UNION CARBIDE CORP INDUSTRIAL -- AMINOETHYLPIPERAZINE
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Material Safety Data Sheet
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MSDS Num: CKZQH
MSDS NAME: AMINOETHYLPIPERAZINE
Responsible Party
Name: UNION CARBIDE CORP INDUSTRIAL
Address: 39 OLD RIDGEBURY ROAD CHEMICALS DIV
City: DANBURY CT 06817-0001
Info Phone: 800-568-4000/732-563-5522
Emergency Phone Number: 304-744-3487;800-822-4357
Resp. Party Other MSDS No.: 000000000487
Published: Y
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Contractor Summary
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Name: UNION CARBIDE CORP
Address: 39 OLD RIDGEBURY ROAD
City: DANBURY CT 06817-0001
Phone: 800-822-4357/732-563-5522 (MSDS)
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Ingredients
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Cas: 140-31-8
RTECS #: TK8050000
Name: AMINOETHYLPIPERAZINE
% low Wt: 96.5
% high Wt: 99.5
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Cas: 111-40-0
RTECS #: IE1225000
Name: DIETHYLENETRIAMINE
% low Wt: .1
% high Wt: 2.
Other REC Limits: ACGIH:SKIN-TLV/STEL
OSHA PEL: 4 MG/M3; 1 PPM
ACGIH TLV: 4.2 MG/M3;1 PPM
ACGIH STEL: NOT ESTABLISHED
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Cas: 111-41-1
RTECS #: KJ6300000
Name: N-(HYDROXYETHYL)ETHYLENEDIAMINE
< Wt: 1.
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: DANGER! MAY CAUSE ASTHMA WITH POSSIBLE LONG-TERM LUNG
DAMAGE. CROSS-SENSITIZATION TO OTHER AMINES MAY OCCUR. CAUSES EYE & SKIN
BURNS. HARMFUL & CORROSIVE IF SWALLOWED. HARMFUL IF INHALED/ABSORBED THRU
SKIN. MAY CAUSE ALLERGIC SKIN REACTION. ASPIRATION MAY CAUSE LUNG DAMAGE.
MAY CAUSE RESPIRATORY SYSTEM DAMAGE. POTENTIAL HEALTH EFFECTS: EFFECTS OF
SINGLE ACUTE OVEREXPOSURE: INHALATION: VAPOR IRRITA TING & MAY CAUSE
EXCESSIVE TEAR FORMATION, BURNING SENSATION OF NOSE/THROAT, COUGHING,
WHEEZING, SHORTNESS OF BREATH, NAUSEA & VOMITING. EXTREMELY HIGH VAPOR
CONCENTRATIONS MAY CAUSE LUNG DAMAGE. SOME MAY DEVELOP ASTHMA.
(OVEREXPOSURE)
Signs And Symptions Of Overexposure: ACUTE/CHRONIC (CONT'D):EYES: CAUSES
CORNEAL INJURY & IRITIS. CAUSES SEVERE IRRIT, EXPERIENCED AS
DISCOMFORT/PAIN, EXCESS BLINKING/TEARING, MARKED EXCESS REDNESS &
SWELLING OF CONJUNCTIVA & CHEMICAL BU RNS OF EYE. CORNEAL INJURY MAY BE
SEVERE, EXTENSIVE; IF NOT TREATED PROMPTLY, COULD RESULT IN PERMANENT VISION
IMPAIRMENT. SKIN: CAUSES CHEMICAL BURNS W/DISCOMFORT/PAIN, SEVERE EXCESS
REDNESS/ SWELLIN G, TISSUE DESTRUCTION, FISSURES, ULCERATION, POSSIBLE
BLEEDING INTO INFLAMED AREA. SKIN ABSORPTION: PROLONGED/WIDESPREAD CONTACT
MAY RESULT IN ABSORPTION OF POTENTIALLY HARMFUL AMOUNTS OF MATERIAL. IN
GESTION: MODERATELY TOXIC. (OTHER INFO)
Medical Cond Aggravated By Exposure: SKIN CONTACT MAY AGGRAVATE AN EXISTING
DERMATITIS. INHALATION OF MATERIAL MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR
FIBROTIC PULMONARY DISEASE.
First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE ARTF RESP IF NOT BREATHING. IF
BREATHING DIFFICULT, OXYGEN MAY BE GIVEN BY QUALIFIED PERSONNEL. OBTAIN
MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH W/WATER; CONTINU E WASHING FOR AT
LEAST 15 MIN. DO NOT REMOVE CONTACT LENSES, IF WORN. OBTAIN MED ATTN WITHOUT
DELAY, PREFERABLY FROM AN OPHTHALMOLOGIST. SKIN: IMMED FLUSH W/WATER FOR AT
LEAST 15 MIN. WHILE REMOVING C ONTAM CLOTHING/SHOES. OBTAIN MED ATTN W/OUT
DELAY. WASH CLOTHING BEFORE REUSE. DISCARD CONTAM LEATHER ARTICLES SUCH AS
SHOES/BELTS. INGESTION: IF CONSCIOUS, GIVE 2 GLASSES WATER/MILK. DO NOT
INDUCE V OMITING. OBTAIN MED ATTN WITHOUT DELAY.
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Handling and Disposal
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Spill Release Procedures: SMALL SPILLS-FLUSH WITH LARGE AMOUNTS WATER. LARGER
SPILLS-COLLECT FOR DISPOSAL. WEAR SUITABLE PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH LIQUID AND VAPORS. ENVIRONMENTAL PRECAUTIONS: SPILLS-LARGE SPILL
COULD BE TOXIC TO AQUATIC LIFE; AVOID DISCHARGE TO NATURAL WATERS. AVOID
DISCHARGE OF LARGE SPILLS TO SEWERS AND WATERWAYS.
Neutralizing Agent: N/P. NOTES TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE.
DIRECT TREATMENT TO CONTROL SYPT & CLINICAL CONDITION.
Waste Disposal Methods: INCINERATE IN FURNACE WHERE PERMITTED UNDER FEDERAL,
STATE & LOCAL REGULATIONS. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, PROVINCIAL & LOCAL ENVIRONMENTAL REGULATIONS. EMPTY
CONTAIN ERS SHOULD BE RECYCLED OR DISPOSED OF THRU APPROVED WASTE MANAGEMENT
FACILITY. DISPOSAL METHODS ARE FOR PRODUCT AS SOLD.
Handling And Storage Precautions: DO NOT SWALLOW, BREATHE VAPOR, GET IN EYES,
ON SKIN, ON CLOTHING. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION.
WASH THOROUGHLY AFTER HANDLING. STORAGE: NO INFORMATION CURRENTLY AVAILABLE.
Other Precautions: DO NOT ADD NITRITES OR OTHER NITROSATING AGENTS. A
NITROSAMINE, WHICH MAY CAUSE CANCER, MAY BE FORMED. CONTACT NEHC FOR
ADDITIONAL INFORMATION (FP N).
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Fire and Explosion Hazard Information
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Flash Point Method: PMCC
Flash Point: =101.7C, 215.F
Flash Point Text: COC-250F; 121.1C
Autoignition Temp Text: N /AV
Lower Limits: NOT DETERMIN
Upper Limits: NOT DETERMIN
Extinguishing Media: APPLY ALCOHOL-TYPE/ALL PURPOSE-TYPE FOAM BY MANUFACTURER'S
RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE CARBON DIOXIDE/DRY CHEMICAL MEDIA
FOR SMALL FIRES. (FIREFIGHT PROC)
Fire Fighting Procedures: DO NOT DIRECT SOLID STREAM OF WATER/FOAM INTO BURNING
MOLTEN MATL; THIS MAY CAUSE SPARKING & SPREAD FIRE. FIREFIGHTERS SHOULD
USE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS, EYE PROTECTION &
PR OTECTIVE CLOTHING. EXTING MEDIA (CONT'D): EXTINGUISHING MEDIA TO AVOID: NO
INFORMATION CURRENTLY AVAILABLE.
Unusual Fire/Explosion Hazard: DURING FIRE, OXIDES OF NITROGEN MAY BE EVOLVED.
HAZARDOUS COMBUSTION PRODUCTS: BURNING CAN PRODUCE: OXIDES OF CARBON &
NITROGEN. CARBON MONOXIDE IS HIGHLY TOXIC IF INHALED; CARBON DIOXIDE IN
SUFFICIEN T CONCENTRATIONS CAN ACT AS ASPHYXIANTS. ACUTE OVEREXPOSURE MAY
RESULT IN IRRITATION OF RESPIRATORY TRACT.
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Control Measures
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Respiratory Protection: NIOSH-APPROVED POSITIVE PRESSURE SUPPLIED-AIR
RESPIRATOR EQUIPPED WITH FULL FACEPIECE SHOULD BE USED DURING ANY OPERATION
WHERE THERE IS POTENTIAL FOR RELEASE OF PRODUCT INTO WORKPLACE AIR.
VENTILATIO N (CONT'D): VAPORS MAY BE EXPECTED TO ESCAPE TO WORKPLACE AIR.
Ventilation: GENERAL (MECHANICAL) ROOM VENT SATISFACTORY WHERE PRODUCT
STORED/HANDLED IN CLOSED EQUIPMENT. SPECIAL, LOCAL VENT NEEDED AT POINTS
WHERE (RESP PROTECTION)
Protective Gloves: BUTYL.
Eye Protection: ANSI-APPROVED CHEMICAL SAFETY GOGGLES & FULL (OTHER PROTECTIVE
EQUIPMENT)
Other Protective Equipment: EYEBATH, SAFETY SHOWER MEETING ANSI DESIGN CRITERIA
(FP N). CHEMICAL APRON. EYE PROTECTION (CONT'D): FACE SHIELD (FP N).
MONOGOGGLES (MFR).
Work Hygienic Practices: PROCESS HAZARD: SUDDEN RELEASE OF HOT ORGANIC CHEMICAL
VAPORS/MISTS FROM PROCESS EQUIP OPERATING AT ELEVATED TEMPS/PRESSURE; OR
SUDDEN INGRESS OF AIR INTO HOT EQUIP UNDER A VACUUM, MAY RESULT IN IGNTION
Supplemental Safety and Health: W/OUT PRESENCE OF OBVIOUS IGNIT SOURCES.
PUBLISHED AUTOIGNITION/IGNITION TEMP VALUES CANNOT BE TREATED AS SAFE
OPERATING TEMPS IN CHEMICAL PROCESSES W/OUT ANALYSIS OF ACUTAL PROCESS
CONDITIONS. ANY US E OF PRODUCT IN ELEVATED TEMP PROCESSES SHOULD BE
EVALUATED THOROUGHLY TO ESTABLISH/MAINTAIN SAFE OPERATING CONDITIONS.
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Physical/Chemical Properties
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Boiling Point: =220.6C, 429.F
Melt/Freeze Pt: =-59.C, -74.2F
M.P/F.P Text: MELTING POINT: NOT APPLIC
Vapor Pres: @20C: 0.001 KPA/0.009MMHG
Vapor Density: 4.46
Spec Gravity: (H20=1): 0.986 20C/20C
PH: NOT AVAILABLE
Solubility in Water: 20C; 100%
Appearance and Odor: TRANSPARENT COLORLESS LIQUID; AMINE ODOR.
Percent Volatiles by Volume: 100%
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Reactivity Data
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Stability Indicator: YES USE CANCER.
Stability Condition To Avoid: SOME DECOMPOSITION CAN OCCUR UPON VIGOROUS
HEATING; E.G., APPLICATION OF HIGH-PRESSURE STEAM OR FLAME. (MATERIALS TO
AVOID)
Materials To Avoid: ACIDS, OXIDIZING AGENTS, ALDEHYDES, KETONES, EPOXIDES,
ACRYLATES, ORGANICE HALIDES. STABILITY CONDITIONS TO AVOID (CONT'D): DO NOT
MIX W/NITRITES OR OTHER NITROSATING AGENTS. A NITROSAMINE MAY BE FORMED.
NITROSAMINES MAY C
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMANS:
REPEATED ORAL EXPOSURES MAY CAUSE KIDNEY/LIVER CHANGES. EVIDENCE OF WEAK
MUTAGENIC ACTIVITY HAS BEEN OBTAINED IN VITRO ASSAY SYSTEMS. MATERIALS OF C
LOSELY RELATED CHEMICAL STRUCTURE DO NOT EXHIBIT CARCINGENIC POTENTIAL IN
LIFE-TIME MOUSE SKIN PAINTING STUDIES. THE RELEVANCE OF FINDINGS TO HUMANS
UNKNOWN. CONTAINS 1 OR MORE AMINES WHICH MAY REACT WITH NITRITES TO FORM
NITROSAMINES. SOME NITROSAMINES HAVE BEEN SHOWN TO BE CARCINOGENIC IN
LABORATORY ANIMALS.
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Ecological Information
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Ecological: ENVIRONMENTAL FATE, ECOTOXICITY: PARTIAL INFO MAY BE AVAILABLE,
CALL UNION CARBIDE. FURTHER INFO: NONE. EFFECTS OF REPEATED OVEREXPOSURE:
REPEATED VAPOR EXPOSURE MAY CAUSE INJURY TO RESPIRATORY TRACT . OTHER
EFFECTS: INHALATION OF ETHYLENEAMINES MAY CAUSE INJURY TO RESP TRACT AND
DEVELOPMENT OF ASTHMATIC REACTIONS ON FURTHER EXPOSURE. SUSCEPTIBLE PERSONS
MAY DEVELOP LONG-TERM HYPERACTIVE AIRWAYS, ASTHMA AND OTHER RESPIRATORY
INJURY AFTER EXPOSURE TO EXTREMELY LOW CONCENTRATIONS OF ETHYLENEAMINES, EVEN
BELOW IRRITATION THRESHOLD. (TRANSPORT)
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MSDS Transport Information
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Transport Information: U.S. D.O.T.: NON-BULK AND BULK: PROPER SHIPPING NAME:
N-AMINOETHYLPIPERAZINE. ID NUMBER: UN2815. HAZARD CLASS: 8. PACKING GROUP:
III. ECOLOGICAL INFO (CONT'D): OTHER RESP IRRIT MAY PRODUCE REACTION IN
PERSONS WHOSE AIRWAYS HAVE BECOME HYPERREACTIVE. SUGGEST PEOPLE WITH ASTHMA
OR OTHER LONGSTANDING RESP CONDITIONS (EMPHYSEMA, BRONCHITIS) SHOULD BE
PROTECTED FROM POTENTIAL EXPOSURE TO ETHYLENEAMINES . SKIN CONTACT MAY CAUSE
SENSITIZATION OR ALLERGIC SKIN REACTION. CROSS-SENSITIZATION MAY OCCUR BY
CONTACT WITH MATERIAL OR OTHER AMINES.
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Regulatory Information
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Sara Title III Information: SECTIONS 302/304: FOLLOWING COMPONENTS OF PRODUCT
ARE LISTED AS EXTREMELY HAZARDOUS SUBSTANCES IN 40 CFR PART 355 & ARE
PRESENT AT LEVELS WHICH COULD REQUIRE REPORTING & EMERGENCY PLANNING:
NONE. SECT ION 313: FOLLOWING COMPONENTS LISTED AS TOXIC CHEMICALS IN 40 CFR
372.65 & ARE PRESENT AT LEVELS WHICH COULD REQUIRE REPORTING &
CUSTOMER NOTIFICATION UNDER SEC 313 & 40 CFR PART 372: PRODUCT DOES NOT
CONTAIN TOXIC CHEMICALS AT LEVELS WHICH REQUIRE REPORTING UNDER STATUTE.
SECTIONS 311/312: DELAYED HAZARD: YES. FIRE HAZARD: NO. IMMEDIATE HEALTH HAZ:
YES. REACTIVE HAZARD: NO. SUDDEN RELEASE OF PRES SURE HAZARD: NO.
Federal Regulatory Information: CERCLA: FOLLOWING COMPONENTS OF PRODUCT ARE
SPECIFICALLY LISTED AS HAZARDOUS SUBSTANCES IN 40 CFR 302.4 & ARE PRESENT
AT LEVELS WHICH COULD REQUIRE REPORTING: NONE. TOXIC SUBSTANCES CONTROL ACT
(TSCA) : ALL COMPONENTS OF PRODUCT ARE ON TSCAINVENTORY OR ARE EXEMPT FROM
TSCA INVENTORY REQUIREMENTS. STATE REGULATORY INFORMATION (CONT'D):
CALIFORNIA SCAOMD RULE 443 (SOUTH COAST AIR QUALITY MGMT DISTRI CT RULE 443.1
LABELING OF MATERIALS CONTAINING ORGANIC SOLVENTS): VOC: 984.55 G/L VAPOR
PRESSURE 0.0 09 MMHG @20C.
State Regulatory Information: PENNSYLVANIA WORKER & COMMUNITY RIGHT-TO-KNOW
ACT: FOLLOWING COMPONENTS OF PRODUCT ARE AT LEVELS WHICH COULD REQ ID IN
MSDS: ALL 3 INGRED LISTED IN INGRED SECTION. MASSACHUSSETS HAZARDOUS
SUBSTANCE DI SCLOSURE-EMPLOYERS: FOLLOWING COMPONENTS APPEAR ON MA SUBSTANCE
LIST & ARE PRESENT AT LEVELS WHICH COULD REQUIRE IDENTIFICATION IN MSDS:
ALL 3 INGREDIENTS LISTED IN INGRED SECTION. CALIFORNIA PROPOSIT ION 65 (SAFE
DRINKING WATER & TOXIC ENFORCEMENT ACT OF 1986). PRODUCT CONTAINS NO
LISTED SUBSTANCES KNOWN TO STATE OF CA TO CAUSE CANCER, BIRTH DEFECTS OR
OTHER REPROD HARM, AT LEVELS WHICH WOULD REQUIRE A WARNING UNDER STATUTE.
(FED REG)
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Other Information
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Other Information:: HEALTH-2, FLAM-1, REACTIVITY-0, PERSONAL PROTECTION -X.
NFPA: HEALTH-3, FLAMM-1, REACTIVITY-1, PERS PROT-B. CHEMICAL NAME:
N-AMINOETHYLPIPERAZINE. CHEM FAMILY: ETHYLENEAMINES. COMMON NAME: AMINO
ETHYLPIPERAZINE. FORMULA: C6H15N3. SYNONYM: AEP, AEP-HP,
1-(2-AMINOETHYL)PIPERAZINE. OVEREXPOSURE (CONT'D): MAY CAUSE BURNS OF
MOUTH/THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA, DIZZINESS, WEAK
NESS, THIRST, COLLAPSE, POSSIBLE COMA. NATURE/SEVERITY OF SIGNS/SYMPT DEPEND
ON AMT SWALLOWED. ASPIRATION INTO LUNG MAY OCCUR DURING INGESTION OR
VOMITING, RESULTING IN LUNG INJURY. CONTACT NEHC FOR A DD'L INFO (FP N).
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HAZCOM Label
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MSDS NAME: AMINOETHYLPIPERAZINE
Company: UNION CARBIDE CORP
Street: 39 OLD RIDGEBURY ROAD
City: DANBURY CT
Zipcode: 06817-0001
Health Emergency Phone: 304-744-3487;800-822-4357
Label Required IND: Y
Date Of Label Review: 03/14/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: DANGER! CROSS-SENSITIZATION TO OTHER AMINES MAY OCCUR.
ACUTE: INHAL: MAY CAUSE IRRIT OF NOSE/THROAT, SHORTNESS OF BREATH &
VOMIT, LUNG DAMAGE, ASTHMA, LONG-TERM LUNG DAMAGE. EYES: CAUSES CORNEAL INJU
RY & IRITIS, SEV IRRIT, PAIN, SWELLING OF CONJUNCTIVA & CHEM BURNS,
POSS PERMANENT VISION IMPAIRMENT. SKIN: CAUSES CHEM BURNS, REDNESS/ SWELLING,
TISSUE DESTRUCTION, FISSURES, ULCERATION. SKIN ABSORPT ION: POSS ABSORPTION
OF HARMFUL AMTS. INGEST: MODERATE TOX. MAY CAUSE BURNS, ABDOMINAL PAIN,
NAUSEA, VOMITING, DIARRHEA, DIZZINESS, WEAKNESS, COLLAPSE, POSSIBLE COMA.
ASPIRATION MAY RESULTING IN LUNG INJURY. CHRONIC: SENSITIZATION (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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