KOST GROUP INC -- KOST USA PRE-CHARGED HEAVY-DUTY ANTIFREEZE
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Material Safety Data Sheet
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NIIN: 01-441-3223
MSDS Num: CLCGC
MSDS NAME: KOST USA PRE-CHARGED HEAVY-DUTY ANTIFREEZE
Responsible Party
Name: KOST GROUP INC
Address: 2775 W US 22 AND 3, SUITE 8
City: MAINEVILLE OH 45039
Info Phone: 513-583-7070
Emergency Phone Number: 800-424-9300
Chemtrec IND/Phone: (800)424-9300
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: KOST GROUP INC
Address: 2775 W US 22 AND 3, SUITE 8
City: MAINEVILLE OH 45039
Phone: 513-583-7070
Contract Number: SP0450-01-M-D987
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Item Description Information
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Item Manager: S9G
Item Name: ANTIFREEZE
Specification Number: A-A-52624
Type/Grade/Class: TYPE I
Unit of Issue: DR
Quantitative Expression: 00000000055GL
UI Container Qty: 1
Type of Container: DRUM
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Effects of Exposure: EYE-MAY CAUSE SLIGHT TRANSIENT IRRITATION. CORNEAL INJURY
UNLIKELY. VAPORS/MISTS CAUSE EYE IRRITATION. SKIN-PROLONGED/REPEATED EXPOSURE
NOT LIKELY TO CAUSE MUCH SKIN IRRITATION. REPEATED EXPOSURE MAY RESULT IN
ABSORPTION OF HARMFUL AMOUNTS.MASSIVE CONTACT WITH DAMAGED SKIN OR HOT
MATERIAL THAT BURNS THE SKIN MAY RESULT IN ABSORPTION OF LETHAL AMOUNTS.
INGESTION-EXCESSIVE EXPOSURE MAY CAUSE CNS EF FECTS, CARDIOPULMONARY EFFECTS,
& KIDNEY FAILURE. SWALLOWING LARGE AMOUNTS MAY CAUSE SERIOUS INJURY, EVEN
DEATH. INHALATION-HIGH TEMPRATURES MAY GENERATE VAPOR LEVELS THAT CAUSE
ADVERSE EFFECTS.
Explanation Of Carcinogenicity: BASED ON DATA FROM LONG-TERM ANIMAL STUDIES,
ETHYLENE GLYCOL IS NOT BELIEVED TO POSE A CARCINOGENIC RISK TO MAN.
Signs And Symptions Of Overexposure: REPEATED EXCESSIVE EXPOSURES MAY CAUSE
SEVERE KIDNEY & ALSO LIVER & GASTROINTESTINAL EFFECTS. SIGN/SYMPTOMS
OF EXCESSIVE EXPOSURE MAY BE CENTRAL NERVOUS SYSTEM EFFECTS, NAUSEA &/OR
VOMITING, ANESTHETI C OR NARCOTIC EFFECTS. OBSERVATIONS IN ANIMALS INCLUDE
FORMATION OF BLADDER STONES AFTER REPEATED ORAL DOSE OF ETHYLENE GLYCOL.
REPORTS OF KIDNEY FAILURE & DEATH IN BURN PATIENTS SUGGEST THAT ETHYLE NE
GLYCOL MAY HAVE BEEN A FACTOR. THE USE OF TOPICAL APPLICATIONS CONTAINING
THIS MATERIAL MAY NOT BE APPROPIATE IN SEVERELY BURNED PATIENTS OR
INDIVIDUALS WITH IMPAIRED RENAL FUNCTION.
First Aid: EYE-IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINS,
LIFTING LOWER/UPPER LIDS. GET MEDICAL AID AS SOON AS POSSIBLE. CONTACT LENSES
SHOULD NEVER BE WORN WHEN WORKING WITH THIS PRODUCT. SKIN-F LUSH AREA WITH
LARGE AMOUNTS OF WATER FOR 15 MINS WHILE REMOVING SOILED CLOTHES. IF
IRRITATION PERSISTS AFTER FLUSHING GET MEDICAL AID PROMPTLY.
INHALATION-REMOVE TO FRESH AIR & CALL EMERGENCY MEDICAL CARE. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. INGESTION-GIVE 2 GLASSES OF WATER & IMMEDIATELY CALL PHYSICIAN.
INDUCE VOMITING OF CONSCIOUS PATIENT BY PR ESSING FINGER DOWN THROAT.
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Handling and Disposal
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Spill Release Procedures: PROTECTIVE ENVIRONMENT-DO NOT DUMP USED PRODUCT OR
DILUTED MATERIAL INTO SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. SMALL
SPILLS-SOAK UP WITH ABSORBENT MATERIAL. LARGE SPILLS-DIKE & PUMP INTO S
UITABLE CONTAINERS FOR DISPOSAL. ENSURE COMPLIANCE WITH ALL APPLICABLE
STATUTES THAT REQUIRE NOTIFICATION OF APPROPRIATE GOVERNMENT OFFICIALS.
Waste Disposal Methods: DO NOT DISCHARGE TO SEWER. WEAR APPROPRIATE PERSONNEL
PROTECTION. TAKE UP WITH SAND, VERMICULITE, OR SIMILAR MATERIAL. DISPOSE IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: PRODUCT ON SURFACES CAN CAUSE SLIPPERY
CONDITIONS. PRACTICE REASONABLE CARE AND CLEANLINESS. AVOID BREATHING SPRAY
MIST IF GENERATED. KEEP OUT OF REACH OF CHILDREN. PRODUCT MAY BECOME A SOLID
AT TEMPE RATURES BELOW -18C(0F). DO NOT STORE NEAR FOOD, FOODSTUFFS, DRUGS OR
POTABLE WATER SUPPLIES.
Other Precautions: PROTECT PEOPLE IN CASE OF SPILL: MATERIAL IS MODERATELY
TOXIC WHEN INGESTED. TAKE ADEQUATE PRECAUTIONS TO KEEP PEOPLE, ESPECIALLY
CHILDREN AWAY FROM SPILL SITE. PVC COATED RUBBER GLOVES AND MONOGOGGLE S OR
FACESHIELD CAN BE USED DURING CLEANUP OF SPILL SITE.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point: =119.C, 246.2F
Autoignition Temp: =398.C, 748.4F
Lower Limits: 3.2%
Upper Limits: 22%
Extinguishing Media: WATER FOG OR FINE SPRAY. ALCOHOL RESISTANT FOAMS (ATC).
GENERAL PURPOSE FOAMS (AFFF) OR PROTEIN FOAMS MAY FUNCTION, BUT LESS
EFFICIENTLY. CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: WEAR POSITIVE PRESSURE, SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE FIRE FIGHTING CLOTHES (INCLUDES FIRE-FIGHTING
HELMET, COAT, PANTS, BOOTS AND GLOVES). DO NOT USE DIRECT WATER STREAM. MAY
SPRE AD FIRE.
Unusual Fire/Explosion Hazard: NO FIRE AND EXPLOSION HAZARD EXPECTED UNDER
NORMAL STORAGE AND HANDLING CONDITIONS. ETHYLENE GLYCOL OR SOLUTIONS OF
ETHYLENE GLYCOL AND WATER CAN FORM FLAMMABLE VAPORS WITH AIR IF HEATED
SUFFICIENTLY. KEEP PEOPLE AWAY. ISOLATE FIRE AND DENY UNNECESSARY ENTRY.
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Control Measures
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Respiratory Protection: SELF-CONTAINED BREATHING APPARATUS WITH A FULL
FACEPIECE; OPERATED IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE, OR
ANY SUPPLIED AIR RESPIRATOR WITH FULL FACE PIECE AND OPERATED IN A PRESSURE
DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY
SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND OR OTHER
POSITIVE MODE.
Ventilation: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.
Protective Gloves: POLYETHYLENE, NEOPRENE, NITRILE, POLYVINYL ALCOHOL, BUTYL
OR NATURAL RUBBER.
Eye Protection: SAFETY GOGGLES AND FACESHIELD.
Other Protective Equipment: EMERGENCY EYE WASH STATION SHOULD BE AVAILABLE.
PROTECTIVE GLOVES RECOMMENDED WHEN PROLONGED SKIN CONTACT CANNOT BE AVOIDED.
SAFETY SHOWER SHOULD BE AVAILABLE.
Work Hygienic Practices: CONTACT LENSES SHOULD NEVER BE WORN WHEN WORKING WITH
THIS CHEMICAL. WASH CLOTHING BEFORE RESUE.
Supplemental Safety and Health: EMERGENCY OVERVIEW: SLIGHT ODOR. MAY BE FATAL
IF SWALLOWED. VAPORS CAN CAUSE EYE IRRITATION. HAZARD RATING SYSTEM (NFPA):
HEALTH=1, FLAMMIBILITY=1, REACTIVITY=0. KEY: 0-MINIMAL, 1-SLIGHT, 2-MODERATE,
3-SERIOUS, 4-SEVERE.
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Physical/Chemical Properties
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HCC: V1
B.P. Text: 164-176C (327-348F)
Melt/Freeze Pt: =-18.C, -.4F
Vapor Pres: <0.1MMHG
Vapor Density: 2.1
Spec Gravity: 1.12
Evaporation Rate & Reference: NIL (BUAC=1)
Solubility in Water: COMPLETE
Appearance and Odor: GREEN; MILD ODOR
Percent Volatiles by Volume: 97%
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ISOLATE FROMOXIDIZERS, HEAT & OPEN FLAME.
Materials To Avoid: ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES,
CHROMATES & PEROXIDES.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE FROM BURNING.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: MATERIAL IS NOT KNOWN TO POLYMERIZE.
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Toxicological Information
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Toxicological Information: LOWEST KNOWN LD50(ORAL), 107-21-1, 5840 MG/KG
(RATS). LOWEST KNOWN LD50 (SKIN), 107-21-1, 9530 MG/KG (RABBITS). SKIN: THE
DERMAL LD50 HAS NOT BEEN DETERMINED. INGESTION: THE LETHAL DOSE IN HUMANS IS
~ 100 ML (3 OZ). THE ORAL LD50 FOR RATS IN THE 6,000-13,000 MG/KG RANGE.
MUTAGENICITY (THE EFFECTS ON GENETIC MATERIAL): IN VITRO MUTAGENICITY STUDIES
WERE NEGATIVE. ANIMAL MUTAGENICITY STUDIES WERE NEG ATIVE. TERATOLOGY (BIRTH
DEFECTS): EXPOSURE TO ETHYLENE GLYCOL HAS CAUSED BIRTH DEFECTS IN LAB ANIMALS
ONLY AT DOSES TOXIC TO THE MOTHER. REPRODUCTIVE EFFECTS: ETHYLENE GLYCOL HAS
NOT INTERFERED WITH REPRODUCTION IN ANIMALS.
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Ecological Information
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Ecological: MOVEMENT & PARTIONING: BIOCONCENTRATION POTENTIAL IS LOW (BCF
LESS THAN 100 OR LOG KOW LESS THAN 3). LOG OCTANOL/WATER PARTION COEFFICIENT
(LOG KOW) IS -1.36 HENRY`S LAW CONSTANT(H) IS 6.0E-08 ATM-M3/ MOL.
BIOCENTRATION FACTOR (BCF) IS 10 IN GOLDEN ORFE. DEGRADATION &
TRANSFORMATION: BIODEGRADATION UNDER AEROBIC STATIC LABORATORY CONDITIONS IS
HIGH (BOD20 OR BOD28/THOD GREATER THAN 40%). 50DAY BI OCHEMICAL OXYGEN DEMAND
(BOD5) IS 0.78 P/P. 10-DAY BIOCHEMICAL OXYGEN DEMAND (BOD10) IS 1.06 P/P.
20-DAY BIOCHEMICAL OXYGEN DEMAND (BOD20) IS 1.15 P/P. THEORETICAL OXYGEN
DEMAND (THOD) IS CALCULATED T O BE 1.29 P/P.
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MSDS Transport Information
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Transport Information: (FOR BULK SHIPMENTS ONLY): PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID NOS (ETHYLENE GLYCOL). HAZARD
CLASS: 9. LABLE: 9. ID NUMBER: UN 3082. LABEL: MISCELLANEOUS RQ PRODUCT.
PACKA GING GROUP: III. SHIPMENT WITH INDIVIDUAL PACKAGING (I.E. - DRUMS,
PAILS, OR GALLONS) CONTAINING LESS THAN THE RQ (5,000 POUNDS) WOULD NOT BE
SUBJECT TO REGULATIONS.
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Regulatory Information
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Sara Title III Information: SECTION 311/312 - CATEGORIES: ACUTE HAZARD, CHRONIC
HAZARD. SECTION 312 - INVENTORY REPORTING: ETHYLENE GLYCOL IS SUBJECT TO TIER
I AND/ OR TIER II ANNUAL INVENTORY REPORTING. SECTION 313 - EMISSION R
EPORTING: ETHYLENE GLYCOL IS SUBJECT TO FORM R REPORTING REQUIREMENTS.
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES: ETHYLENE GLYCOL IS NOT LISTED.
Federal Regulatory Information: UNITES STATES TSCA INVENTORY: LISTED. WATER
STANDARD: NO DATA AVAILABLE. ATMOSPHERIC STANDARDS: CLEAN AIR ACT (1990) -
LIST OF HAZARDOUS AIR CONTAMINANTS: LISTED.
CERCLA: REPORTABLE QUANTITY (RQ): 5, 000 POUNDS (532 GALLONS).
State Regulatory Information: CALIFORNIA-EXPOSURE LIMITS-CEILINGS: VAPOR - 50
PPM; 125 MG/M3 CEILING. DIRECTOR`S LIST OF HAZARDOUS SUBSTANCES: LISTED.
FLORIDA - HAZARDOUS SUBSTANCE LIST: LISTED. MASSACHUSETTS - RIGHT-TO-KNOW
LIST: LISTED. MINNESOAT - HAZARDOUS SUBSTANCE LIST: LISTED (PARTICULATE AND
VAPOR). NEW JERSEY - RIGHT-TO-KNOW LIST (TOTAL): PRESENT GREATER THAN 1.0%.
PENNSYLVANIA - RIGHT-TO-KNOW LIST: ENVIRONMENTAL HAZA RD.
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Other Information
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Other Information: CANADIAN REGULATIONS: THIS PRODUCT HAS BEEN CLASSIFIED IN
ACCORDANCE WITH THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS
(CPR) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED. W INF ORMATION:
D2A-MATERIAL HAS POTENTIAL TOXIC EFFECTS. REFER ELSEWHERE IN THE MSDS FOR
SPECIFIC WARNINGS AND SAFE HANDLING INFORMATION. REFER TO THE EMPLOYERS
WORKPLACE EDUCATION PROGRAM.
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Transportation Information
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Trans ID NO: 156816
MSDS NAME: KOST USA PRE-CHARGED HEAVY-DUTY ANTIFREEZE
MSDS Prepared Date: 01/01/2001
Review Date: 04/24/2001
Tech Entry NOS Shipping Nm: ETHYLENE GLYCOL
Net Unit Weight: 557 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 1
Type Of Container: DRUM
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Detail DOT Information
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DOT PSN Code: FST
Symbols: G
DOT Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
Hazard Class: 9
UN ID Num: UN3082
DOT Packaging Group: III
Label: CLASS 9
Special Provision: 8,T1
Packaging Exception: 155
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: NONE
Max Qty Cargo: NONE
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: GMW
IMO Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. o
IMDG Page Number: 9028
UN Number: 3082
UN Hazard Class: 9
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: NONE
MED First Aid Guide NUM: NON
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Detail IATA Information
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IATA PSN Code: KTV
IATA UN ID Num: 3082
IATA Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
*
IATA UN Class: 9
IATA Label: MISCELLANEOUS
UN Packing Group: III
Packing Note Passenger: 914
Max Quant Pass: NO LIMIT
Max Quant Cargo: NO LIMIT
Packaging Note Cargo: 914
Exceptions: A97
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Detail AFI Information
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AFI PSN Code: KTV
AFI Symbols: *
AFI Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
AFI Hazard Class: 9
AFI UN ID NUM: UN3082
AFI Packing Group: III
Special Provisions: P5, 8
Back Pack Reference: A13.3
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HAZCOM Label
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MSDS NAME: KOST USA PRE-CHARGED HEAVY-DUTY ANTIFREEZE
Company: KOST GROUP INC
Street: 2775 W US 22 AND 3, SUITE 8
City: MAINEVILLE OH
Zipcode: 45039
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 04/24/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: EYE-MAY CAUSE SLIGHT TRANSIENT IRRITATION. CORNEAL
INJURY UNLIKELY. VAPORS/MISTS CAUSE EYE IRRITATION. SKIN-PROLONGED/REPEATED
EXPOSURE NOT LIKELY TO CAUSE MUCH SKIN IRRITATION. REPEATED EXPOSURE MAY
RESULT IN ABSORPTION OF HARMFUL AMOUNTS.MASSIVE CONTACT WITH DAMAGED SKIN OR
HOT MATERIAL THAT BURNS THE SKIN MAY RESULT IN ABSORPTION OF LETHAL AMOUNTS.
INGESTION-EXCESSIVE EXPOSURE MAY CAUSE CNS EF FECTS, CARDIOPULMONARY EFFECTS,
& KIDNEY FAILURE. SWALLOWING LARGE AMOUNTS MAY CAUSE SERIOUS INJURY, EVEN
DEATH. INHALATION-HIGH TEMPRATURES MAY GENERATE VAPOR LEVELS THAT CAUSE
ADVERSE EFFECTS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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