| MSDS | : | SCOTCHCAL BRAND SCREEN PRINTING INK 6605I | | CAS | : | 763-69-9
108-65-6
9010-88-2
9011-14-7
1333-86-4
80-62-6
108-88-3
140-88-5 | | NAME | : | ing 12:depress:signs/symps can incl hdch, dizz, drow, musc weak,
ing 13: vision, slurred speech, gidd, tremors & convls. carbon black
ing 14:haz causing stom & skin cancer by dietary route of expos in
ing 15: cancer haz causing stomach cancer by oral route of expos in lab
spill proc: tools. cover w/absorb matl. clean up residue. place in u.s.
vent: ventilation is not adequate, use appropriate niosh/msha approved
propionic acid, 3-ethoxy-, ethyl ester; (ethyl-3-ethoxypropionate)
acetic acid, 2-methoxy-1-methylethyl ester; (1-methoxy-2-propyl acetate)
2-propanoic acid,2-methyl-methyl ester polymer w/(lucite 30); ethyl
polymethylmethacrylate; (poly(methyl methacrylate)
carbon black
methacrylic acid, methyl ester; (methyl methacrylate) (sara 313) (cercla)
toluene (sara 313) (cercla)
acrylic acid, ethyl ester; (ethyl acrylate) (sara 313) (cercla)
volatile organic compound: <910 g/l
supdat: w/one or more s in prod & are reqd to be incl on msds
ing 10: during foreseeable use of prod. kidney efts: signs/symps can incl
ing 11: back pain. liver efts: signs/symps can incl yellow skin
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3M GENERAL OFFICES -- SCOTCHCAL BRAND SCREEN PRINTING INK 6605I
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Material Safety Data Sheet
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MSDS Num: BSBKC
MSDS NAME: SCOTCHCAL BRAND SCREEN PRINTING INK 6605I
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
=======================================================
Contractor Summary
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Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
=======================================================
Ingredients
=======================================================
Name: ING 12:DEPRESS:SIGNS/SYMPS CAN INCL HDCH, DIZZ, DROW, MUSC WEAK,
INCOORDINATION, SLOWED RXN TIME, FATG, BLURRED
-----------------------------
Name: ING 13: VISION, SLURRED SPEECH, GIDD, TREMORS & CONVLS. CARBON BLACK
(BENZENE SOLV EXTRACTS) IS POTNTL CANCER
-----------------------------
Name: ING 14:HAZ CAUSING STOM & SKIN CANCER BY DIETARY ROUTE OF EXPOS IN
LAB ANIMAL STUDIES. ETHYL ACRYLATE IS POTNTL
-----------------------------
Name: ING 15: CANCER HAZ CAUSING STOMACH CANCER BY ORAL ROUTE OF EXPOS IN LAB
ANIMAL STUDIES.
-----------------------------
Name: SPILL PROC: TOOLS. COVER W/ABSORB MATL. CLEAN UP RESIDUE. PLACE IN U.S.
DOT-APPRVD CNTNR & SEAL.
-----------------------------
Name: VENT: VENTILATION IS NOT ADEQUATE, USE APPROPRIATE NIOSH/MSHA APPROVED
RESPIRATORY PROTECTION.
-----------------------------
Cas: 763-69-9
RTECS #: UF3325000
Name: PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL-3-ETHOXYPROPIONATE)
% Wt: 15-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 108-65-6
RTECS #: AI8295000
Name: ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY-2-PROPYL ACETATE)
% Wt: 15-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9010-88-2
Name: 2-PROPANOIC ACID,2-METHYL-METHYL ESTER POLYMER W/(LUCITE 30); ETHYL
ACRYLATE-METHYL METHACRYLATE POLYMER
% Wt: 15-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY(METHYL METHACRYLATE)
% Wt: 10-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1333-86-4
RTECS #: FF5800000
Name: CARBON BLACK
% Wt: 1-5
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
Cas: 80-62-6
RTECS #: OZ5075000
Name: METHACRYLIC ACID, METHYL ESTER; (METHYL METHACRYLATE) (SARA 313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA 313) (CERCLA)
% Wt: 0.1-0.5
OSHA PEL: 200 PPM
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 140-88-5
RTECS #: AT0700000
Name: ACRYLIC ACID, ETHYL ESTER; (ETHYL ACRYLATE) (SARA 313) (CERCLA)
% Wt: <0.1
OSHA PEL: 25 PPM, S
ACGIH TLV: 5 PPM; 15 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: <910 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: SUPDAT: W/ONE OR MORE INGREDS IN PROD & ARE REQD TO BE INCL ON MSDS
BY OSHA, THEY ARE NOT EXPECTED EFTS
-----------------------------
Name: ING 10: DURING FORESEEABLE USE OF PROD. KIDNEY EFTS: SIGNS/SYMPS CAN INCL
REDUCED URINE VOL, BLOOD IN URINE &
-----------------------------
Name: ING 11: BACK PAIN. LIVER EFTS: SIGNS/SYMPS CAN INCL YELLOW SKIN
(JAUNDICE) & TENDERNESS OF UPPER ABDOM. CNS
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES:MOD IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELL, PAIN,
TEARING & HAZY VISION. SKIN: MILD IRRIT: SIGNS/SYMPS CAN INCL REDNESS,
SWELL & ITCH. INHAL: CNS DEPRESS: SIGNS/SYMPS CAN INCL HDCH, DIZZ, DRO W,
INCOORDINATION, SLOWED RXN TIME, SLURRED SPEECH, GIDD & UNCON. IRRIT
(UPPER RESP): SIGNS/SYMPS CAN (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:INCL SORENESS OF NOSE &
THROAT, COUGH & SNEEZING. INGEST:MAY CAUSE IRRIT OF GI TISS: SIGNS/SYMPS
CAN INCL PAIN, VOMIT, ABDOM TENDERNESS, NAUS, BLOOD IN VOMITUS & IN
FECES. CHRONIC:TOLUENE APP EARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK
CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MIN. GET MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH LARGE AMOUNTS OF
WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHAL: REMOVE TO FRESH
AIR. IF NOT BREATHING,GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GET IMMEDIATE MEDICAL ATTENTION. INGEST: DO NOT INDUCE VOMITING. DRINK TWO
GLASSES OF WATER. CALL MD.
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Handling and Disposal
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Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING
PHYSICAL & HLTH HAZS, RESP PROT, VENT & PERSONAL PROT EQUIP. CALL
612-733-1110 OR 612-733-6100 FOR 24-HR SPILL ASSISTANCE. VENT AREA. EXTING
ALL IGNI T SOURCES. COLLECT USING NON-SPARKING
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). INCINERATE IN A PERMITTED HAZ WASTE INCINERATOR. DISPOSE
OF WASTE PROD IN FACILITY PERMITTED TO ACCEPT CHEMICAL WASTE. RECLAIM IF FEAS
IBLE. U.S. EPA HAZ WASTE NO = D001 (IGNITABLE).
Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
CONTAINER IN WELL VENTILATED AREA.
Other Precautions: KEEP CNTNR TIGHTLY CLSD. KEEP AWAY FROM HEAT, SPK, OPEN
FLAME & OTHER IGNIT SOURCES. PVNT ALL SOURCES OF IGNIT. GROUND CNTNRS
SECURELY WHEN TRANSFERRING CONTENTS. WEAR LOW STATIC/PROPERLY GROUNDED SHO
ES. COMBUST LIQ & VAP. NO SMOKING.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 110F,43C
Lower Limits: 1%
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NOT DETERMINED.
=======================================================
Control Measures
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Respiratory Protection: AVOID PRLNG BREATHING OF VAPORS. SELECT ONE OF
FOLLOWING NIOSH/MSHA APPROVED RESPIRATORS BASED ON AIRBORNE CONCENTRATION OF
CONTAMINANTS & I/A/W/ OSHA REGS: HALF-MASK ORGANIC VAP RESPIRATOR,
FULL-FACE ORGANIC VAPOR RESPIRATOR.
Ventilation: USE W/APPROP LOC EXHST VENT. PROVIDE SUFFICIENT VENT TO MAINTAIN
EMISSIONS BELOW RECOM EXPOS LIMS. IF EXHST
Protective Gloves: NITRILE RUBBER.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: AVOID PROLONGED OR REPEATED SKIN CONTACT. WEAR
APRON, COVERALLS AS NECESSARY TO PREVENT SKIN CONTACT.
Work Hygienic Practices: DO NOT EAT/DRINK/SMOKE WHEN USING PROD. WASH EXPOS
AREAS THORO W/SOAP & WATER. WASH HANDS AFTER HNDLG & BEFORE EATING.
Supplemental Safety and Health: EFTS OF OVEREXP: HAZ LIST INFO & SAFE HNDLG
& EXPOS INFO (FP N). PRLNG/RPTD OVEREXP ABOVE RECOM GUIDELINES MAY CAUSE:
KIDNEY EFTS: SIGNS/SYMPS CAN INCL REDUCED URINE VOL, BLOOD IN URINE &
BACK PAIN. L IVER EFTS: SIGNS/SYMPS CAN INCL YELLOW SKIN (JAUNDICE) &
TENDERNESS OF ABDOMEN. WHILE FOLLOWING EFTS ARE ASSOC
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Physical/Chemical Properties
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B.P. Text: >295F,>146C
Vapor Pres: <4
Vapor Density: >1
Spec Gravity: 1.1-1.4(H*2O=1)
Solubility in Water: MODERATE
Appearance and Odor: LIQUID, BLACK; SWEET SOLVENT ODOR.
Percent Volatiles by Volume: 45-65
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: SCOTCHCAL BRAND SCREEN PRINTING INK 6605I
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 03/24/1993
Status Code: C
Label Date: 03/24/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. KEEP AWAY FROM HEAT & OPEN FLAME.
ACUTE:EYE:CAUSES SEVERE IRRITATION. SKIN:MAY CAUSE IRRITATION UPON PROLONGED
OR REPEATED CONTACT. MAY BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INHAL:
MAY CAUSE RESPIRATORY SYSTEM IRRITATION& NERVOUS SYSTEM IMPAIRMENT.
MODERATELY TOXIC BY INGESTION. MAY CAUSE NAUSEA, VOMITING, DIARRHEA &
NARCOSIS. CHRONIC:TOLUENE APPEARS ON THE NAVY LISTING OF OCCUP ATIONAL
CHEMICAL REPRODUCTIVE HAZARDS (FP N). MAY CAUSE KIDNEY OR LIVER DAMAGE.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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