| MSDS | : | R-11, CFC-11, REFRIGERANT 11 | | CAS | : | 75-69-4 | | NAME | : | methane, trichlorofluoro-; (trichloromonofluoromethane) (sara iii)
supdat:if such options are not avail, then matl shld be sent to epa
ing 2:meet definition of "u" listed waste. 2)chem addns,
ing 3:management info presented in this msds incomplete, inaccurate or
other prot equip:could occur, use prot clthg such as butyl rubber,
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LAROCHE CHEMICALS INC -- R-11, CFC-11, REFRIGERANT 11
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BSQMB
MSDS NAME: R-11, CFC-11, REFRIGERANT 11
Responsible Party
Name: LAROCHE CHEMICALS INC
Box: 5500
City: GRAMEREY LA 70052
Info Phone: 800-526-4963
Emergency Phone Number: 800-424-9300(CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LAROCHE CHEMICALS INC
Address: AIRLINE HWY
Box: 1031
City: BATON ROUGE LA 70821
Phone: 504-356-8467
=======================================================
Ingredients
=======================================================
Cas: 75-69-4
RTECS #: PB6125000
Name: METHANE, TRICHLOROFLUORO-; (TRICHLOROMONOFLUOROMETHANE) (SARA III)
% Wt: >99.9
OSHA PEL: 1000 PPM, C
ACGIH TLV: 1000 PPM, C
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
Ozone Depleting Chemical: 1
------------------------------
Name: SUPDAT:IF SUCH OPTIONS ARE NOT AVAIL, THEN MATL SHLD BE SENT TO EPA
APPRVD INCIN. NOTE:1)USED/SPENT R-11 DOES NOT
-----------------------------
Name: ING 2:MEET DEFINITION OF "U" LISTED WASTE. 2)CHEM ADDNS,
PROCESSING/OTHERWISE ALTERING THIS MATL MAY MAKE WASTE
-----------------------------
Name: ING 3:MANAGEMENT INFO PRESENTED IN THIS MSDS INCOMPLETE, INACCURATE OR
OTHERWISE INAPPROPRIATE.
-----------------------------
Name: OTHER PROT EQUIP:COULD OCCUR, USE PROT CLTHG SUCH AS BUTYL RUBBER,
IMPERVIOUS TO THIS MATERIAL.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CHLOROFLUOROCARBON (CFC) MATLS HAVE PRDCD SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIM EFT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-S
USTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CFC'S (FP N). EYE:NOT
READILY ABSORBED THRU MUC(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:MEMB/TISS; HOWEVER, MAY CAUSE
FROSTBITE IF EXPOSED TO DIRECT SPRAY. SKIN:NOT READILY ABSORBED THRU
SKIN;HOWEVER, MAY CAUSE FROSTBITE IF EXPOSED TO DIRECT SPRAY; LIQ NOT
INJURIOUS IF PROMPTLY WASHED AWAY. INHAL:MAY CAUSE NARCOSIS IN CONCS
>1000 PPM; MAY CAUSE ASPHY IN HIGH CONCS. MAY CAUSE UNCON/PARAL (SUPDAT)
Medical Cond Aggravated By Exposure: PERSONS W/CARDIAC ARRHYTHMIA MAY BE AT
INCREASED RISK IN SEVERE EXPOSURE.
First Aid: EYE:FLUSH W/WATER FOR AT LEAST 15 MINUTES; GET MEDICAL ATTENTION IF
IRRITATION PERSISTS. SKIN:FLUSH W/WATER; GET MEDICAL ATTENTION IF REDDENING
DEVELOPS. INHAL:REMOVE FROM CONTAMINATED AREA; APPLY OXY GEN IF BREATHING IS
DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED & GET
MEDICAL ATTENTION. INHAL:COMPOUND NOT NORMALLY CONSIDERED HAZ BY INGEST; GET
MEDICAL ATTENTION AS NECESSARY.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: STOP DISCHARGE IF POSS. KEEP PEOPLE AWAY. AVOID CONT
W/LIQ. ISOLATE & REMOVE DISCHARGED MATL. SHLD SPILL OCCUR INTO AIR,
WATER/ONTO LAND, NOTIFICATION TO NRC (800-424-8802) WILL BE REQD IF SPILL
EXCEE DS ESTABLISHED REPORTABLE QTY (5000 LBSOR(SUPDAT)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: TRICHLOROMONOFLUOROMETHANE(R-11) AS COMMERCIALLY PRDCD
IS LISTED AS HAZ WASTE (U121). DISP OF THIS PROD MUST BE I/A/W APPROP FED,
STATE & LOC ENVIRON LAWS & REGS. DO NOT VENT TO ATM. DO NOT DISCHARGE
TO GROUND/WATER. IT IS REC THAT PROD WASTE(SUPDAT)
Handling And Storage Precautions: STORE IN WELL-VENTED, DRY AREA (<125F);
CONT W/FLAMES OR HIGH TEMPS SHLD BE AVOIDED.
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV
RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR PHOSGENE (FP N).
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: AS APPROPRIATE FOR COMBUSTIBLE IN AREA.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
FLUORIDES, CHLORIDES & PHOSGENE (FP N). MAY DECOMPOSE TO FORM HALOGEN
ACID &/OR PHOSGENE AT TEMPERATURES >600C.
=======================================================
Control Measures
=======================================================
Respiratory Protection: ATM LEVELS SHLD BE MAINTAINED BELOW EXPOS GUIDELINES.
WHERE EXPOS GUIDELINE MAY BE GREATLY EXCEEDED, USE NIOSH/MSHA APPRVD POS
PRESS SCBA. IN CONFINED/POORLY VENTED AREAS, USE NIOSH/MSHA APPRVD POS SC BA.
Ventilation: CTL AIRBORNE CONCS BELOW EXPOS GUIDELINES. USE ONLY W/ADEQ VENT.
LOC EXHST VENT MAY BE NEC FOR SOME OPERATIONS.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: FOR BRIEF CONT, NO PRECS OTHER THEN CLEAN
BODY-COVERING CLTHG SHLD BE NEEDED. WHEN PRLNG/FREQUENTLY RPTD CONT
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MATLS TO AVOID:SHAVINGS, GRANULAR BARIUM. EFTS
OF OVEREXP:IF EXPOSED TO HIGH CONCS. INGEST:NOT LIKELY DUE TO LOW VOLAT.
SPILL PROC:GREATER). FOR ADDNL ASSISTANCE IN ANY TRANSPORTATION EMER, CALL
CHEMT REC 1-800-424-9300. WASTE DISP METH:BE COLLECTED FOR POSS
RECYLE/RECLAMATION ACTIVITIES.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 74.8F,23.8C
Vapor Pres: 694 @ 70F
Vapor Density: 5.1
Spec Gravity: 1.46 (H*2O=1)
Evaporation Rate & Reference: 0.4 (ETHER=1)
Solubility in Water: 0.011%
Appearance and Odor: COLORLESS LIQUID; FAINT ETHEREAL ODOR.
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID OPEN FLAMES & HIGH TEMPERATURES.
Materials To Avoid: CHEMICALLY-ACTIVE METALS SUCH AS SODIUM, POTASSIUM,
CALCIUM, POWDERED ALUMINUM, ZINC, MAGNESIUM & LITHIUM (SUPDAT)
Hazardous Decomposition Products: CHLORIDES, FLUORIDES & PHOSGENE (FP N). MAY
DECOMPOSE TO HALOGEN ACIDS OR PHOSGENE AT TEMPERATURES >600C.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: R-11, CFC-11, REFRIGERANT 11
Company: LAROCHE CHEMICALS INC
Street: AIRLINE HWY
PO Box: 1031
City: BATON ROUGE LA
Zipcode: 70821
Health Emergency Phone: 800-424-9300(CHEMTREC)
Label Required IND: Y
Date Of Label Review: 04/14/1993
Status Code: C
Label Date: 04/14/1993
Origination Code: G
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: AVOID CHEMICALLY-REACTIVE METALS (SODIUM, CALCIUM,
POWDERED ALUMINUM, ZINC, ETC). DECOMPOSITION PRODUCTS HAZARDOUS.
ACUTE:EYE:MAY CAUSE FROSTBITE IF EXPOSED TO DIRECT SPRAY. SKIN:MAY CAUSE
FROSTBITE I F EXPOSED TO DIRECT SPRAY; LIQUID NOT INJURIOUS IF PROMPTLY
WASHED AWAY. INHAL:MAY CAUSE NARCOSIS OR ASPHYXIATION IN HIGH CONCENTRATIONS.
MAY CAUSE UNCONSCIOUSNESS OR PARALYSIS & MAY CAUSE IRREGULAR H EARTBEAT.
INGEST:NOT LIKELY. CHRONIC: NONNE LISTED BY MFR.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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DE-SOLV-IT
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WINDSHIELD WASH SOLVENT & ANTIFREEZE-CONCENTRATED
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MIL-C-83286B TYPE 27886, 03W163
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62-4615-1730-2, CITRUS BASE INDUSTRIAL (SUPDAT)
| |
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SCOTCHCAL BRAND SCREEN PRINTING INK 6613I
| 763-69-9
108-65-6
12656-85-8
9010-88-2
9011-14-7
80-62-6
108-88-3
140-88-5 |
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SCOTCHCAL BRAND SCREEN PRINTING INK 6619I - PART A
| 108-65-6
763-69-9
9011-14-7
9010-88-2
80-62-6
108-88-3
140-88-5 |
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SCOTCHCAL BRAND SCREEN PRINTING INK 6619I - PART B
| 7440-50-8
7440-66-6
57-11-4 |
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SCOTCHCAL BRAND SCREEN PRINTING INK 6635I
| 763-69-9
108-65-6
9010-88-2
9011-14-7
4051-63-2
80-62-6
108-88-3
140-88-5 |
|
R-11, CFC-11, REFRIGERANT 11
| 75-69-4 |
|
GCO-30, 02295
| |
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PENTA PRESERVATIVE READY TO USE, 8260
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SAFETEE H. I. MASTIC
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MODEL 1640 PHOTOCONDUCTOR
| 7429-90-5
7782-49-2
13494-80-9 |
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REAGENT PACKAGE (FREE CHLORINE) (400 TESTS), 10426
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SUPER STRENGTH ADHESIVE, 6004
| 78-93-3
9005-09-8
25068-38-6 |
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VINEX RESINS, VX1002
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VINEX RESINS, VX1003
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VINEX RESINS, VX2019
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VINEX RESINS, VX2025
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VINEX RESINS, VX2034
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SPARMITE BARYTES
| 7440-41-7
7440-47-3
7727-43-7
14808-60-7
7440-38-2
7440-43-9
7439-92-1 |
|
JET-MELT ADHESIVE 3765-AE
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JET-MELT ADHESIVE 3765-PG
| |
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JET-MELT ADHESIVE 3765-TC
| |
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JET-MELT ADHESIVE 3765-TC-Q
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JET-MELT ADHESIVE 3765-Q (PD)
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BLUE SILICONE GASKET MAKER, 49206
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BLUE SILICONE GASKET MAKER, 49296
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BLUE SILICONE GASKET MAKER, 49236
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HYDRAULIC CEMENT TYPE I
| 10034-77-2
12042-78-3
12068-35-8
13397-24-5
65997-15-1
12168-85-3 |
|
HYDRAULIC CEMENT TYPE II
| 65997-15-1
12168-85-3
10034-77-2
12042-78-3
12068-35-8
13397-24-5 |
|
HYDRAULIC CEMENT TYPE III
| 13397-24-5
65997-15-1
12168-85-3
10034-77-2
12042-78-3
12068-35-8 |
|
TINT-AYD UL 20-42A ORGANIC YELLOW-MEDIUM (L.F.)
| |
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TINT-AYD ST 8703 PHTHALO GREEN
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TINT-AYD AL-492 ORGANIC YELLOW-MEDIUM (LOW FADE)
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DU-RUST, 418
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FINAL TOUCH CONTROL SPRAY ENAMEL, 70000 SERIES
| 67-64-1
64742-89-8
108-88-3
1330-20-7
111-76-2
106-97-8
74-98-6 |
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BLACK RE-INKING FLUID
| |
|
RED RE-INKING FLUID
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BLUE RE-INKING FLUID
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GREEN RE-INKING FLUID
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VIOLET RE-INKING FLUID
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SQR LITH PROCESSOR REPLENISHER- PART CR
| 7732-18-5
584-08-7
111-42-2
1303-96-4
141-43-5
1310-58-3 |
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ANIONIC SURFACTANT SOLUTION, 23755
| 36445-71-3
70146-13-3
7647-14-5
7757-82-6
7732-18-5 |
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CATALYST, S-4
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ECO-STS TILE RED-STD TRAFFIC SYSTEM PART A, 08557
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ECO-STS (450)-STD TRAFFIC SYSTEM PART B, 08546
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DL PERMATEX FAST ORANGE FINE PUMICE HAND (SUPP DATA)
| 9003-01-4
8006-54-0
26172-55-4
2682-20-4
61789-91-1
8001-97-6
7732-18-5
5989-27-5
1332-09-8
69013-18-9
102-71-6 |
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DL PERMATEX FAST ORANGE FINE PUMICE HAND (SUPP DATA)
| 7732-18-5
5989-27-5
1332-09-8
69013-18-9
102-71-6
9003-01-4
8006-54-0
26172-55-4
2682-20-4
61789-91-1
8001-97-6 |
|
DL PERMATEX FAST ORANGE FINE PUMICE HAND (SUPP DATA)
| 1332-09-8
69013-18-9
102-71-6
9003-01-4
8006-54-0
26172-55-4
2682-20-4
61789-91-1
8001-97-6
7732-18-5
5989-27-5 |
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