207
Name: ICI DULUX/DEVOE COATINGS
Address: 4000 DUPONT CIR
City: LOUISVILLE KY 40207
Phone: 502-897-9861
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Ingredients
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Cas: 1070-10-6
Name: 1-HEXANOL, 2-ETHYL-, TITANIUM(4+) SALT
% low Wt: 5.
% high Wt: 10.
OSHA PEL: NOT ESTABLISHED
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
ACGIH STEL: NOT ESTABLISHED
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: BENZENE, DIMETHYL-, (XYLENE)
% low Wt: 20.
% high Wt: 30.
OSHA PEL: 100 PPM
OSHA STEL: 150 PPM
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 651 MG/M3;150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 107-98-2
RTECS #: UB7700000
Name: 2-PROPANOL, 1-METHOXY- ; (1-METHOXY-2-PROPANOL)
% low Wt: 5.
% high Wt: 10.
OSHA PEL: 100 PPM
OSHA STEL: 150 PPM
ACGIH TLV: 369 MG/M3;100 PPM
ACGIH STEL: 553 MG/M3;150 PPM
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Cas: 14464-46-1
RTECS #: VV7325000
Name: CRISTOBALITE; (CRYSTALLINE SILICA, CRISTOBALITE)
% low Wt: .1
% high Wt: 1.
OSHA PEL: 0.05 MG/M3
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: 0.05 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE
% low Wt: .01
% high Wt: .1
OSHA PEL: 1 PPM
OSHA STEL: 5 PPM
ACGIH TLV: 32 MG/M3;10 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL- ; (ETHYLBENZENE)
% low Wt: 1.
% high Wt: 5.
OSHA PEL: 435 MG/M3;100 PPM
OSHA STEL: 125PPM
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 543 MG/M3;125 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 11099-06-2
Name: ETHYL SILICATE POLYMER
% low Wt: 20.
% high Wt: 30.
OSHA PEL: NOT ESTABLISHED
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
ACGIH STEL: NOT ESTABLISHED
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Cas: 60676-86-0
RTECS #: VV7328000
Name: SILICA, VITREOUS
% low Wt: 30.
% high Wt: 40.
OSHA PEL: 0.1 MG/M3
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT,
EYE CONTACT, INGESTION. EFFECTS OF OVEREXPOSURE: INHALATION: IRRITATION OF
RESPIRATORY TRACT. PROLONGED OR REPEATED INHALATION MAY LEAD TO FATI GUE,
DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION,
NAUSEA, VOMITING, COUGHING, CENTRAL NERVOUS SYSTEM DEPRESSION, INTOXICATION,
TIGHTNESS OF CHEST, ANESTHETIC EFFECT OR NARCO SIS, DIFFICULTY OF BREATHING,
FEVER AND CHILLS, SEVERE LUNG IRRITATION OR DAMAGE, LOSS OF CONSCIOUSNESS,
RESPIRATORY FAILURE, ASPHYXIATION, DEATH. SKIN CONTACT: IRRITATION OF SKIN.
PROLONGED OR REPEA TED CONTACT CAN (EFFECTS OF OVEREXP)
Explanation Of Carcinogenicity: BENZENE: OSHA REGULATED, 29 CFR 1910.1028;
GROUP 1, IARC MONOGRAPHS VOL 29, P 149, 1982; KNOWN CARCINOGEN, NTP 8TH
ANNUAL REPORT ON CARCINOGENS, 1998. CRYSTALLINE SILICA-CRISTOBALITE: GROUP
2A, IARC MONOGRAPHS VOL 42, P 39, 1987; ANTICIPATED CARCINOGEN, NTP 8TH
ANNUAL REPORT ON CARCINOGENS, 1998
Signs And Symptions Of Overexposure: HEALTH HAZ (CONT): CAUSE DERMATITIS,
DEFATTING, BLISTERING, ALLERGIC RESPONSE. POSSIBLE SENSITIZATION TO THE SKIN.
SKIN CONT MAY RESULT IN DERMAL ABSORPTION OF COMPONENT(S) OF THIS PRODUCT
WHICH MAY C AUSE DROWSINESS. EYE CONTACT: IRRITATION OF THE EYES. PROLONGED
OR REPEATED CONT CAN CAUSE CONJUNCTIVITIS, BLURRED VISION, TEARING OF EYES,
REDNESS OF EYES, SEVERE EYE IRRITATION. INGESTION: INGESTI ON MAY CAUSE LUNG
INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS,
DROWSINESS, DIZINESS AND/OR LIGHTHEADEDNESS, UNCOORDINATION, NAUSEA,
VOMITING, DIARRHEA, GASTRO-INTESTINAL DISTURBANCE S, ABDOMINAL PAIN,
DIFFICULTY BREATHING.
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS. LUNG
DISORDERS. BLOOD DISORDERS. KIDNEY DISORDERS. LIVER DIRSORDERS.
First Aid: INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED
BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSONNEL GIVE
OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULT Y. SKIN
CONTACT: FLUSH FROM SKIN WITH WATER. REMOVE CONTAMINATED CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE. EYE CONTACT: FLUSH IMMEDIATELY WITH
LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR AT LEAST 15 MINUTES. IF
IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN MEDICAL TREATMENT. INGESTION: IF
SWALLOWED, OBTAIN MEDICAL TREATMENT IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL
REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. VENTILATE
AREA WITH EXPLOSION-PROOF EQUIPMENT. SPILLS MAY BE COLLECTED WITH ABSORBEN T
MATERIALS. USE NON-SPARKING TOOLS. EVACUATE ALL UNNECESSARY PERSONNEL. PLACE
COLLECTED MATERIAL IN PROPER CONTAINER. COMPLETE PERSONAL PROTECTIVE
EQUIPMENT MUST BE USED DURING CLEANUP. (OTHER INFO)
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
Handling And Storage Precautions: STORE BELOW 80F (27C). STORE BELOW 100F
(38C). KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP CONTAINER TIGHTLY
CLOSED IN A WELL VELTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT
WHEN NOT IN USE. GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT ACCUMULATION
OF STATIC CHARGE.
Other Precautions: USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES AND BREATHING
OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BE FORE EATING OR
SMOKING. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES.
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Fire and Explosion Hazard Information
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Flash Point: =15.6C, 60.F
Extinguishing Media: DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS. FIRE FIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE
PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS. SELF-CONTAINED BREATHING
APPARATUS RECOMMENDED.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE/BURST WHEN EXPOSED
TO EXTREME HEAT OR FIRE. VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT
TEMPERATURES. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL LONG DISTANCES TO A
SOURCE O F IGNITION AND FLASH BACK. MAY DECOMPOSE UNDER FIRE CONDITIONS
EMITTING IRRITANT AND/OR TOXIC GASSES.
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Control Measures
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Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED
RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Protective Gloves: IMPERVIOUS GLOVES
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: EYE WASH, SAFETY SHOWER (MEETING ANSI DESIGN
CRITERIA - FP N), IMPERVIOUS CLOTHING. FACE SHIELD, APRON, BOOTS.
Work Hygienic Practices: USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING
EQUIPMENT.
Supplemental Safety and Health: CONTAINS A CHEMICAL THAT IS MODERATELY TOXIC BY
INGESTION. OTHER EFFECTS OF OVEREXPOSUREMAY INCLUDE TOXICITY TO LIVER,
KIDNEY, CENTRAL NERVOUS SYSTEM, BLOOD. CONTAINS A CHEMICAL THAT MAY BE
ABSORBED T HROUGH SKIN. THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC) HAS DETERMINED THAT THERE IS SUFFICIENT (TOX INFO)
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Physical/Chemical Properties
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B.P. Text: 176-291
Spec Gravity: WT/GAL 9.79
VOC Grams/Liter: 392
Appearance and Odor: GRAY LIQUID
Percent Volatiles by Volume: 45.11
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES, MOISTURE, CONTACT WITH
OXIDIZING AGENTS, SPARKS, OPEN FLAME, IGNITION SOURCES.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, MONOMERS, AMINES, ALKALIS WATER,
HALOGENATED COMPOUNDS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF
SILICON, HYDROGEN, TOXIC GASES, ZINC OXIDE, UNIDENTIFIED ORGANIC COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: SUP DATA (CONT): EVIDENCE FOR THE CARCINOGENICITY OF
BENZENE TO HUMANS AND EXPERIMENTAL ANIMALS (GROUP 1). THE NATIONAL TOXICOLOGY
PROGRAM (NTP) HAS DETERMINED THAT BENZENE IS KNOWN TO BE CARCINOGENIC .
BENZENE IS REGULATED BY OSHA AS A CARCINOGEN. NOTICE - REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONA L MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A HAZARD BY INHALATION. IARC
HAS CLASSIFIED CRYSTALLINE SILICA AS CARCINOGENIC TO (ECOLOGICAL INFO)
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Ecological Information
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Ecological: TOX INFO (CONT): HUMANS (GROUP 1). CRYSTALLINE SILICA IS ALSO A
KNOWN CAUSE OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. NTP HAS CLASSIFIED
CRYSTALLINE SILICA A REASONABLY ANTICIPATED HUMAN CARCINOGEN. IN A 2 YEAR
INHALATION STUDY CONDUCTED BY THE NATIONAL TOXICOLOGY PROGRAM (NTP),
ETHYLBENZENE VAPOR AT 750 PPM PRODUCED KIDNEY AND TESTICULAR TUMORS IN RATS,
AND LUNG AND LIVER TUMORS IN MICE. GENETIC TOXICITY STUDIES SHOWED NO
GENOTOXIC EFFECTS. THE RELEVANCE OF THESE RESULTS TO HUMANS IS NOT KNOWN.
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MSDS Transport Information
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Transport Information: FREIGHT CLASSIFICATION: LIQUID - PAINT, 3, PG II, UN1263
(FLAMMABLE LIQUID). POWDER - ZINC DUST, 4.3, PG II, UN1436 (DANGEROUS WHEN
WET) SHIPPING WEIGHT: 4 - 1 GALLON KITS - 100 LBS (45.5 KG), 5 GAL LON KIT -
124 LBS (56.4 KG). FLASH POINT 60F (15.6C). PACKAGING: 1 GALLON KIT (3.785
L): 0.67 GALLON BASE, 0.33 POWDER; 5 GALLON KIT (18.925 L): 3.36 GALLONS
BASE, 1.64 POWDER. PAINT **PROTECT FROM FREEZING**
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Regulatory Information
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Sara Title III Information: CONTAINS THE FOLLOWING SARA SECTION 302 EHS
CHEMICALS: NONE. CONTAINS THE FOLLOWING SARA SECTION 313 CHEMICALS: ZINC,
DIMETHYLBENZENE, BENZENE, ETHYLBENZENE, ZINC OXIDE.
Federal Regulatory Information: CONTAINS THE FOLLOWING CERCLA CHEMICALS: ZINC,
DIMETHYLBENZENE, BENZENE, ETHYLBENZENE.
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Other Information
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Other Information: RATINGS: LIQUID: HEALTH-2, FLAMMABILITY-3, REACTIVITY-2;
POWDER: HEALTH-0, FLAMMABILITY-1, REACTIVITY-1. SPILL PROC (CONT): LARGE
SPILLS - SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN SPILL. PUMP TO
STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP EXCESS RESIDUE. KEEP
SALVAGABLE MATERIAL AND RINSE WATER OUT OF SEWERS AND WATER COURSES. SMALL
SPILLS - USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY.
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HAZCOM Label
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MSDS NAME: CATHA-COAT 304V LIQUID, 304E0200
Assigned IND: Y
Company: ICI DULUX/DEVOE COATINGS
Street: 4000 DUPONT CIR
City: LOUISVILLE KY
Zipcode: 40207
Health Emergency Phone: 800-545-2643
Label Required IND: Y
Date Of Label Review: 03/30/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: RESP TRACT IRRIT, FATIGUE, DROWS, DIZZ,
LIGHTHEAD, HEADACHE, UNCOORD, NAUSEA, VOMITING, COUGHING, CNS DEPRESS, INTOX,
TIGHT CHEST, ANESTH EFFECT, NARCOSIS, DIFF BREATHING, FEVER, CHILLS, SEV
LUNG IRRIT/DAMAGE, UNCONSC, RESP FAILURE, ASPHYX, DEATH. SKIN: IRRIT, DERM,
DEFATTING, BLISTERING, ALLERGIC RESP. DERMAL ABSORP MAY CAUSE DROWSINESS.
EYET: IRRIT, CONJUNCT, BLURRED VISION, TEARI NG, REDNESS, SEV IRRIT. INGEST:
ASPIR HAZ. MAY CAUSE DROWS, DIZZ, LIGHTHEAD, UNCOORD, NAUSEA, VOMITING,
DIARR, GI DISTURB, ABDOM PAIN, DIFF BREATHING. CHRONIC: CONT'S BENZENE-BLOOD
CARCIN & CRYST SIL ICA-LUNG CARCIN (FP N). MAY CAUSE SKIN SENSIT.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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