DOW AGROSCIENCES LLC -- DURSBAN PRO INSECTICIDE; PRODUCT CODE: 46482
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Material Safety Data Sheet
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NIIN: 01-412-4361
MSDS Num: CKLVW
MSDS NAME: DURSBAN PRO INSECTICIDE; PRODUCT CODE: 46482
Responsible Party
Name: DOW AGROSCIENCES LLC
Address: 9330 ZIONSVILLE ROAD
Box: 681428
City: INDIANAPOLIS IN 46268-1189
Info Phone: 800-992-5994
Emergency Phone Number: 800-992-5994
Resp. Party Other MSDS No.: 004949
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DOW AGROSCIENCES LLC
Address: 9330 ZIONSVILLE ROAD
Box: 681428
City: INDIANAPOLIS IN 46268-1189
Phone: 800-992-5994
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Item Description Information
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Item Manager: S9G
Item Name: INSECTICIDE,DURSBAN
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: PT
UI Container Qty: 0
Type of Container: BOTTLE,SQUEEZ
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: LD50 (ORAL, MALE RAT) IS 620 MG/KG.
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: MAY CAUSE SLIGHT EYE IRRITATION. CORNEAL INJURY IS
UNLIKELY. SKIN: PROLONGED EXPSURE NOT LIKELY TO CAUSE SIGNIFICANT SKIN
IRRITATION. A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN THE
MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INGESTION: SINGLE
DOSE ORAL TOXICITY IS CONSIDERED TO BE LOW. INHALATION: AT ROOM TEMPERATURE,
VAPORS ARE MINIMAL DUE TO LOW VAPOR PRESSURE. EXCESSIVE EXPOSURE MAY
PRODUCE ORGANOPHOSPHATE TYPE CHOLINESTERASE INHIBITION.
Explanation Of Carcinogenicity: CHLORPYROFOS AND OTHER TESTED COMPONENTS DID
NOT CAUSE CANCER IN LONG-TERM ANIMAL STUDIES.
Signs And Symptions Of Overexposure: IRRITATION, HEADACHE, DIZZINESS,
INCOORDINATION, MUSCLE TWITCHING, TREMORS, NAUSEA, VOMITING, ABDOMINAL
CRAMPS, DIARRHEA, SWEATING, PINPOINT PUPILS, BLURRED VISION, SALIVATION,
TEARING, TIGHTNESS IN C HEST, EXCESSIVE URINATION, CONVULSION.
First Aid: CALL PHYSICIAN IF SYMPTOMS PERSIST. EYE: IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN: WASH WITH SOAP AND WATER.
INHALED: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION,
PREFERABLY BY MOUTH TO MOUTH. ORAL: DO NOT INDUCE VOMITING. CALL A
PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. DO NOT PUT ANYTHING INTO THE
MOUTH OF AN UNCONSCIOUS PERSON.
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Handling and Disposal
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Spill Release Procedures: WEAR LONG PANTS, LONG-SLEEVED SHIRT, AND IMPERVIOUS
RUBBER GLOVES WHEN HANDLING CONCENTRATE AND CLEANING UP SPILLS. ABSORB SPILLS
WITH AN INERT ABSORBENT MATERIAL SUCH AS HAZORB, ZORBALL, SAND, OR DIR T.
SCOOP CONTAMINATED ABSORBENT MATERIAL INTO CONTAINER. THOROUGHLY WASH BODY
AREAS THAT COME INTO CONTACT WITH THIS PRODUCT. FOR LARGE SPILL CONSULT DOW
AGROSCIENCES (517)636-4400.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. DO NOT CONTAMINATE FOOD, FEED OR WATER BY STORAGE OR DISPOSAL.
EXCESS PESTICIDE RESULTING FROM THE USE OF THIS PRODUCT MAY BE DISPOS ED OF
ON SITE ACCORDING TO LABEL DIRECTIONS OR AT AN APPROVED WASTE DISPOSAL
FACITITY.
Handling And Storage Precautions: SEE LABEL. STORE AWAY FROM INCOMPATIBLES,
FOOD & FEED. PREVENT CROSS-CONTAMINATION WITH OTHER PESTICIDES OR
FERTILIZERS. KEEP OUT OF REACH OF CHILDREN. DO NOT SWALLOW. HANDLE
CONCENTRATE IN VENTILATED AREA.
Other Precautions: AVOID CONTACT WITH EYES AND SKIN AND CLOTHING. AVOID
BREATHING VAPORS OR MISTS. WASH THOROUGHLY AFTER HANDLING MATERIAL AND BEFORE
EATING, CHEWING GUM, USING TOBACCO, USING THE TOILET OR SMOKING.KEEP AWAY
FROM FOOD, FEEDSTUFFS, AND WATER SUPPLIES.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point: =115.C, 239.F
Lower Limits: N/D
Upper Limits: N/D
Extinguishing Media: FOAM, CARBON DIOXIDE (CO2), DRY CHEMICAL. FOAM IS
PREFERRED AS UNCONTROLLED WATER CAN SPREAD POSSIBLE CONTAMINATION.
Fire Fighting Procedures: FOAM IS PREFERRED AS UNCONTROLLED WATER CAN SPREAD
POSSIBLE CONTAMINATION.FIRE FIGHTERS SHOULD USE POSITIVE-PRESURE., SELF
CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard: TOXIC, IRRITATING GASES MAY BE FORMED UNDER FIRE
CONDITIONS.
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Control Measures
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Respiratory Protection: ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE
EXPOSURE GUIDELINES. WHEN RESPIRATORY PROTECTION IS REQUIRED, USE AN
APPROVED AIR-PURIFYING OR POSITIVE-PRESSURE SUPPLIED-AIR RESPIRATOR DEPENDING
ON THE POTENTIAL AIRBORNE CONCENTRATION.
Ventilation: PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Protective Gloves: NO PRECAUTIONS OTHER THAN CLEAN BODY-COVERING SHOULD BE
NEEDED.
Eye Protection: WEAR EYE PROTECTION, SUCH AS SAFETY GLASSES.
Other Protective Equipment: NO PRECAUTIONS OTHER THAN CLEAN BODY-COVERING
SHOULD BE NEEDED.
Work Hygienic Practices: WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND
BEFORE EATING OR SMOKING. KEEP AWAY FROM FOODSTUFFS AND WATER SUPPLIES.
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Physical/Chemical Properties
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HCC: T5
NRC/State LIC No: NONE
B.P. Text: NOT DETERMINED
M.P/F.P Text: NOT DETERMINED
Vapor Pres: NOT DETERMINED
Vapor Density: N/D
Spec Gravity: 1.0271G/ML
PH: 4.52
Solubility in Water: EMULSIFIABLE
Appearance and Odor: LIGHT YELLOW, CLOUDY LIQUID; PETROLEUM ODOR
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: AVOID HEATING >122F (50C). CHLORPYRIFOS
DECOMPOSES EXOTHERMICALLY AT 266F WHICH CAN LEAD TO HIGHER TEMPERATURES AND
VIOLENT DECOMPOSITION IF GENERATED HEAT IS NOT REMOVED..
Materials To Avoid: OXIDIZING MATERIALS, STRONG ACIDS. WITH ORGANIC MATERIAL
AND FINELY DIVIDED INORGANICS, PRODUCT MAY UNDERGO SPONTANEOUS COMBUSTION.
Hazardous Decomposition Products: HYDROGEN CHLORIDE, NITROGEN OXIDES AND OTHER
TOXIC, IRRITATING VAPORS MAY BE FORMED IF PRODUCT IS INVOLVED IN FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: TERATOLOGY (BIRTH DEFECTS): CHLOPYRIFOS DID NOT
CAUSE BIRTH DEFECTS IN LABORATORY ANIMALS. REPRODUCTIVE EFFECTS:CHLORPYRIFOS
DID NOT INTERFERE WITH FERTILITY IN REPRODUCTIVE STUDIES IN LABORATORY ANIM
ALS.SOME EVIDENCE OF TOXICITY TO THE OFFSPRING OCCURRED BUT ONLY AT DOSES
HIGH ENOUGH TO PRODUCE SIGNIFIGANT TOXICITY IN THE PARENT ANIMALS.FOR
DETAILED TOXICOLOGICAL DATA,WRITE THE ADDRESS IN 1ST SEC TION OR CALL THE
EMERGENCY NUMBER SHOWN.MUTAGENICITY:BASED ON A MAJORITY OF NEGATIVE DATA
& SOME EQUIVOCAL OR MARGINALLY POSITIVE RESULTS,CHLORPYRIFOS IS
CONSIDERED TO HAVE MINIMAL MUTAGENIC POTENTIAL .
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Ecological Information
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Ecological: FOR DETAILED ECOLOGICAL DATA, WRITE THE ADDRESS IN THE 1ST SECTION
OR CALL THE EMERGENCY NUMBER SHOWN. TOXIC TO FISH, AQUATIC ORGANISMS, BEES
AND AVIAN.
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MSDS Transport Information
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Transport Information: FOR DOT REGULATORY INFORMATION, IF REQUIRED, CONSULT
TRANSPORTATION REGULATIONS, PRODUCT SHIPPING PAPERS OR CONTACT YOUR DOW
AGROSCIENCES REPRESENTATIVE,
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Regulatory Information
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Sara Title III Information: SARA 313 INFORMATION: TO THE BEST OF OUR KNOWLEDGE,
THE PRODUCT CONTAINS NO CHEMICAL SUBJECT TO TO SARA TITLE III SECTION 313
SUPPLIER NOTIFICATION REQUIREMENTS.SARA SECTION 311/312 HAZARD CATEGORY: I
MMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD.
Federal Regulatory Information: TOXIC SUBSTANCES CONTROL ACT (TSCA): ALL
INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE LISTED ON THE
TSCA INVENTORY. OSHA HAZARD COMMUNICATION STANDARD: THIS PRODUCT IS A
"HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD COMMUNICATION STANDARD,
29 CFR 1910.1200. COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT (CERCLA OR SUPERFUND): THIS PRODUCT CONTAINS THE F OLLOWING
SUBSTANCE(S) LISTED AS "HAZARDOUS SUBSTANCES" UNDER CERCLA WHICH MAY REQUIRE
REPORTING OF R ELEASES: CHLORPYRIFOS, CAS# 2921-88-2, RQ=1 LB, 23.5%.
State Regulatory Information: THE FOLLOWING PRODUCT COMPONENTS ARE CITED ON
CERTAIN STATE LISTS AS MENTIONED. NON-LISTED COMPONENTS MAY BE SHOWN IN THE
COMPOSITION SECTION OF THE MSDS: 1,2-PROPANEDIOL, CAS# 57-55-6, PENNSYLVANIA
H AZARDOUS SUBSTANCE (PRESENT AT GREATER THAN OR EQUAL TO 0.1%);
CHLORPYRIFOS, CAS# 2921-88-2, PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT
GREATER THAN OR EQUAL TO 0.1%); PENNSYLVANIA HAZARDOUS SUBSTAN CE (PRESENT AT
GREATER THAN OR EQUAL TO 1.0%); NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE
(PRESENT AT GREATER THAN OR EQUAL TO 1.0%).
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Other Information
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Other Information: EPA REGISTRATION NUMBER 62719-166.
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Transportation Information
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Trans ID NO: 153053
MSDS NAME: DURSBAN PRO INSECTICIDE; PRODUCT CODE: 46482
MSDS Prepared Date: 01/01/1996
Review Date: 05/18/2000
Net Unit Weight: 1 LB
Multiple KIT Number: 0
Unit Of Issue: PT
Container QTY: 0
Type Of Container: BOTTLE,SQUEEZ
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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