ASHLAND CHEMICAL CO. -- ENZYBATE E ODOR CONTROL AGENT
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CLJRV
MSDS NAME: ENZYBATE E ODOR CONTROL AGENT
Responsible Party
Name: ASHLAND CHEMICAL CO.
Box: 2219
City: COLUMBUS OH 43216-2219
Info Phone: 614-790-3333/800-274-5263
Emergency Phone Number: 800-274-5263
Resp. Party Other MSDS No.: 306.0354171-001.001
Proprietary Ind: Y
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
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Name: ASHLAND CHEMICAL CO
Box: 2219
City: COLUMBUS OH 43216-2219
Phone: 614-790-3333/800-274-5263
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Ingredients
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Name: *** PROPRIETARY ***
-----------------------------
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Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: PRIMARY ROUTES OF ENTRY: INHALATION, SKIN CONTACT, EYE
CONTACT, INGESTION. POTENTIAL HEALTH EFFECTS: EYE: CAN CAUSE EYE IRRITATION.
SYMPTOMS INCLUDE STINGING, TEARING, REDNESS, AND SWELLING OF EYES. SKIN: CAN
CAUSE SKIN IRRITATION. SYMPTOMS MAY INCLUDE REDNESS AND BURNING OF SKIN, AND
OTHER SKIN DAMAGE. SWALLOWING: SWALLOWING SMALL AMOUNTS OF THIS MATERIAL
DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS. SWALLOWING
LARGE AMOUNTS MAY BE HARMFUL. INHALATION: BREATHING SMALL AMOUNTS OF THIS
MATERIAL DURING NORMAL HANDLING IS NOT LIKELY TO CAUSE HARMFUL EFFECTS.
BREATHING LARGE AMOU NTS (SIGNS AND SYMPTOMS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: THIS MATERIAL IS NOT LISTED AS A CARCINOGEN BY
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER, THE NATIONAL TOXICOLOGY
PROGRAM, OR THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
Signs And Symptions Of Overexposure: HEALTH HAZARD ACUTE AND CHRONIC (CONT):
MAY BE HARMFUL. SYMPTOMS OF EXPOSURE: SIGNS AND SYMPTOMS OF EXPOSURE TO THIS
MATERIAL THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE MATERIAL
THROUGH THE SKIN MAY INCLUDE: STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING,
DIARRHEA, IRRITATION (NOSE, THROAT, AIRWAYS), TIGHT FEELING IN THE CHEST,
MUSCLE WEAKNESS. TARGET ORGAN EFFECTS: NO DATA. DEVELOPMENT AL INFORMATION:
THERE ARE NO DATA AVAILABLE FOR ASSESSING RISK TO THE FETUS FROM MATERNAL
EXPOSURE TO THIS MATERIAL. OTHER HEALTH EFFECTS: NO DATA.
Medical Cond Aggravated By Exposure: PREEXISTING DISORDERS OF THE SKIN, LUNG
(I.E. ASTHMA-LIKE CONDITIONS), LIVER, KIDNEY, ANY CONDITION SENSITIVE TO
DECREASE IN OXYGEN LEVELS (I.E. CHRONIC LUNG DISEASE, CORONARY ARTERY
DISEASE, ANEMIAS)
First Aid: EYES: IF SYMPTOMS DEVELOP, IMMEDIATELY MOVE INDIVIDUAL AWAY FROM
EXPOSURE AND INTO FRESH AIR. FLUSH EYES GENTLY WITH WATER FOR AT LEAST 15
MINUTES WHILE HOLDING EYELIDS APART; SEEK IMMEDIATE MEDICAL A TTENTION. SKIN:
REMOVE CONTAMINATED CLOTHING. FLUSH EXPOSED AREA WITH LARGE AMOUNTS OF WATER.
IF SKIN IS DAMAGED, SEEK IMMEDIATE MEDICAL ATTENTION. IF SKIN IS NOT DAMAGED
AND SYMPTOMS PERSIST, SEEK ME DICAL ATTENTION. SWALLOWING: SEEK MEDICAL
ATTENTION. IF INDIVIDUAL IS DROWSY OR UNCONSCIOUS, DO NOT GIVE ANYTHING BY
MOUTH; PLACE INDIVIDUAL ON THE LEFT SIDE WITH THE HEAD DOWN. CONTACT A
PHYSICIAN, M EDICAL FACILITY, OR (TOXICOLOGICAL INFO)
=======================================================
Handling and Disposal
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Spill Release Procedures: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR
ABSORBENT OR OTHER ABSORBENT MATERIAL. PERSONS NOT WEARING PROPER PERSONAL
PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL. SCOOP OR SCRAPE
UP. PUT IN CONTAINER FOR RECOVERY OR DISPOSAL. LARGE SPILL: PERSONS NOT
WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL
CLEAN-UP HAS BEEN (SUPPLEMENTAL SAFETY AND HEALTH)
Waste Disposal Methods: WASTE MANAGEMENT INFORMATION: DISPOSE OF IN ACCORDANCE
WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
Handling And Storage Precautions: HANDLING: PRECAUTIONS DURING USE: AVOID
PROLONGED OR FREQUENTLY REPEATED SKIN CONTACT WITH THIS MATERIAL. SKIN
CONTACT CAN BE MINIMIZED BY WEARING IMPERVIOUS PROTECTIVE GLOVES. AS WITH ALL
PRODUCTS OF THIS NATURE, GOOD PERSONAL HYGIENE IS ESSENTIAL. HANDS AND OTHER
EXPOSED AREAS (OTHER PRECAUTIONS)
Other Precautions: HANDLING & STORAGE PRECAUTIONS (CONT): SHOULD BE WASHED
THOROUGHLY WITH SOAP AND WATER AFTER CONTACT, ESPECIALLY BEFORE EATING AND/OR
SMOKING. REGULAR LAUNDERING OF CONTAMINATED CLOTHING IS ESSENTIAL TO REDUCE
INDIRECT SKIN CONTACT WITH THIS MATERIAL. STORAGE: DO NOT STORE NEAR HIGH
HEAT OR OPEN FL AMES. (OTHER INFO)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Autoignition Temp Text: NO DAT
Lower Limits: N/APPLICABLE
Upper Limits: N/APPLICABLE
Extinguishing Media: USE AN EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures: WEAR A (NIOSH APPROVED - FP N) SELF-CONTAINED
BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE
DEMAND MODE WITH APPROPRIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PERSONAL
PRO TECTIVE EQUIPMENT. REFER TO THE (CONTROL MEASURES) SECTION OF THIS MSDS.
Unusual Fire/Explosion Hazard: NO SPECIAL FIRE HAZARDS ARE KNOWN TO BE
ASSOCIATED WITH THIS PRODUCT. HAZARDOUS PRODUCTS OF COMBUSTION: MAY FORM
METAL OXIDES, SODIUM OXIDE.
=======================================================
Control Measures
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Respiratory Protection: IF NEEDED USE A NIOSH APPROVED RESPIRATOR SUITABLE FOR
THE POTENTIAL EXPOSURE LEVEL. WORK HYGENIC PRACTICES (CONT): EATING
AND/OR SMOKING. REGULAR LAUNDERING OF CONTAMINATED CLOTHING IS ESSENTIA L TO
REDUCE INDIRECT SKIN CONTACT WITH THIS MATERIAL. LAUNDER CLOTHING BEFORE
REUSE.
Ventilation: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW LEVEL OF OVEREXPOSURE (FROM
KNOWN/EXPECTED ADVERSE EFFECTS).
Protective Gloves: WEAR IMPERVIOUS GLOVES TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYEWASH FOUNTAINS AND SAFETY SHOWERS
SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY OF POTENTIAL EXPOSURE. WEAR
IMPERVIOUS CLOTHING AND BOOTS (CONULT YOUR SAFETY EQUIPMENT SUPPLIER).
Work Hygienic Practices: AS WITH ALL PRODUCTS OF THIS NATURE, GOOD HYGIENE IS
ESSENTIAL. HANDS AND OTHER EXPOSED AREAS SHOULD BE THOROUGHLY WASHED WITH
SOAP AND WATER AFTER CONTACT, ESPECIALLY BEFORE (RESPIRATORY PROTECTION)
Supplemental Safety and Health: SPILL RELEASE PROCEDURES (CONT): COMPLETED.
STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO
SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR
ABS ORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS.
=======================================================
Physical/Chemical Properties
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Boiling Point: =100.C, 212.F
B.P. Text: @ 760 MM HG
Melt/Freeze Pt: =0.C, 32.F
M.P/F.P Text: (FREEZING POINT)
Vapor Pres: 17.500 RATIO @ 77.00 F.
Vapor Density: 1.0 @AIR=1
Spec Gravity: 1.050 - 1.100 @ 77.00 F.
PH: 6.5
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER.
Solubility in Water: MISCIBLE.
Percent Volatiles by Volume: 91.0%
=======================================================
Reactivity Data
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Stability Indicator: YES
Materials To Avoid: AVOID CONTACT WITH: ALKALI METALS, INTERHALOGEN COMPOUNDS,
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY FORM: METAL OXIDES, SODIUM OXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.
=======================================================
Toxicological Information
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Toxicological Information: THIS MIXTURE HAS NOT BEEN SPECIFICALLY TESTED.
FIRST AID (CONT): POISON CONTROL CENTER FOR ADVICE ABOUT WHETHER TO INDUCE
VOMITING. IF POSSIBLE, DO NOT LEAVE THE INDIVIDUAL UNATTENDED. INHALATI ON:
IF SYMPTOMS DEVELOP, MOVE THE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH
AIR. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN. KEEP PERSON WARM AND QUIE T; SEEK IMMEDIATE MEDICAL
ATTENTION. NOTE TO PHYSICIANS: PREEXISTING DISORDERS OF THE FOLLOWING ORGANS
(OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL: SKIN, LUNG
(FOR EXAMPLE, ASTH MA-LIKE CONDITIONS), (ECOLOGICAL INFO)
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Ecological Information
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Ecological: ECOTOXICOLOGICAL INFORMATION: THIS MIXTURE HAS NOT BEEN
SPECIFICALLY TESTED. TOXICOLOGICAL INFO (CONT): LIVER, KIDNEY,
EXPOSURE TO THIS MATERIAL MAY AGGRAVATE ANY PREEXISTING CONDITION SENSITIV E
TO A DECREASE IN AVAILABLE OXYGEN, SUCH AS CHRONIC LUNG DISEASE, CORONARY
ARTERY DISEASE OR ANEMIAS.
=======================================================
MSDS Transport Information
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Transport Information: DOT INFORMATION - 49 CFR 172.101: DOT DESCRIPTION:
NON-REGULATED BY D.O.T. CONTAINE / MODE: 55 GAL DRUM / TRUCK PACKAGE. NOS
COMPONENT: NONE. RQ (REPORTABLE QUANTITY) - 49 CFR 172.101: NOT APPLICAB LE.
=======================================================
Regulatory Information
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Sara Title III Information: SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A: NONE.
SECTION 311/312 HAZARD CLASS - 40 CFR 370.2: IMMEDIATE. SARA 313
COMPONENTS - 40 CFR 372.65: NONE.
Federal Regulatory Information: TSCA (TOXIC SUBSTANCES CONTROL ACT) STATUS:
TSCA (UNITED STATES) THE INTENTIONAL INGREDIENTS OF THIS PRODUCT ARE LISTED.
CERCLA RQ - 40 CFR 302.4(A): NONE LISTED. INTERNATIONAL REGULATIONS:
INVENTO RY STATUS: NOT DETERMINED.
State Regulatory Information: CALIFORNIA PROPOSITION 65: NONE.
=======================================================
Other Information
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Other Information: GENERAL OR GENERIC ID: ODOR CONTROL AGENT. REGULATORY
INFORMATION NUMBER: 1-800-325-3751. NFPA RATING: HEALTH-1,
FLAMMABILITY-0, REACTIVITY-0. PHYSICAL / CHEMICAL PROPERTIES (CON T):
LIQUID DENSITY: 8.740 - 9.150 LBS/GAL @ 77.00 F. 1.050 - 1.100 KG/L @ 25.00
C. PHYSICAL FORM: HOMOGENOUS SOLUTION. OTHER PRECAUTIONS (CONT):
STORE IN CLOSED CONTAINERS IN A DRY, WELL-VENTI LATED AREA. KEEP FROM
FREEZING.
=======================================================
HAZCOM Label
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MSDS NAME: ENZYBATE E ODOR CONTROL AGENT
Company: ASHLAND CHEMICAL CO
PO Box: 2219
City: COLUMBUS OH
Zipcode: 43216-2219
Health Emergency Phone: 800-274-5263
Label Required IND: Y
Date Of Label Review: 08/23/2001
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: CAN CAUSE EYE IRRITATION, STINGING, TEARING,
REDNESS, AND SWELLING OF EYES. CAN CAUSE SKIN IRRITATION, REDNESS AND BURNING
OF SKIN, AND OTHER SKIN DAMAGE. CAN BE ABSORBED THROUGH SKIN. SWALLOWI NG MAY
BE HARMFUL AND CAUSE STOMACH OR INTESTINAL UPSET, NAUSEA, VOMITING, AND
DIARRHEA. BREATHING MAY BE HARMFUL AND MAY CAUSE IRRITATION OF THE NOSE,
THROAT AND AIRWAYS, TIGHT FEELING IN CHEST, OR M USCLE WEAKNESS. CHRONIC:
NONE SPECIFIED BY MANUFACTURER.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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