HACH COMPANY -- BUFFER POWDER PILLOWS CITRATE TYPE FOR HEAVY
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CKZYC
MSDS NAME: BUFFER POWDER PILLOWS CITRATE TYPE FOR HEAVY METALS, 14202
Responsible Party
Name: HACH COMPANY
Box: 389
City: LOVELAND CO 80539
Info Phone: 970-669-3050
Emergency Phone Number: 303-623-5716/515-232-2533
Resp. Party Other MSDS No.: M00153
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: HACH CO
Address: 5600 LINDBERGH DR
Box: 389
City: LOVELAND CO 80539
Phone: 970-669-3050/ 303-623-5716
=======================================================
Ingredients
=======================================================
Cas: 77-92-9
RTECS #: GE7350000
Name: CITRIC ACID
% low Wt: 65.
% high Wt: 75.
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NONE ESTABLISHED
------------------------------
Cas: 10034-93-2
RTECS #: MV9625000
Name: HYDRAZINE SULFATE
% low Wt: 10.
% high Wt: 20.
OSHA PEL: 0.1 PPM AS N2H4
ACGIH TLV: 0.1 PPM AS N2H4
------------------------------
Cas: 68-04-2
RTECS #: GE8300000
Name: SODIUM CITRATE
% low Wt: 10.
% high Wt: 20.
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: CAS# 10034-93-2: LD50 ORAL RAT=601 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: NO
OSHA: NO
Effects of Exposure: CITRIC ACID: HAZARD: CAUSES SEVERE EYE IRRITATION.
HYDRAZINE SULFATE: HAZARD: CAUSES IRRITATION. EXPERIMENTAL CARCINOGEN. MAY
CAUSE ALLERGIC REACTION. SODIUM CITRATE: HAZARD: MAY CAUSE IRRITATION. HAR
MFUL IF SWALLOWED, INHALED, ABSORBED THROUGH SKIN. CAUSES EYE, SKIN AND
RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. CONTAINS
MATERIAL WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA. E YE CONTACT: CAUSES
IRRITATION. SKIN CONTACT: CAUSES IRRITATION. MAY CAUSE ALLERGIC REACTION.
SKIN ABSORPTION: HARMFUL IF ABSORBED THROUGH SKIN. (OVEREXPOSURE)
Explanation Of Carcinogenicity: THIS PRODUCT DOES NOT CONTAIN ANY OSHA LISTED
CARCINOGENS. HYDRAZINE SULFATE: NTP REASONABLY ANTICIPATED TO BE HUMAN
CARCINOGEN, NTP NINTH REPORT ON CARCINOGENS.
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE/CHRONIC
(CONT'D):TARGET ORGANS: CENTRAL NERVOUS SYSTEM. INGESTION: TOXIC. MAY CAUSE:
GASTROINTESTINAL DISTURBANCES, CENTRAL NERVOUS SYSTEM EFFECTS. TARGET ORGANS:
CENTRAL NERVOUS SYSTEM. INHALATION: CAUSES RESPIRATORY TRACT IRRITATION. MAY
CAUSE: CENTRAL NERVOUS SYSTEM EFFECTS TARGET ORGANS: CENTRAL NERVOUS SYSTEM.
CHRONIC EFFECTS: CITRIC ACID CHRONIC OVEREXPOS MAY CAUSE EFFEC TS DUE TO
ABILITY OF CITRIC ACID TO CHELATE METALS, WHICH COULD IMPAIR BODY'S ABILITY
TO ABSORB CALCIUM & IRON. CHRONIC OVEREXPOS MAY CAUSE CANCER, LIVER
DAMAGE, ADVERSE EFFECTS TO THE BLOOD & LUNG OR KIDNEY DAMAGE.
Medical Cond Aggravated By Exposure: PRE-EXISTING: EYE CONDITIONS, SKIN
CONDITIONS, RESPIRATORY CONDITIONS. CENTRAL NERVOUS SYSTEM DISEASES. LIVER
CONDITIONS, KIDNEY CONDITIONS.
First Aid: EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. CALL
PHYSICIAN. SKIN CONTACT: WASH SKIN WITH PLENTY OF WATER FOR 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. CALL PHYSICIAN IMMEDIATELY. IN GESTION: INDUCE
VOMITING USING SYRUP OF IPECAC OR BY STICKING FINGER DOWN THROAT. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN IMMEDIATELY.
INHALATION: REMOVE TO FRESH AIR. GI VE ARTIFICIAL RESPIRATION, IF NECESSARY.
CALL PHYSICIAN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: ONLY PERSONS QUALIFIED TO RESPOND TO EMERGENCY
INVOLVING HAZARDOUS SUBSTANCES MAY RESPOND IAW OSHA 29 CFR 1910.1200 (A)(V)
& PER YOUR COMPANY'S EMERGENCY RESPONSE PLAN & GUIDELINE/PROCEDURES.
STOP SP ILLED MATL FROM BEING RELEASED TO ENVIRONMENT. SCOOP UP SPILLED MATL
INTO LARGE BEAKER & DISSOLVE WITH WATER. WORK IN APPROVED FUME HOOD.
ADJUST TO PH 6-9 WITH AN ALKALI, (OTHER INFORMATION)
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS (FP N). EPA WASTE ID#: NONE. INCINERATE
MATERIAL AT AN EPA APPROVED HAZARDOUS WASTE FACILITY. EMPTY CONTAINERS: RINSE
3 TIMES WITH AN APPROPRIATE SOLVENT. DISPOSE OF EMPTY CONTAINER AS NORMAL
TRASH. THESE DISPOSAL GUID ELINES BASED ON FEDERAL (OTHER INFORMATION)
Handling And Storage Precautions: AVOID CONTACT WITH EYES, SKIN, CLOTHING. DO
NOT BREATHE DUST. WASH THOROUGHLY AFTER HANDLING. MAINTAIN GENERAL INDUSTRIAL
HYGIENE PRACTICES WHEN USING. PROTECT FROM HEAT; KEEP AWAY FROM OXIDIZERS.
Other Precautions: AVOID CONTACT WITH: EYES, SKIN, CLOTHING. DO NOT BREATHE:
DUST. WASH THOROUGHLY AFTER HANDLING. PROTECT FROM : HEAT. KEEP AWAY FROM :
OXIDIZERS. USE WITH ADEQUATE VENTILATION.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Autoignition Temp Text: N/AV
Lower Limits: NOT APPLICAB
Upper Limits: NOT APPLICAB
Extinguishing Media: USE MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N).
Ventilation: ADEQUATE VENTILATION.
Protective Gloves: DISPOSABLE LATEX GLOVES.
Eye Protection: ANSI APPROVED SAFETY GLASSES WITH TOP & SIDE SHIELDS.
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI-DESIGN
CRITERIA (FP N). LAB COAT.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. MAINTAIN GENERAL
INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT.
=======================================================
Physical/Chemical Properties
=======================================================
Melt/Freeze Pt: =153.C, 307.4F
Vapor Density: NOT APPLIC
Spec Gravity: 1.74 (WATER=1)
PH: 1% SOLUTION=2.4
Solubility in Water: SOLUBLE
Appearance and Odor: SOLID; WHITE POWDER; ODORLESS.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: STABLE WHEN STORED UNDER PROPER CONDITIONS.
CONDITIONS TO AVOID: HEAT, EXCESS MOISTURE.
Materials To Avoid: OXIDIZERS, METAL NITRATES, METAL NITRITES.
Hazardous Decomposition Products: HEATING TO DECOMPOSITION RELEASES TOXIC
AND/OR CORROSIVE FUMES OF: NITROGEN OXIDES, CARBON DIOXIDE, CARBON MONOXIDE,
SULFUR OXIDES, AMMONIA.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: CITRIC ACID: LD50: ORAL, RAT=6730 MG/KG. LC50: NONE
REPORTED. HYDRAZINE SULFATE: LD50: ORAL, RAT=601 MG/KG. LC50: NONE REPORTED.
SODIUM CITRATE: LD50: ORAL, RAT LD50 > 8 G/KG. LC50: NONE REPORTED. PRO
DUCT TOX. DATA: LD50, LC50: NONE REPORTED. DERMAL TOXICITY DATA: NONE
REPORTED. SKIN & EYE IRRIT DATA: CITRIC ACID: EYE RABBIT 750
UG/24H-SEVERE, SKIN RABBIT 500 MG/24H-MODERATE. HYDRAZINE SULFATE: EY E
RABBIT 20 MG/24H-MODERATE. MUTATION DATA: HYDRAZINE SULFATE: SISTER
CHROMATOID EXCHANGE-HAMSTER-LUNG - 100 NMOL/L; DNA
INHIBITION-MOUSE-INTRAPERITONEAL-180 MG/KG; MORE DATA AVAILABLE IN RTECS.
(ECOL OGICAL INFORMATION)
=======================================================
Ecological Information
=======================================================
Ecological: PRODUCT ECOLOGICAL INFO: NO ECOLOGICAL DATA AVAILABLE FOR THIS
PRODUCT. INGREDIENT ECOLOGICAL INFO: NO ECOLOGICAL DATA AVAILABLE FOR THE
INGREDIENTS OF THIS PRODUCT. TOXICOLOGICAL INFO (CONT'D): REPR ODUCTIVE
EFFECTS DATA: NONE REPORTED. INGREDIENT TOX. DATA: HYDRAZINE SULFATE: ORAL
RAT LD50=601 MG/KG; CITRIC ACID: ORAL RAT LD50=6730 MG/KG; SODIUM CITRATE:
ORAL RAT LD50 > 8 G/KG. EXPERIMENTAL CAR CINOGEN. PRODUCT DOES NOT
CONTAIN ANY OSHA-LISTED CARCINOGENS. INGREDIENT OF THIS MIXTURE IS: IARC
GROUP 2B: EXPERIMENTAL CARCINOGEN: HYDRAZINE SULFATE. INGREDIENT OF MIXTURE
IS: NTP LISTED GROUP 2B: EXPERIMENTAL CARCINOGEN: (TRANSPORT)
=======================================================
MSDS Transport Information
=======================================================
Transport Information: DOT PROPER SHIPPING NAME: NOT CURRENTLY REGULATED. DOT
HAZARD CLASS, DOT SUBSIDIARY RISK, DOT ID #, DOT PACKING GROUP: NA. ICAO:
ICAO PROPER SHIPPING NAME: NOT CURRENTLY REGULATED. ICAO HAZARD CLASS, ICAO
SUBSIDIARY RISK, ICAO ID #, ICAO PACKING GROUP: NA. IMO: IMO PROPER SHIPPING
NAME: NOT CURRENTLY REGULATED. IMO HAZARD CLASS, IMO SUBSIDIARY RISK, IMO ID
#, IMO PACKING GROUP: NA. ECOLOGICAL INFO RMATION (CONT'D): HYDRAZINE
SULFATE. CONTAINS AN EXPERIMENTAL MUTAGEN. TOXICOLOGICALLY SYNERGISTIC
PRODUCTS: NONE REPORTED.
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: BUFFER POWDER PILLOWS CITRATE TYPE FOR HEAVY METALS, 14202
Company: HACH CO
Street: 5600 LINDBERGH DR
PO Box: 389
City: LOVELAND CO
Zipcode: 80539
Health Emergency Phone: 303-623-5716/515-232-2533
Label Required IND: Y
Date Of Label Review: 03/22/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: HARMFUL IF SWALLOWED, INHALED. CAUSES EYE, SKIN
& RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. EYES:
CAUSES IRRIT. SKIN : CAUSES IRRIT. MAY CAUSE ALLERGIC REACTION. SKIN ABSO
RPTION: HARMFUL IF ABSORBED THROUGH SKIN. INGESTION: TOXIC. MAY CAUSE
GASTROINTESTINAL TRACT DISTURBANCES, CNS EFFECTS. INHAL: CAUSES RESP TRACT
IRRIT. MAY CAUSE CNS EFFECTS. CHRONIC: CANCER HAZARD: CONTAINS HYDRAZINE
SULFATE WHICH IS REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN. MAY IMPAIR
BODY'S ABILITY TO ABSORB CALCIUM & IRON. LIVER/KIDNEY DAMAGE, ADVERSE
EFFECTS TO BLOOD & LUNG. TARGET O RGAN: CENTRAL NERVOUS SYSTEM.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|