R. T. VANDERBILT COMPANY, INC -- BLACK-OUT BLACK, 07209
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Material Safety Data Sheet
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MSDS Num: CLHKZ
MSDS NAME: BLACK-OUT BLACK, 07209
Responsible Party
Name: R. T. VANDERBILT COMPANY, INC.
Address: 30 WINFIELD ST
City: NORWALK CT 06855
Info Phone: 203-853-1400
Emergency Phone Number: 203-853-1400
Preparer's Name: ERIN A. BENDIG
Proprietary Ind: Y
Published: Y
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Contractor Summary
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Name: R. T. VANDERBILT COMPANY, INC.
Address: 30 WINFIELD ST
City: NORWALK CT 06855
Phone: 203-853-1400
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: ACUTE ORAL TOX. (LD50): 636 MG/KG (RAT)
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE EFFECTS: EYE: NO DATA AVAILABLE. CONTACT WITH LIQUID
CAN CAUSE SEVERE EYE IRRITATION, AND VAPORS CAN CAUSE MILD TO MODERATE
IRRITATION BASED ON COMPONENT TESTING. SKIN: NO DATA AVAILABLE. PRODUC T
EXPECTED TO BE AN IRRITANT BASED ON COMPONENT TESTING. SENSITIZATION: NO DATA
AVAILABLE. INGESTION: THIS PRODUCT MAY BE AN INGESTION HAZARD. IF ASPIRATED
INTO THE LUNGS, CAN CAUSE PNEUMONITIS. INHAL ATION: PRODUCT IS EXPECTED TO BE
TOXIC BY INHALATION BASED ON COMPONENT DATA. REMARKS: TOLUENE: SHORT-TERM
EXPOSURE CAN CAUSE DRYNESS AND IRRITATION OF SKIN. EYE IRRITATION IS CAUSED
AT 300 PPM. INHAL ATION EXPOSURE AT (EFTS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: CARCINOGENIC EFFECTS: CLASSIFIED A4 (NOT
CLASSIFIABLE FOR HUMAN OR ANIMAL) BY ACGIH. 3 (NOT CLASSIFIABLE FOR HUMAN) BY
IARC (TOLUENE). CLASSIFIED + (PROVEN) BY NIOSH (CARBON BLACK). CLASSIFIED 2B
(POS SIBLE FOR HUMAN) BY IARC (CARBON BLACK). CLASSIFIED NONE BY OSHA (CARBON
BLACK). CLASSIFIED A4 (NOT CLASSIFIABLE FOR HUMAN OR ANIMAL) BY ACGIH (CARBON
BLACK).
Signs And Symptions Of Overexposure: HLTH HAZ (CONT'D): 100 PPM CAN CAUSE
DIZZINESS, DROWSINESS & HALLUCINATIONS; AT 100-200 PPM CAN CAUSE
DEPRESSION, & AT 200-500 PPM CAN CAUSE HEADACHES, NAUSEA, LOSS OF
APPETITE, ENERGY, & COMA. INGEST ION CAN CAUSE ABDOMINAL PAIN, NAUSEA,
HEADACHE, LOSS OF COORDINATION & COMA. CHRONIC EFFECTS ON HUMANS:
REPEATED OR PROLONGED EXPOSURE TO THE SUBSTANCE CAN PRODUCE DAMAGE TO THE
KIDNEYS, NERVOUS SYST EM, LIVER, UPPER RESPIRATORY TRACT & EYES. REMARKS:
TOLUENE: LONG-TERM EXPOSURE AT 200-500 PPM MAY CAUSE LOSS OF MEMORY &
APPETITE. LEVELS OF 1500 PPM MAY CAUSE HEART PALPITATIONS & LOSS OF
COORDINATI ON. CAN ALSO CAUSE LIVER (SUPP SAFETY)
Medical Cond Aggravated By Exposure: N/P. EMERGENCY OVERVIEW: BLACK FLAMMABLE
LIQUID. HARMFUL IF INHALED. EYE, SKIN IRRITANT. MAY BE INGESTION/ASPIRATION
HAZARD.
First Aid: EYE: CHECK FOR & REMOVE ANY CONTACT LENSES. IMMEDIATELY FLUSH
EYES WITH RUNNING WATER FOR AT LEAST 15 MINUTES, KEEPING EYELIDS OPEN. COLD
WATER MAY BE USED. DO NOT USE AN EYE OINTMENT. SEEK MEDICAL AT TENTION. SKIN:
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER. GENTLY &
THOROUGHLY WASH CONTAMINATED SKIN WITH RUNNING WATER & NON-ABRASIVE SOAP.
BE PARTICULARLY CAREFUL TO CLEAN FOLDS , CREVICES, CREASES & GROIN. COVER
IRRITATED SKIN WITH AN EMOLLIENT. IF IRRITATION PERSISTS, SEEK MEDICAL
ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: ALLOW THE
VICTIM TO REST IN A WELL VENTILATED AREA. (TRANSPORT)
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Handling and Disposal
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Spill Release Procedures: SMALL: ABSORB WITH INERT MATERIAL & PUT SPILLED
MATERIAL IN APPROPRIATE WASTE DISPOSAL. LARGEL: FLAMMABLE LIQUID. KEEP AWAY
FROM HEAT & SOURCES OF IGNITION. STOP LEAK IF WITHOUT RISK. ABSORB WITH
DRY EARTH, SAND, OR OTHER NON-COMBUSTIBLE MATERIAL. DO NOT TOUCH SPILLED
MATERIAL. PREVENT ENTRY INTO SEWERS, BASEMENTS OR CONFINED AREAS; DIKE IF
NEEDED. ELIMINATE ALL IGNITION SOURCES. (WASTE DISPOSAL)
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE
AND LOCAL REGULATIONS (FP N). WASTE INFORMATION: RCRA CLASS D001. WASTE
STREAM: NOT AVAILABLE. SPILL/RELEASE (CON'T): BE CAREFUL THAT PRODUCT IS
NOT PRESENT AT A CONCENTRATION LEVEL ABOVE TLV. CHECK TLV ON MSDS AND WITH
LOCAL AUTHORITIES.
Handling And Storage Precautions: TO AVOID FIRE/EXPLOSION, DISSIPATE STATIC
ELECTRICITY DURING TRANSFER BY GROUNDING & BONDING CONTAINERS &
EQUIPMENT BEFORE TRANSFERRING MATL. USE EXPLOSION-PROOF ELECTRICAL
(VENTILATING, LIGHTING & MA TERIAL HANDLING) EQUIPMENT. AVOID CONTACT
W/SKIN & EYES. AVOID BREATHING VAPORS/SPRAY (OTHER PREC)
Other Precautions: HNDLNG/STOR (CON'T): OR MISTS. FLAMMABLE MATERIALS SHOULD
BE STORED IN A SEPARATE SAFETY STORAGE CABINET/ROOM. KEEP AWAY FROM HEAT
& SOURCE OF IGNITION. KEEP CONTAINER TIGHTLY CLOSED. KEEP IN A COOL,
WELL-VENTED PLACE. GROUND ALL EQUIP CONTAINING MATL. A REFRIGERATED ROOM IS
PREFERABLE FOR MATLS W/ FLASH POINT < 100F.
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Fire and Explosion Hazard Information
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Flash Point Method: CC
Flash Point: =5.C, 41.F
Autoignition Temp: =480.C, 896.F
Lower Limits: 1.2
Upper Limits: 7 (TOLUENE)
Extinguishing Media: SMALL FIRE: USE DRY CHEMICAL POWDER. LARGE FIRE: CO2, DRY
CHEMICAL OR ALCOHOL FOAM. FLAMMABLE LIQUID, SOLUBLE OR DISPERSED IN WATER.
FLAMMABILITY OF PRODUCT: FLAMMABLE.
Fire Fighting Procedures: WEAR NIOSH-APPROVED SELF-CONTAINTED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N). THIS PRODUCT WILL FLOAT UPON
WATER, SO WATER SPRAY IS NOT A SUITABLE EXTINGUISHING AGENT AS IT MAY CAUSE A
NY FIRE TO SPREAD. AUTO-IGNITION TEMPERATURE SHOWN IS THE LOWEST KNOWN VALUE
(TOLUENE).
Unusual Fire/Explosion Hazard: FUMES MAY SPREAD CONSIDERABLE DISTANCES AND
FLASH BACK IF EXPOSED TO FLAME. RISKS OF EXPLOSION OF THE PRODUCT IN PRESENCE
OF MECHANICAL IMPACT OR STATIC DISCHARGE: NOT AVAILABLE. PRODUCTS OF
COMBUSTI ON: THESE PRODUCTS ARE CARBON OXIDES (CO, CO2) AND
CHLOROHYDROCARBONS. FLAMMABILITY LIMITS: THE (HAZ DECOMP PROD)
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Control Measures
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Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N). AT LEVELS UP TO 500 PPM USE CHEMICAL CARTRIDGE
RESPIRATOR W/ORGANIC VAPOR CARTRIDGE, A SUPPLIED-AIR RESPIRATOR OR SELF-CONTA
INED BREATHING APPARATUS. AT UP TO 1,000 PPM USE A CHEMICAL CARTRIDGE
RESPIRATOR W/ORGANIC VAPOR CARTRIDGE & FACEPIECE. AT UP TO 2,000 PPM USE
A (HYGIENE PRACT)
Ventilation: PROVIDE EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
THE AIRBORNE CONCENTRATIONS OF VAPORS BELOW THEIR RESPECTIVE THRESHOLD LIMIT
VALUE.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: ENSURE THAT EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA ARE PROXIMAL TO THE WORK-STATION LOCATION (FP N). LAB COAT.
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE. RESP PROT
(CONT'D): GAS MASK W/ORGANIC CARTRIDGE, SUPPLIED-AIR RESPIRATOR W/FULL
FACEPIECE, HOOD, HELMET OR SELF-CONTAINED BREATHING APPARATUS W/FULL
FACEPIECE.
Supplemental Safety and Health: SIGN/SYMP OF OVEREXPOS (CONT'D): DAMAGE. CARBON
BLACK: LONG-TERM EXPOSURE MAY AFFECT LUNGS, BREATHING PASSAGES & HEART.
AS FORMULATED IN THIS PRODT, NONE WILL BE RELEASED INTO ATMOSPHERE BY
VOLATIZATI ON. EMERGENCY OVERVIEW: BLACK FLAMMABLE LIQUID. HARMFUL IF
INHALED. EYE & SKIN IRRITANT. MAY BE INGEST & ASPIRATION HAZ.
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Physical/Chemical Properties
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Boiling Point: =110.6C, 231.1F
B.P. Text: TOLUENE
M.P/F.P Text: NOT AVAILABLE.
Vapor Pres: 22 MM HG @ 20C (TOLUENE)
Vapor Density: OTHER INFO
Spec Gravity: 0.866 (WATER=1) (TOLUENE)
PH: ACIDIC (1% SOL)
Viscosity: NOT AVAILABLE.
Evaporation Rate & Reference: OTHER INFORMATION
Solubility in Water: MODERATELY IN COLD WATER.
Appearance and Odor: BLACK LIQUID. ODOR: NOT AVAILABLE.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: INSTABILITY TEMPERATURE: NOT AVAILABLE.
CONDITIONS OF INSTABILITY: NOT AVAILABLE.
Materials To Avoid: REACTIVE WITH OXIDIZING AGENTS. REACTS VIOLENTLY WITH
CHLORINE, PERMANGANATE AND DICHROMATE. CORROSIVITY: NOT AVAILABLE. SPECIAL
REMARKS ON REACTIVITY: NOT AVAILABLE.
Hazardous Decomposition Products: N/P (EXPLO HAZ, CONT'D) GREATEST KNOWN RANGE
IS LOWER: 1.2% UPPER: 7% (TOLUENE). SPECIAL REMARKS ON EXPLOSION HAZARDS: NOT
AVAILABLE.
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: TOXICITY TO ANIMALS: WARNING: LC50 VALUES HEREUNDER
ARE ESTIMATED ON BASIS OF A 4-HOUR EXPOSURE. ACUTE ORAL TOXICITY (LD50): 636
MG/KG (RAT)(TOLUENE). ACUTE DERMAL TOXICITY (LD50): 14000 MG/KG (RAT)(
TOLUENE). ACUTE TOXICITY OF THE GAS (LC50): 4000 PPM 4 HOUR(S)
(RAT)(TOLUENE). SPECIAL REMARKS ON TOXICITY TO ANIMALS: NOT AVAIL. MUTAGENIC
EFFECTS, DEVELOPMENTAL TOXICITY & REPRODUCTIVE TOXICITY: NOT AVAIL.
PHYSICAL/CHEM (CON'T): MOLECULAR WT: NOT APPLIC. DENSITY: 0.88 MG/M3 @25C
(77F). VAPOR DENSITY: 3.1 (TOLUENE) (AIR=1). VOLATILITY: 89% (W/W).
EVAPORATION RATE: 2.24 (TOLUENE) COMPARED TO BUTY L ACETATE. WATER/OIL DIST.
COEFF: N/A.
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Ecological Information
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Ecological: ECOTOXOCITY: NOT AVAILABLE. BOD5 AND COD: NOT AVAILABLE. PRODUCTS
OF BIODEGRADATION: POSSIBLY HAZARDOUS SHORT TERM DEGRADATION PRODUCTS ARE NOT
LIKELY. HOWEVER, LONG TERM DEGRADATION PRODUCTS MAY ARIS E. TOXICITY OF THE
PRODUCTS OF BIODEGRADATION: THE PRODUCTS OF DEGRADATION ARE LESS TOXIC THAN
THE PRODUCT ITSELF. SPECIAL REMARKS ON THE PRODUCTS OF BIODEGRADATION: NOT
AVAILABLE.
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MSDS Transport Information
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Transport Information: DOT: CLASS 3: FLAMMABLE LIQUID. SHIPPING NAME: FLAMMABLE
LIQUIDS N.O.S. (TOLUENE SOLUTION). (TOLUENE) UNNA: 1294. PG: NOT AVAILABLE.
REMARKS: NOT AVAILABLE. MARITIME TRANSPORTATION: NOT AVAILABLE. F IRST AID
(CON'T): SEEK IMMEDIATE MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. IMMEDIATELY GIVE TWO GLASSES OF WATER, A LITTLE AT A TIME. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON . CALL A PHYSICIAN. IF
VOMITING OCCURS SPONTANEOUSLY, LOWER HEAD BELOW WAIST TO PREVENT FLUID FROM
ENTERING THE LUNGS.
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Regulatory Information
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Sara Title III Information: SARA 302/304/311/312 HAZARDOUS CHEMICALS: CARBON
BLACK. SARA 311/312 MSDS DISTRIBUTION - CHEMICAL INVENTORY- HAZARD
IDENTIFICATION: CARBON BLACK: IMMEDIATE HEALTH HAZARD, DELAYED HEALTH HAZARD.
SARA 3 13 TOXIC CHEMICAL NOTIFICATION AND RELEASE REPORTING: TOLUENE 88.5%.
CERCLA: HAZARDOUS SUBSTANCES: TOLUENE: 1000 LBS. (453.6 KG).
Federal Regulatory Information: CLASSIFICATIONS : HCS (USA) CLASS: FLAMMABLE
LIQUID HAVING A FLASH POINT LOWER THAN 37.8C (100F). CLASS: TOXIC. CLASS:
IRRITATING SUBSTANCE.
OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STAND ARD (29 CFR
1910.1200). TSCA 8(B) INVENTORY: BLACK-OUT BLACK. TSCA 8(A) PAIR: TOLUENE.
CERCLA: HAZARDOUS SUBSTANCES: TOLUENE: 1000 LBS. (453.6 KG). EINECS: THIS
PRODUCT IS ON THE EUROPEAN INVENTORY OF EXISTING COMERCIAL CHEMICAL
SUBSTANCES. CEPA DSL: BLACK-OUT BLACK. CANADIAN NPRI: TOLUENE. AUSTRALI A:
BLACK-OUT BLACK.
State Regulatory Information: CALIFORNIA PROP. 65: THIS PRODUCT CONTAINS THE
FOLLOWING INGREDIENTS FOR WHICH THE STATE OF CALIFORNIA HAS FOUND TO CAUSE
BIRTH DEFECTS WHICH WOULD REQUIRE A WARNING UNDER THE STATUTE: TOLUENE. RHODE
ISLAND RTK HAZARDOUS SUBSTANCES: CARBONBLACK. PENNSYLVANIA RTK: TOLUENE;
CARBON BLACK: (GENERIC ENVIRONMENTAL HAZARD). FLORIDA: TOLUENE. MINNESOTA:
TOLUENE; CARBON BLACK. MICHIGAN CRITICAL MATERIAL: T OLUENE. MASSACHUSETTS
RTK: TOLUENE; CARBON BLACK. NEW JERSEY: TOLUENE; CARBON BLACK. NEW JERSEY
SPIL L LIST: CARBON BLACK.
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Other Information
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HAZCOM Label
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MSDS NAME: BLACK-OUT BLACK, 07209
Company: R. T. VANDERBILT COMPANY, INC.
Street: 30 WINFIELD ST
City: NORWALK CT
Zipcode: 06855
Health Emergency Phone: 203-853-1400
Label Required IND: Y
Date Of Label Review: 08/03/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: CONTACT WITH LIQUID CAN CAUSE SEVERE
EYE IRRITATION, & VAPORS CAN CAUSE MILD TO MODERATE IRRITATION. SKIN:
PRODUCT EXPECTED TO BE AN IRRITANT. INGESTION: MAY BE AN INGESTION HAZARD.
IF ASPIRATED INTO LUNGS, CAN CAUSE PNEUMONITIS. INHALATION: MAY BE TOXIC BY
INHALATION. TOLUENE: SHORT-TERM EXPOSURE CAN CAUSE DRYNESS & IRRITATION
OF SKIN. CAN CAUSE EYE IRRITATION, DIZZINESS, DROWS INESS, HALLUCINATIONS.
CHRONIC: REPEATED/PROLONGED EXPOSURE CAN DMG KIDNEYS, LIVER, NERVOUS SYS,
EYES & UPPER RESPIRATORY TRACT. TOLUENE: MAY CAUSE LOSS OF MEMORY &
APPETITE, HEART PALPITATIONS & LOS S OF COORDINATION. CAN CAUSE LIVER
DAMAGE.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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