| MSDS | : | SCOTCHCAL BRAND SCREEN PRINTING INK 6613I | | CAS | : | 763-69-9
108-65-6
12656-85-8
9010-88-2
9011-14-7
80-62-6
108-88-3
140-88-5 | | NAME | : | ing 11:vomit, abdom spasms, weak, anemia, lead-line on gums & coma.
ing 12:norm cndtns of use. note:toluene & lead cmpnds appr on navy
ing 13:from approp hlth profs concerning latest haz list info & safe
other prot equip:needed to prevent contact during handling, transferring,
propionic acid, 3-ethoxy-, ethyl ester; (ethyl-3-ethoxypropionate)
acetic acid, 2-methoxy-1-methylethyl ester; (1-methoxy-2-propyl acetate)
molybdate orange; (lead chromate/sulfate orange) (limits given as lead)
2-propanoic acid, 2-methyl-methyl ester polymer; (ethyl acrylate-methyl
polymethylmethacrylate; (poly(methyl methacrylate))
methacrylic acid, methyl ester; (methyl methacrylate) (sara iii)
toluene (sara iii)
acrylic acid, ethyl ester; (ethyl acrylate) (sara iii)
volatile organic compounds. %: <770 g/l.
supdat:cummulative pois. lead causes peripheral nerve dmg, kidney, liver
ing 10:deterioration, abnormal sperm morphology & fetal efts. symps
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3M GENERAL OFFICES -- SCOTCHCAL BRAND SCREEN PRINTING INK 6613I
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BSQLB
MSDS NAME: SCOTCHCAL BRAND SCREEN PRINTING INK 6613I
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
=======================================================
Ingredients
=======================================================
Name: ING 11:VOMIT, ABDOM SPASMS, WEAK, ANEMIA, LEAD-LINE ON GUMS & COMA.
INGEST IS NOT EXPECTED RTE OF EXPOS UNDER
-----------------------------
Name: ING 12:NORM CNDTNS OF USE. NOTE:TOLUENE & LEAD CMPNDS APPR ON NAVY
LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULT
-----------------------------
Name: ING 13:FROM APPROP HLTH PROFS CONCERNING LATEST HAZ LIST INFO & SAFE
HNDLG & EXPOS RECOMS (FP N).
-----------------------------
Name: OTHER PROT EQUIP:NEEDED TO PREVENT CONTACT DURING HANDLING, TRANSFERRING,
EQUIPMENT CLEANUPS & SPILL CLEANUPS.
-----------------------------
Cas: 763-69-9
RTECS #: UF3325000
Name: PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL-3-ETHOXYPROPIONATE)
% Wt: 15-35
Other REC Limits: 50 PPM;100 STEL(MFR)
------------------------------
Cas: 108-65-6
RTECS #: AI8295000
Name: ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY-2-PROPYL ACETATE)
% Wt: 15-35
Other REC Limits: 100 PPM (MFR)
------------------------------
Cas: 12656-85-8
RTECS #: QA4660000
Name: MOLYBDATE ORANGE; (LEAD CHROMATE/SULFATE ORANGE) (LIMITS GIVEN AS LEAD)
% Wt: 20-25
OSHA PEL: 0.05 MG/M3
ACGIH TLV: 0.15 MG/M3
------------------------------
Cas: 9010-88-2
Name: 2-PROPANOIC ACID, 2-METHYL-METHYL ESTER POLYMER; (ETHYL ACRYLATE-METHYL
METHACRYLATE POLYMER)
% Wt: 5-25
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY(METHYL METHACRYLATE))
% Wt: 5-25
------------------------------
Cas: 80-62-6
RTECS #: OZ5075000
Name: METHACRYLIC ACID, METHYL ESTER; (METHYL METHACRYLATE) (SARA III)
% Wt: 0.1-0.5
OSHA PEL: 100 PPM (MFR)
ACGIH TLV: 100 PPM (MFR)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
Name: TOLUENE (SARA III)
% Wt: 0.1-0.5
OSHA PEL: 100 PPM;150 PPM STEL
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 140-88-5
RTECS #: AT0700000
Name: ACRYLIC ACID, ETHYL ESTER; (ETHYL ACRYLATE) (SARA III)
% Wt: <0.1
OSHA PEL: 5 PPM;25 PPM STEL, S
ACGIH TLV: 5 PPM;15 PPM STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS. %: <770 G/L.
% Wt: SEE ING
-----------------------------
Name: SUPDAT:CUMMULATIVE POIS. LEAD CAUSES PERIPHERAL NERVE DMG, KIDNEY, LIVER
& BLOOD DMG, ENCEPHALOPATHY, MENTAL
-----------------------------
Name: ING 10:DETERIORATION, ABNORMAL SPERM MORPHOLOGY & FETAL EFTS. SYMPS
OF LEAD ACCUM IN BODY MAY INCL HDCH, NAUS,
=======================================================
Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: EYE:CAUSES SEV IRRIT. SKIN:MAY CAUSE IRRIT UPON PRLNG/RPTD
CONT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INHAL:MAY CAUSE RESP SYS
IRRIT & NERV SYS IMPAIRMENT. PRLNG/RPTD EXPOS CAN CAUSE KIDNEY &/OR
LIVER EFTS. IARC REPORTS THAT THERE ISSUFFICIENT EVID OF CARCIN PROVIDED BY
EXPTL STUDIES IN LAB (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: LEAD CHROMATE: GROUP 1, (IARC VOL49, P49,
1990).
Signs And Symptions Of Overexposure: HLTH HAZ:ANIMALS EXPOSED TO LEAD CHROMATE.
IARC REPORTS THAT THERE IS SUFFICIENT EVID OF RESP CARCIN IN MEN OCCUP
EXPOSED DURING CHROMATE PROD, BUT INSUFFICIENT DATA ON LUNG CANCER IN OTHER
OCCUPS & F OR CANCER AT OTHER SITES TO ALLOW FOR EVAL OF POTNTL RISK OF
CANCER IN HUMANS. EXPOS TO MISTS MAY CAUSE BLOOD & (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE:IMMED FLUSH W/PLENTY OF WATER & CONTINUE FOR AT LST 15 MINS
HOLDING EYE LIDS OPEN. CALL MD. SKIN:WASH W/SOAP & WATER. INHAL:REMOVE
PERSON TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN. IF BRTHG HA S STOPPED,
GIVE ARTF RESP. KEEP PERSON WARM & QUIET. CALL MD. INGEST:DO NOT INDUCE
VOMIT. GIVE ONE TO TWO GLASSES OF WATER. CALL MD.
=======================================================
Handling and Disposal
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Spill Release Procedures: OBSERVE ALL PRECS IN PRECAUTIONARY INFO SECTION.
EXTING ALL IGNIT SOURCES. COLLECT SPILLED MATL, CLEAN UP RESIDUE & PLACE
IN DOT APPRVD CNTNR. USE ABSORB MATL AS NEEDED IN CLEANUP PROC.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: RECLAMATION/INCIN IN PERMITTED HAZ WASTE FACILITY
CAPABLE OF MEETING APPLIC REGULATORY RQMTS FOR DESTRUCT & REMOVAL IS
PREF. OTHERWISE DISPOSE I/A/W APPLIC FED, STATE & LOC REGS. U.S. EPA HAZ
WASTE #: D001 (IGNITABLE), D008 (LEAD) & D007 (CHROMIUM).
Handling And Storage Precautions: COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT,
SPARKS & OPEN FLAME. PREVENT ALL SOURCES OF IGNITION. KEEP CONTAINERS
CLOSED WHEN NOT IN USE.
Other Precautions: GROUND CONTAINERS SECURELY WHEN TRANSFERRING CONTENTS. DO
NOT GET IN EYES. AVOID SKIN CONTACT. AVOID PROLONGED EXPOSURE TO ELEVATED
CONCENTRATIONS OF VAPORS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 110F,43C
Lower Limits: 1%
Extinguishing Media: CARBON DIOXIDE, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: COMBUSTIBLE LIQUID.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR (OR
EQUIVALENT) FOR SUPPLEMENTAL PROTECTION WHERE NEEDED (E.G., SPILLS, CLEANUP
ACTIVITIES).
Ventilation: USE LOCAL & GENERAL VENTILATION TO MAINTAIN VAPOR LEVELS W/IN
ESTABLISHED TLVS.
Protective Gloves: IMPERVIOUS GLOVES (E.G., NBR NITRILE).
Eye Protection: ANSI APRV CHEMICAL WORKERS GOGGLES (FP N
Other Protective Equipment: WEAR LOW-STATIC/PROPERLY GROUNDED SHOES TO PVNT
BUILDUP OF STATIC CHARGES ON BODY. WEAR OTHER PROT CLTHG AS
Work Hygienic Practices: REMOVE ANY CONTAM CLTHG & WASH BEFORE REUSE. ROUTINELY
WASH HANDS, ARMS & FACE W/SOAP & WATER AFTER HANDLING.
Supplemental Safety and Health: EFTS OF OVEREXP:PERIPHERAL NERVE DMG. CHRONIC
EXPOS TO LEAD MAY ALSO CAUSE PERIPHERAL NERVE DMG. INHAL EXPOS TO LEAD
CHROMATE IS LIKELY TO OCCUR ONLY IN AEROSOL/MIST FORM & WOULD NOT BE
EXPECTED TO OC CUR UNDER NORM USE. INGEST:MOD TOX BY INGEST. SYMPS MAY INCL
NAUS, VOMIT, DIARR & NARCOSIS. LEAD IF INGESTED IS
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >295F,>146C
Vapor Pres: <4
Vapor Density: >1
Spec Gravity: 1.1-1.4(H*2O=1)
Solubility in Water: MODERATE
Appearance and Odor: ORANGE LIQUID; SWEET SOLVENT ODOR.
Percent Volatiles by Volume: 45-55
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: OXIDIZING MATERIALS OR STRONG BASES.
Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE CARBON
DIOXIDE OR CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: SCOTCHCAL BRAND SCREEN PRINTING INK 6613I
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 03/25/1993
Status Code: C
Label Date: 03/25/1993
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUST. AVOID OXIDIZERS, BASES. ACUTE:EYE:CAUSES SEV
IRRIT. SKIN:MAY CAUSE IRRIT UPON PRLNG/RPTD CONT. MAY BE ABSRBED THRU SKIN IN
HRMFUL AMTS. INHAL:MAY CAUSE RESP SYS IRRIT & NERV SYS IMPAIR. PRLNG
/RPTD EXPOS CAN CAUSE KIDNEY &/OR LIVEREFTS, BLOOD & PERIPH NERVE
DMG. INGEST:MOD TOX. MAY CAUSE NAUS, VOMIT, DIARR, NARCOS, LEAD POIS.
CHRONIC:CANCER HAZ. LEAD CHROMATE IS A LUNG CARCIN (FP N).LEAD I S CUMMUL
POIS. CAUSES PERIPH NERVE DMG, KDNY, LIVER & BLOOD DMG, ENCEPHALOPATHY,
MENTAL DETERIOR, ABNORM SPERM & FETAL EFTS. HDCH, NAUS, VOMIT, ABDOM
SPASMS, ANEMIA, LEAD-LINE ON GUMS & COMA. TOLUNE & LEAD CMPNDS APPR
ON NAV OCC CHEM REPROD HAZ LIST
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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