RHONE-POULENC AG COMPANY AGRI -- SEVIN(R) BRAND 80S CARBARYL INSECTICIDE
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Material Safety Data Sheet
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NIIN: 00-932-7297
MSDS Num: CKLSW
MSDS NAME: SEVIN(R) BRAND 80S CARBARYL INSECTICIDE
Responsible Party
Name: RHONE-POULENC AG COMPANY AGRICULTURAL CHEMICALS
Address: 2 T. W. ALEXANDER DRIVE
City: RESEARCH TRIANGLE PK NC 27709
Info Phone: 800-334-7577
Emergency Phone Number: 800-334-7577
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: RHONE-POULENC AG COMPANY AGRICULTURAL CHEMICALS
Address: 2 T. W. ALEXANDER DRIVE
City: RESEARCH TRIANGLE PK NC 27709
Phone: 800-334-7577
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Item Description Information
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Item Manager: S9G
Item Name: INSECTICIDE,CARBARYL
Unit of Issue: BX
Quantitative Expression: 00000000005EA
UI Container Qty: 1
Type of Container: BOX
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NONE PROVIDED BY MFR.
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: WARNING! MAY BE FATAL IF SWALLOWED. ACUTE: EYE: CAUSES
REDNESS, IRRITATION, TEARING. SKIN: HARMFUL IF ABRORBED THROUGH SKIN. MAY
PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. INHALATION: HARMFUL I F
INHALED. MAY PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. INGESTION: MAY
BE FATAL IF SWALLOWED. THIS PRODUCT CAUSES REVERSIBLE CHOLINESTERASE
INHIBITION. REPEATED OVEREXPOSURE MAY CAUSE MORE SE VERE CHOLINESTERASE
INHIBITION WITH MORE PRONOUNCED SIGNS & SYMPTOMS.
Explanation Of Carcinogenicity: THIS PRODUCT CONTAINS INGREDIENTS THAT ARE
CONSIDERED BY OSHA, NTP, IARC OR ACGIH TO BE POSSIBLE OR SUSPECTED HUMAN
CARCINOGENS.
Signs And Symptions Of Overexposure: MAY LEAD TO RAPID ONSET OF NAUSEA,
VOMITING, DIARRHEA, ABDOMINAL PAIN, INVOLUNTARY SHAKING, EXCESS SALIVATION,
PINPOINT PUPILS, BLURRED VISION, PROFUSE SWEATING, TEMPORARY PARALYSIS,
RESPIRATORY DESPR ESSION, CONVULSIONS.
Medical Cond Aggravated By Exposure: INHALATION OF PRODUCT MAY AGGRAVATE
EXISTING CHRONIC RESPIRATORY PROBLEMS SUCH AS ASTHMA, EMPHYSEMA, OR
BRONCHITIS. SKIN CONTACT MAY AGGRAVATE EXISTING SKIN DISEASE.
First Aid: EYE: HOLD EYELIDS OPEN & FLUSH WITH WATER FOR AT LEAST 15 MINS.
SEEK MEDICAL ATT'N. SKIN: IMMEDIATELY WASH WITH PLENTY OF SOAP & WATER
FOR AT LEAST 5 MINS. SEEK MEDICAL ATT'N IF IRRITATION DEVELOPS/P ERSISTS.
REMOVE CONTAMINATED CLOTHING & SHOES. INHALATION: REMOVE VICTIM FROM
IMMEDIATE SOURCE OF EXPOSURE & ASSURE THAT THE VICTIM IS BREATHING. IF
BREATHING IS DIFFICULT, ADMINISTER OXYGEN, IF AVAI LABLE. IF VICTIM IS NOT
BREATHING, ADMINISTER CPR. SEEK MEDICAL ATT'N. INGESTION: IF VICTIM IS
CONSCIOUS & ALERT, GIVE 2-3 GLASSES OF WATER & INDUCE VOMITING. SEEK
IMMEDIATE MEDICAL ATT'N. PREVENT ASP IRATION IF VOMITING OCCURS.
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Handling and Disposal
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Spill Release Procedures: WEAR APPROPRIATE PROTECTIVE GEAR. SHOVEL UP INTO AN
APPROPRIATE CLOSED CONTAINER. CLEAN UP RESIDUAL MATERIAL BY WASHING AREA WITH
WATER. DECONTAMINATE EQUIPMENT FOLLOWING CLEANUP. IF SPILLED ON THE GR OUND,
THE AFFECTED AREA SHOULD BE SCRAPED CLEAN & PLACED IN A APPROPRIATE
CONTAINER FOR DISPOSAL. SPILLS MAY BE REPORTABLE TO THE NATIONAL RESPONSE
CENTER (800-424-8802) AND STATE/LOCAL AGENCIES.
Neutralizing Agent: NONE PROVIDED BY MFR.
Waste Disposal Methods: CONSULT STATE & LOCAL REGULATIONS REGARDING THE
PROPER DISPOSAL OF THIS MATERIAL. ALTERING THIS MATERIAL MAY MAKE THE WASTE
MANAGEMENT INFORMATION PRESENTED IN THIS MSDS INCOMPLETE, INACCURATE OR OTHE
RWISE INAPPROPRIATE. STATE & LOCAL REQUIREMENTS FOR WASTE DISPOSAL MAY BE
MORE RESTRICTIVE OR OTHERW ISE DIFFERENT FROM FEDERAL.
Handling And Storage Precautions: MIN/MAX STORAGE TEMPERATURE: <38C (100F).
AVOID DIRECT OR PROLONGED CONTACT WITH SKIN & EYES. AVOID BREATHING
DUSTS. DO NOT INGEST. STORE IN ORIGINAL CONTAINER. STORE IN AN AREA THAT IS
COOL, DRY, A WAY FROM FOODSTUFFS OR ANIMAL FEED, OUT OF REACH OF CHILDREN
& ANIMALS.
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Fire and Explosion Hazard Information
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Lower Limits: NONE PROVIDE
Upper Limits: NONE PROVIDE
Extinguishing Media: SM: CARBON DIOXIDE, DRY CHEMICAL. LG: ALCOHOL FOAM,
POLYMER FOAM, WATER SPRAY
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED SELF
CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. KEEP
UNNECESSARY PEOPLE AWAY, ISOLATE HAZARD AREA & DENY ENTRY. EVACUATE
RESIDENTS WHO ARE D OWNWIND OF FIRE. DIKE AREA TO PREVENT RUNOFF &
CONTAMINATION OF WATER SOURCES. DISPOSE OF FIRE CONTROL WATER LATER.
Unusual Fire/Explosion Hazard: LIKE ALL ORGANIC & MOST DRY CHEMICALS, AS A
POWDER OR DUST, THIS PRODUCT (WHEN MIXED WITH AIR IN CRITICAL PROPORTIONS
& IN THE PRESENCE OF AN IGNITION SOURCE) MAY PRESENT AN EXPLOSION HAZARD.
PERSONS WHO MAY HAVE BEEN EXPOSED TO CONTAMINATED SMOKE SHOULD BE
IMMEDIATELY EXAMINED BY A PHYSICIAN & CHECKED FOR POISONING.
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Control Measures
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Respiratory Protection: WHEN RESPIRATORS ARE REQUIRED, SELECT NIOSH/MSHA
APPROVED EQUIPMENT BASED ON ACTUAL OR POTENTIAL AIRBORNE CONCENTRATIONS &
IN ACCORDANCE WITH THE LATEST OSHA STANDARD (29 CFR 1910.134) AND/OR ANSI Z88
.2 RECOMMENDATIONS.
Ventilation: GENERAL AREA DILUTION/EXHAUST VENTILATION.
Protective Gloves: USE SUITABLE PROTECTIVE GLOVES.
Eye Protection: CHEMICAL SAFETY GLASSES WITH SIDE SHIELDS OR SPLASH PROOF
GOGGLES.
Other Protective Equipment: AN EMERGENCY EYE WASH MUST BE READILY ACCESSIBLE TO
THE WORK AREA, SUITABLE PROTECTIVE CLOTHING AND FOOTWEAR.
Work Hygienic Practices: DO NOT STORE, USE, AND/OR CONSUME FOODS, BEVERAGES,
TOBACCO PRODUCTS, OR COSMETICS IN AREAS WHERE THIS MATERIAL IS STORED. WASH
HANDS & FACE CAREFULLY BEFORE EATING, DRINKING, ETC.
Supplemental Safety and Health: WASH EXPOSED SKIN PROMPTLY TO REMOVE ACCIDENTAL
SPLASHES OF CONTACT WITH THIS MATERIAL. DO NOT TAKE CLOTHING/OBJECTS
CONTAMINATED BY THIS MATERIAL OFF THE WORK SITE. SHOWER & CHANGE INTO
STREET CLOTHE S BEFORE LEAVING THE WORK SITE.
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Physical/Chemical Properties
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HCC: T5
B.P. Text: NO DATA AVAILABLE
M.P/F.P Text: NO DATA AVAILABLE
Decomp Temp: =40.C, 104.F
Vapor Pres: NO DATA AVAILABLE
Vapor Density: NO DATA AV
Spec Gravity: NO DATA AVAILABLE
PH: 4-6.5@5 WT/WT%
Viscosity: NONE PROVIDED BY MFR.
Evaporation Rate & Reference: NONE PROVIDED BY MFR.
Solubility in Water: DISPERSIBLE
Appearance and Odor: OFF-WHITE TO PALE YELLOW POWDER SOLID. PHENOLIC ODOR
Percent Volatiles by Volume: NONE PROVIDE
Corrosion Rate: NONE PROVIDED BY MFR
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS MATERIAL IS STABLE UNDER NORMAL HANDLING &
STORAGE CONDITIONS. AVOID EXTREME HEAT AND OPEN FLAME
Materials To Avoid: STRONG ACIDS, BASES
Hazardous Decomposition Products: OXIDES OF NITROGEN, OXIDES OF CARBON, METHYL
ISOCYANATE (TRACE AMOUNTS; NO ADVERSE HEALTH EFFECTS EXPECTED)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR
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Toxicological Information
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Toxicological Information: ACUTE EYE IRRITATION: SLIGHT IRRITATION, RABBIT.
ACUTE SKIN IRRITATION: MINIMAL IRRITATION, RABBIT. ACUTE DERMAL TOXICITY:
LD50 >2000 MG/KG, RABBIT. ACUTE RESPIRATORY IRRITATION: NO TEST DATA
FOUND FOR PRODUCTS. ACUTE ORAL TOXICITY: LD50 281 MG/KG, RAT. CARBARYL HAS
BEEN SHOWN TO CAUSE TUMORS IN LABORATORY ANIMALS IN LIFETIME FEEDING STUDIES.
CARBARYL, WHEN ADMINISTERED BY VARIOUS ROUTES, AT DOSES TOXIC TO THE
MATERNAL ANIMALS, HAS BEEN SHOWN TO PRODUCE DEVELOPMENTAL TOXICITY IN A
NUMBER OF SPECIES. CARBARYL PRODUCES NO TERATOGENIC EFFECT IN THE ABSENCE OF
MATERIAL TOXICITY.
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Ecological Information
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Ecological: FOR ECOTOXICOLOGICAL DATA OR CHEMICAL FATE DATA CALL THE PRODUCT
INFORMATION PHONE NUMBER LISTED.
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MSDS Transport Information
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Transport Information: FOR TRANSPORTATION REGULATORY INFORMATION CALL THE
PRODUCT INFORMATION PHONE NUMBER.
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Regulatory Information
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Sara Title III Information: ACUTE AND CHRONIC HEALTH HAZARD UNDER SARA TITLE
III. SARA 313 CHEMICALS: CARBARYL, (1-NAPHTHYL N-METHYLCARBAMATE) (80%).
SARA EXTREMELY HAZARDOUS SUBSTANCES (EHS) / CERCLA HAZARDOUS SUBSTANCES : CA
RBARYL, (1-NAPHTHYL N-METHYLCARBAMATE), 100 LBS.
State Regulatory Information: THIS PRODUCT CONTAINS THE FOLLOWING COMPONENTS
THAT ARE REGULATED UNDER CALIFORNIA PROPOSITION 65: SILICA, CRYSTALLINE
(AIRBORNE PARTICLES OF RESPIRABLE SIZE). CANCER LIST: Y.
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Other Information
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Transportation Information
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Trans ID NO: 153032
MSDS NAME: SEVIN(R) BRAND 80S CARBARYL INSECTICIDE
MSDS Prepared Date: 12/18/1995
Review Date: 05/17/2000
Multiple KIT Number: 0
Unit Of Issue: BX
Container QTY: 1
Type Of Container: BOX
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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