| MSDS | : | CHLORINATED HYDROCARBONS MIXTURE, US-111 | | CAS | : | 75-09-2
91-58-7
95-50-1
541-73-1
106-46-7
118-74-1
87-68-3
77-47-4
67-72-1
1888-71-7
608-93-5
76-01-7
95-94-3
120-82-1 | | NAME | : | methane, dichloro-; (methylene chloride) (sara iii). ld50:(oral,rat)
naphthalene, 2-chloro-; (2-chloronaphthalene) (sara iii).
benzene, 0-dichloro-; (1,2-dichlorobenzene) (sara iii). ld50:(oral,rat)
benzene, m-dichloro-; (1,3-dichlorobenzene)
benzene, p-dichloro-; (1,4-dichlorobenzene) (sara iii). ld50:(oral,rat)
benzene, hexachloro-; (hexachlorobenzene) (sara iii). ld50:(oral,rat)
1,3-butadiene, hexachloro-; (hexachlorobutadiene) (sara iii). ld50:
1,3-cyclopentadiene, 1,2,3,4,5,5-hexachloro-; (hexachlorocyclopentadiene)
ethane, hexachloro-; (hexachloroethane) (sara iii)
propene, hexachloro-; (hexachloropropene) (sara iii)
benzene, pentachloro-; (pentachlorobenzene) (sara iii)
ethane, pentachloro-; (pentachloroethane) (sara iii)
benzene, 1,2,4,5-tetrachloro-; (1,2,4,5-tetrachlorobenzene) (sara iii).
benzene, 1,2,4,-trichloro-; (1,2,4-trichlorobenzene) (sara iii). ld50:
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ULTRA SCIENTIFIC -- CHLORINATED HYDROCARBONS MIXTURE, US-111
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Material Safety Data Sheet
=======================================================
MSDS Num: BSCJW
MSDS NAME: CHLORINATED HYDROCARBONS MIXTURE, US-111
Responsible Party
Name: ULTRA SCIENTIFIC
Address: 250 SMITH ST
City: NO KINGSTOWN RI 02852
Info Phone: 401-294-9400
Emergency Phone Number: 401-294-9400
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ULTRA SCIENTIFIC
Address: 250 SMITH STREET
City: NORTH KINGSTOWN RI 02852-5000
Phone: 401-294-9400
=======================================================
Ingredients
=======================================================
Cas: 75-09-2
RTECS #: PA8050000
Name: METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA III). LD50:(ORAL,RAT)
2136 MG/KG
% Wt: 98.04
OSHA PEL: 500 PPM;1000 PPM, C
ACGIH TLV: 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 91-58-7
RTECS #: QJ2275000
Name: NAPHTHALENE, 2-CHLORO-; (2-CHLORONAPHTHALENE) (SARA III).
LD50:(ORAL,RAT) 2078 MG/KG
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 95-50-1
RTECS #: CZ4500000
Name: BENZENE, 0-DICHLORO-; (1,2-DICHLOROBENZENE) (SARA III). LD50:(ORAL,RAT)
500 MG/KG
% Wt: 0.151
OSHA PEL: 50 PPM, C
ACGIH TLV: 25 PPM;50 STEL, S
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 541-73-1
RTECS #: CZ4499000
Name: BENZENE, M-DICHLORO-; (1,3-DICHLOROBENZENE)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 106-46-7
RTECS #: CZ4550000
Name: BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA III). LD50:(ORAL,RAT)
500 MG/KG
% Wt: 0.151
OSHA PEL: 75 PPM;110 STEL
ACGIH TLV: 75 PPM;110 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 118-74-1
RTECS #: DA2975000
Name: BENZENE, HEXACHLORO-; (HEXACHLOROBENZENE) (SARA III). LD50:(ORAL,RAT)
10,000 MG/KG
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 87-68-3
RTECS #: EJ0700000
Name: 1,3-BUTADIENE, HEXACHLORO-; (HEXACHLOROBUTADIENE) (SARA III). LD50:
(ORAL,RAT) 90 MG/KG
% Wt: 0.151
OSHA PEL: 0.02 PPM
ACGIH TLV: 0.02 PPM, S
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 77-47-4
RTECS #: GY1225000
Name: 1,3-CYCLOPENTADIENE, 1,2,3,4,5,5-HEXACHLORO-; (HEXACHLOROCYCLOPENTADIENE)
(SARA III). LD50: (ORAL,RAT) 584 MG/KG
% Wt: 0.151
OSHA PEL: 0.01 PPM
ACGIH TLV: 0.01 PPM
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 67-72-1
RTECS #: KI4025000
Name: ETHANE, HEXACHLORO-; (HEXACHLOROETHANE) (SARA III)
% Wt: 0.151
OSHA PEL: 1 PPM, S
ACGIH TLV: 1 PPM, S
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 1888-71-7
RTECS #: UD0175000
Name: PROPENE, HEXACHLORO-; (HEXACHLOROPROPENE) (SARA III)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 608-93-5
RTECS #: DA6640000
Name: BENZENE, PENTACHLORO-; (PENTACHLOROBENZENE) (SARA III)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 76-01-7
RTECS #: KI6300000
Name: ETHANE, PENTACHLORO-; (PENTACHLOROETHANE) (SARA III)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 95-94-3
RTECS #: DB9450000
Name: BENZENE, 1,2,4,5-TETRACHLORO-; (1,2,4,5-TETRACHLOROBENZENE) (SARA III).
LD50: (ORAL,RAT) 1500 MG/KG
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 120-82-1
RTECS #: DC2100000
Name: BENZENE, 1,2,4,-TRICHLORO-; (1,2,4-TRICHLOROBENZENE) (SARA III). LD50:
(ORAL,RAT) 756 MG/KG
% Wt: 0.151
OSHA PEL: 5 PPM, C
ACGIH TLV: 5 PPM, C
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: CONTAINS CARCINOGEN(S) OR CANCER SUSPECT AGENT(S). TOXIC:
IRRITANT. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS - DIRECT PHYSICAL
CONTACT SHOULD BE AVOIDED. CHLOROCARBON MATLS HAVE PRODUCED SENSITIZA TION OF
THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS AND COULD HAVE SIMILAR EFFECT IN
HUMANS. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: METHYLENE CHLORIDE:IARC MONOGRAPHS SUPPLEMENT,
VOL 7, PG 194, 1987:GRP 2B. NTP 6TH ANNUAL REPORT ON CARCINS, (SUPP DATA)
Signs And Symptions Of Overexposure: HLTH HAZ: ADRENOMIMETICS (E.G.,
EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS (FP N).
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE/SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. INHAL: REMOVE TO
FRESH AIR - GIVE OXYGEN, IF NECESSARY. CONTACT PHYSICIAN. INGEST: GET MD
IMMEDIATELY (FP N).
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Handling and Disposal
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Spill Release Procedures: DUE TO THE SMALL QUANTITIY INVOLVED, SPILLS OR LEAKS
SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLES MAY BE PLACED IN A
PLASTIC BAG AND NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE
ABSORBED ON VERMICULITE OR SAND.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURN IN A CHEMICAL INCINIERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FFFEDERAL, STATE, AND LOCAL LAWS
CONCERNING DISPOSAL.
Handling And Storage Precautions: USE APPROPRIATE NIOSH/MSHA APPROVED SAFETY
EQUIPMENT. KEEP TIGHTLY CLOSED, AND STORE IN A COOL, DRY PLACE.
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF
ARC WELDING, HOT SURFACES OR OPEN FLAMES. HEAT AND/OR UV RADIATION MAY CAUSE
THE FORMATION OF HCL &/OR PHOSGENE (FP N).
=======================================================
Fire and Explosion Hazard Information
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Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER, OR WATER SPRAY.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL
&/OR PHOSGENE (FP ).
=======================================================
Control Measures
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Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPROVED CHEMICAL WORKERS (SUPP)
Other Protective Equipment: CHEMICAL RESISTANT CLOTHING SUCH AS LAB COAT AND/OR
A RUBBER APRON TO PREVENT CONTACT WITH EYES, SKIN & CLOTHING.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: CARCIN COMMENTS: 1991: ANTICIPATED TO BE A
CARCINOGEN. BENZENE, P-DICHLORO: IARC MONOGRAPHS SUPPLEMENT, VOL 7, PG 192,
1987: GRP 2B. NTP 6TH ANNUAL REPORT ON CARCINOGENS; ANTICIPATED TO BE
CARCINOGEN. EYE PROTECTION: GOGGLES WITH FULL LENGTH FACESHIELD (FP N).
=======================================================
Physical/Chemical Properties
=======================================================
HCC: T6
Appearance and Odor: LIQUID.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZERS.
Hazardous Decomposition Products: HCL, PHOSGENE (FP N).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: CHLORINATED HYDROCARBONS MIXTURE, US-111
Company: ULTRA SCIENTIFIC
Street: 250 SMITH STREET
City: NORTH KINGSTOWN RI
Zipcode: 02852-5000
Health Emergency Phone: 401-294-9400
Label Required IND: Y
Date Of Label Review: 10/27/1993
Status Code: C
Label Date: 10/27/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. ACUTE:
INHALATION OF VAPORS MAY CONTRIBUTE TO THE OCCURRENCE OF IRREGULAR HEARTBEAT
(FP N). IRRITANT. CHRONIC: CANCER HAZARD. CONTAINS METHYLENE CHLORIDE AND
BENZENE, P-DICHLORO-, WHICH ARE LISTED AS CARCINOGENS (FP N).
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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