RHONE-POULENC AG CO -- WEEDAR BRAND 64 HERBICIDE
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Material Safety Data Sheet
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NIIN: 00-664-7060
MSDS Num: CKMMF
MSDS NAME: WEEDAR BRAND 64 HERBICIDE
Responsible Party
Name: RHONE-POULENC AG CO
Address: 2 T W ALEXANDER DR
Box: 12014
City: RESEARCH TRIANGLE PARK NC 27709
Info Phone: 800-334-9745/800-424-9300(CHEMTREC)
Emergency Phone Number: 800-424-9300/703-527-3887
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Item Description Information
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Item Manager: S9G
Item Name: HERBICIDE,2,4-DICHLOROPHENOXYACETIC ACID
Specification Number: A-A-197
Type/Grade/Class: TYPE II
Unit of Issue: BX
Quantitative Expression: 00000000002EA
UI Container Qty: 1
Type of Container: CONTAINER
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: 1161 MG/KG, ORAL-RAT
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE EYE: CAUSES CORNEAL OPACITY, IRREVERSIBLE EYE
DAMAGE. VAPORS AND MISTS CAN CAUSE IRRITATION. SKIN: MAY CAUSE SLIGHT
TRANSIENT IRRITATION. TOXIC IF ABSORBED THROUGH THE SKIN, MAY PRODUCE
SYMPTOMS SIMILAR TO THOSE FROM INHALATION AND INGESTION. MAY CAUSE DECREASED
BLOOD PRESSURE, MUSCLE WEAKNESS, MUSCLE SPASMS. INHALATION: HARMFUL IF
INHALED. MAY CAUSE UPPER RESPIRATORY TRACT IRRITATION, NAUSE A, DECREASED
BLOOD PRESSSURE, MUSCLE WEAKNESS, MUSCLE SPASMS. INGESTION: HARMFUL IF
INGESTED. MAY CAUSE NAUSEA, VOMITING, ABDOMINAL PAIN, DECREASED BLOOD
PRESSURE, MUSCLE WEAKNESS, MUSCLE SPASMS.
Explanation Of Carcinogenicity: PRODUCT CONTAINS INGREDIENTS CONSIDERED
PROBABLE/SUSPECTED HUMAN CARCINOGENS. IARC 2B. EPA CLASS D, NOT
CLASSIFICABLE AS TO HUMAN CARCINOGENITY. REQUIRES ADDITIONAL TESTS. VARIOUS
ANIMAL TESTS SHOW N O POSITIVE ASSOCIATION BETWEEN 2,4-D EXPOSURE &
CANCER. RECENT RESULTS FROM LIFETIME STUDY IN LAB ANIMALS DO NOT SHOW
EVIDENCE OF CARCINOGENIC EFFECTS BY 2,4-D.
Signs And Symptions Of Overexposure: ACUTE EYE: CAUSES CORNEAL OPACITY,
IRREVERSIBLE EYE DAMAGE. VAPORS AND MISTS CAN CAUSE IRRITATION. SKIN: MAY
CAUSE SLIGHT TRANSIENT IRRITATION. TOXIC IF ABSORBED THROUGH THE SKIN, MAY
PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INHALATION AND INGESTION. MAY CAUSE
DECREASED BLOOD PRESSURE, MUSCLE WEAKNESS, MUSCLE SPASMS. INHALATION: HARMFUL
IF INHALED. MAY CAUSE UPPER RESPIRATORY TRACT IRRITATION, NAUSE A, DECREASED
BLOOD PRESSSURE, MUSCLE WEAKNESS, MUSCLE SPASMS. INGESTION: HARMFUL IF
INGGESTED. MAY CAUSE NAUSEA, VOMITING, ABDOMINAL PAIN, DECREASED BLOOD
PRESSURE, MUSCLE WEAKNESS, MUSCLE SPASMS.
Medical Cond Aggravated By Exposure: INHALATION OF THIS PRODUCT MAY AGGRAVATE
EXISTING CHRONIC RESPIRATORY PROBLEMS SUCH AS ASTHMA OR BRONCHITIS. SKIN
CONTACT MAY AGGRAVATE EXISTING SKIN DISEASE.
First Aid: EYE: HOLD EYELIDS OPEN & FLUSH WITH STEADY, GENTLE STREAM OF
WATER FOR AT LEAST 15 MIN. GET IMMEDIATE MEDICAL HELP. SKIN: IMMEDIATELY WASH
WITH PLENTY SOAP & WATER FOR AT LEAST 15 MIN. GET MEDICAL HEL P. REMOVE
CONTAMINATED CLOTHING & SHOES BEFORE RE-USE. DISCARD IF CANNOT BE
CLEANED. INHALATION: MOVE FROM EXPOSURE. ASSURE VICTIM IS BREATHING. IF
BREATHING DIFFICULT, GIVE OXYGEN, IF AVAILABLE. IF N OT BREATHING, GIVE CPR.
GET MEDICAL HELP. INGESTION: GIVE 2-3 GLASSES WATER, INDUCE VOMITING IF
CONSCIOUS. PREVENT ASPIRATION INTO LUNGS BY LAYING ON SIDE WITH HEAD LOWER
THAN WAIST. IF UNCONSCIOUS, D ON'T INDUCE VOMITING.
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Handling and Disposal
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Spill Release Procedures: DIKE SPILL USING ABSORBENT OR IMPERVIOUS MATERIALS
SUCH AS EARTH, SAND OR CLAY. COLLECT AND CONTAIN CONTAMINATED ABSORBENT AND
DIKE MATERIAL FOR DISPOSAL. PUMP ANY FREE LIQUID INTO APPROPRIATE CONTAIN ER.
COLLECT WASHINGS FOR DISPOSAL. DECONTAMINATE TOOLS AND EQUIPMENT FOLLOWING
CLEANUP.
Neutralizing Agent: NOT PROVIDED
Waste Disposal Methods: CHEMICAL ADDITIONS, PROCESSING OR OTHERWISE ALTERING
MATERIAL MAY MAKE INFORMATION PRESENTED IN MSDS INCOMPLETE, INACCURATE OR
OTHERWISE INAPPROPRIATE. STATE & LOCAL REQUIREMENTS FOR WASTE DISPOSAL MA
Y BE MORE RESTRICTIVE OR OTHERWISE DIFFERENT FROM FEDERAL LAWS &
REGULATIONS REGARDING PROPER DISPO SAL OF THIS MATERIAL.
Handling And Storage Precautions: DO NOT BREATHE VAPORS AND MISTS. DO NOT GET
ON SKIN OR IN EYES. DO NOT INGEST. STORE IN AN AREA THAT IS AWAY FROM FOOD,
FEEDSTUFFS, FERTILIZERS AND SEED.
Other Precautions: NOT PROVIDED
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: >100.C, 212.F
Extinguishing Media: RECOMMEND (SMALL FIRES): DRY CHEMICAL, CARBON DIOXIDE.
RECOMMEND (LARGE FIRES): FOAM, WATER SPRAY.
Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. DIKE AREA TO
PREVENT RUNOFF AND CONTAMINATION OF WATER SOURCE. DISPOSE OF FIRE CONTROL WAT
ER LATER.
Unusual Fire/Explosion Hazard: UNDER FIRE CONDITIONS, TOXIC, CORROSIVE FUMES
ARE EMITTED.
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Control Measures
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Respiratory Protection: WHEN RESPIRATORS ARE REQUIRED, SELECT NIOSH/MSHA
APPROVED EQUIPMENT BASED ON ACTUAL OR POTENTIAL AIRBORNE CONCENTRATIONS AND
IN ACCORDANCE WITH THE APPROPRIATE REGULATORY STANDARDS AND/OR INDUSTRIAL R
ECOMMENDATIONS.
Ventilation: LOCAL EXHAUST VENTILATION AT THE POINT OF GENERATION.
Protective Gloves: RESISTANT GLOVES
Eye Protection: CHEMICAL SAFETY GLASSES WITH SIDE SHIELDS OR SPLASH PROOF
GOGGLES
Other Protective Equipment: PERMEATION RESISTANT CLOTHING, GLOVES AND FOOTWEAR,
SELECTED WITH REGARD FOR USE CONDITIONS AND EXPOSURE POTENTIAL. AN EMERGENCY
SHOWER.
Work Hygienic Practices: DO NOT STORE/USE FOOD, BEVERAGES, TOBACCO, COSMETICS
IN AREA. WASH HANDS, FACE BEFORE EATING, DRINKING, SMOKING, APPLYING
COSMETICS OR USING TOILET. WASH EXPOSED SKIN PROMPTLY TO REMOVE SPLASHES.
Supplemental Safety and Health: HCC OF V5 CHOSEN OVER T5 AS PER TABLE B-3 OF
JOINT SERVICE DOCUMENT "STORAGE AND HANDLING OF HAZARDOUS MATERIALS".
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Physical/Chemical Properties
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HCC: V5
B.P. Text: NOT AVAILABLE
Melt/Freeze Pt: =-6.C, 21.2F
Spec Gravity: 1.1589
PH: 4.81
Solubility in Water: SOLUBLE
Appearance and Odor: REDDISH BROWN LIQUID; CHARACTERISTIC ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES
Materials To Avoid: STRONG ACIDS; STRONG OXIDIZING AGENTS
Hazardous Decomposition Products: HYDROGEN CHLORIDE, OXIDES OF NITROGEN; OXIDES
OF CARBON
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: EYE-SEVERELY IRRITATING TO RABBIT. SKIN-MINIMALLY
IRRITATING TO RABBIT. DERMAL TOXICITY: LD50-1544 MG/KG, RABBIT. ACUTE
INHALATION TOXICITY: >2.06 MG/L/4 HR, RAT.
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Ecological Information
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Ecological: LC50-MALLARD DUCK: >5620 MG/KG/8 DAYS. LC50-BOBWHITE QUAIL: 500
MG/KG/8 DAYS., EC50-DAPHNIA MAGNA: 184 MG/L/48 HR, LC50-RAINBOW TROUT: 240
MG/L/96 HR, LC50-BLUE SUNFISH: 524 MG/L/96 HR. FOR CHEMICAL F ATE DATA CALL
800-334-9745
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MSDS Transport Information
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Transport Information: FOR TRANSPORTATION INFORMATION CALL 800-334-9745
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Regulatory Information
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Sara Title III Information: SARA HAZARD CLASSES: ACUTE HEALTH, CHRONIC HEALTH
Federal Regulatory Information: EXCLUDED FROM TSCA BECAUSE IT IS SOLELY FOR
FIFRA USE.
State Regulatory Information: DOES NOT CONTAIN ANY COMPONENTS REGULATED UNDER
CALIFORNIA PROPOSITION 65.
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Other Information
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Transportation Information
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Trans ID NO: 153201
MSDS NAME: WEEDAR BRAND 64 HERBICIDE
MSDS Prepared Date: 11/13/1998
Review Date: 05/25/2000
Multiple KIT Number: 0
Unit Of Issue: BX
Container QTY: 1
Type Of Container: CONTAINER
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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