| MSDS | : | BASE NEUTRALS MIXTURE 3, US-114 | | CAS | : | 60-11-7
119-93-7
122-09-8
122-39-4
134-32-7
91-59-8
99-55-8
62-44-2
106-50-3
95-53-4
75-09-2
53-96-3
92-67-1
91-94-1 | | NAME | : | ing 20: rpt on carcins, 1994:known to be carn. animal:kidney, bladder,
ing 21: p-acetophenetidide: iarc mono, supp, vol 7, pg 310, 1987:group
ing 22: antic to be carcin. human:kidney, urether, bladder. o-toluidine:
ing 23: group 2b. ntp 7th annual report on carcins, 1994: antic to be
other prot equip: such as lab coat &/or rubber apron to prevent
aniline, n,n-dimethyl-p-phenylazo-; (p- (dimethylamino)azobenzene) (sara
benzidine, 3,3'-dimethyl-; (3,3'-dimethylbenzidine) (sara 313) (cercla).
phenethylamine, alpha, alpha-dimethyl-; (a,a-dimethylphenethylamine)
diphenylamine
1-naphthylamine (sara 313) (cercla). ld50: (oral, rat) 779 mg/kg.
2-naphthylamine (sara 313) (cercla). ld50: (oral, rat) 727 mg/kg.
o-toluidine, 5-nitro-; (5-nitro-o-toluidine) (sara 313)
p-acetophenetidide; (phenacetin) (cercla). ld50: (oral, rat) 3600 mg/kg
p-phenylenediamine (sara 313) (cercla)
o-toluidine (sara 313) (cercla). ld50: (oral, rat) 900 mg/kg
supdat:carcin. osha reg:cfr 29 1910.1911. benzidine, 3,3'-dichloro-: iarc
ing 15: 2b. ntp 7th annual report on carcins, 1994:antic to be carcin.
ing 16: dimethyl-p-phenylazo: iarc mono supp, vol 7, pg 56, 1987:group
ing 17: antic to be carcin. osha reg:cfr 29 1910.1015.
ing 18: 1987:group 2b. ntp 7th annual rpt on carcins, 1994:antic carcin.
ing 19:osha reg:cfr 29 1910.1004. 2-naphthylamine:iarc mono, vol 7, pg
methane, dichloro-; (methylene chloride) (sara 313) (cercla). ld50:
acetamide, n-fluoren-2-yl-; (2-acetylaminofluorene) (sara 313) (cercla)
4-biphenylamine; (4-aminodiphenyl) (sara 313) (cercla). ld50: (oral,
benzidine, 3,3'-dichloro-; (3,3'-dichlorobenzidine) (sara 313) (cercla).
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ULTRA SCIENTIFIC -- BASE NEUTRALS MIXTURE 3, US-114
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Material Safety Data Sheet
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MSDS Num: BTWVS
MSDS NAME: BASE NEUTRALS MIXTURE 3, US-114
Responsible Party
Name: ULTRA SCIENTIFIC
Address: 250 SMITH ST
City: NORTH KINGSTOWN RI 02852
Info Phone: 401-294-9400
Emergency Phone Number: 401-294-9400
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: ULTRA SCIENTIFIC
Address: 250 SMITH STREET
City: NORTH KINGSTOWN RI 02852-5000
Phone: 401-294-9400
=======================================================
Ingredients
=======================================================
Name: ING 20: RPT ON CARCINS, 1994:KNOWN TO BE CARN. ANIMAL:KIDNEY, BLADDER,
BLOOD, LUNGS, OSHA REG:CFR 1910.1009.
-----------------------------
Name: ING 21: P-ACETOPHENETIDIDE: IARC MONO, SUPP, VOL 7, PG 310, 1987:GROUP
2A. NTP 7TH RPT ON CARCINS, 1994:
-----------------------------
Name: ING 22: ANTIC TO BE CARCIN. HUMAN:KIDNEY, URETHER, BLADDER. O-TOLUIDINE:
IARC MONO, SUPP 7, PG 362, 1987:
-----------------------------
Name: ING 23: GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994: ANTIC TO BE
CARCIN. ANIMAL: KIDNEY, BLOOD, LUNG, SKIN.
-----------------------------
Name: OTHER PROT EQUIP: SUCH AS LAB COAT &/OR RUBBER APRON TO PREVENT
CONTACT W/EYES, SKIN & CLOTHING.
-----------------------------
Cas: 60-11-7
RTECS #: BX7350000
Name: ANILINE, N,N-DIMETHYL-P-PHENYLAZO-; (P- (DIMETHYLAMINO)AZOBENZENE) (SARA
313) (CERCLA). LD50: (ORAL, RAT) 200 MG/KG.
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 119-93-7
RTECS #: DD1225000
Name: BENZIDINE, 3,3'-DIMETHYL-; (3,3'-DIMETHYLBENZIDINE) (SARA 313) (CERCLA).
LD50: (ORAL, RAT) 404 MG/KG.
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 122-09-8
RTECS #: SH4025000
Name: PHENETHYLAMINE, ALPHA, ALPHA-DIMETHYL-; (A,A-DIMETHYLPHENETHYLAMINE)
(CERCLA)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 122-39-4
RTECS #: JJ7800000
Name: DIPHENYLAMINE
% Wt: 0.151
OSHA PEL: 10 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 134-32-7
RTECS #: QM1400000
Name: 1-NAPHTHYLAMINE (SARA 313) (CERCLA). LD50: (ORAL, RAT) 779 MG/KG.
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 91-59-8
RTECS #: QM2100000
Name: 2-NAPHTHYLAMINE (SARA 313) (CERCLA). LD50: (ORAL, RAT) 727 MG/KG.
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 99-55-8
RTECS #: XU2250000
Name: O-TOLUIDINE, 5-NITRO-; (5-NITRO-O-TOLUIDINE) (SARA 313)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 62-44-2
RTECS #: AM4375000
Name: P-ACETOPHENETIDIDE; (PHENACETIN) (CERCLA). LD50: (ORAL, RAT) 3600 MG/KG
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 106-50-3
RTECS #: SS8050000
Name: P-PHENYLENEDIAMINE (SARA 313) (CERCLA)
% Wt: 0.151
OSHA PEL: 0.1 MG/M3, S
ACGIH TLV: 0.1 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 95-53-4
RTECS #: XU2975000
Name: O-TOLUIDINE (SARA 313) (CERCLA). LD50: (ORAL, RAT) 900 MG/KG
% Wt: 0.151
OSHA PEL: 5 PPM, S
ACGIH TLV: 2 PPM, S
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Name: SUPDAT:CARCIN. OSHA REG:CFR 29 1910.1911. BENZIDINE, 3,3'-DICHLORO-: IARC
MONO, SUPP, VOL 7, PG 193, 1987:GROUP
-----------------------------
Name: ING 15: 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:ANTIC TO BE CARCIN.
OSHA REG:CFR 29 1910.1007. ANILINE,N,N-
-----------------------------
Name: ING 16: DIMETHYL-P-PHENYLAZO: IARC MONO SUPP, VOL 7, PG 56, 1987:GROUP
2B. NTP ANNUAL RPT ON CARCINS, 1994:
-----------------------------
Name: ING 17: ANTIC TO BE CARCIN. OSHA REG:CFR 29 1910.1015.
BENZIDINE,3,3'-DIMETHYL: IARC MONO, SUPP, VOL 7, PG 56,
-----------------------------
Name: ING 18: 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC CARCIN.
ANIMAL:SKIN, LIVER. 1-NAPHTHYLAMINE:
-----------------------------
Name: ING 19:OSHA REG:CFR 29 1910.1004. 2-NAPHTHYLAMINE:IARC MONO, VOL 7, PG
261, 1987:GROUP 1. NTP 7TH ANNUAL
-----------------------------
Cas: 75-09-2
RTECS #: PA8050000
Name: METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313) (CERCLA). LD50:
(ORAL, RAT) 2136 MG/KG.
% Wt: 98.04
OSHA PEL: 500 PPM
ACGIH TLV: 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 53-96-3
RTECS #: AB9450000
Name: ACETAMIDE, N-FLUOREN-2-YL-; (2-ACETYLAMINOFLUORENE) (SARA 313) (CERCLA)
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 92-67-1
RTECS #: DU8925000
Name: 4-BIPHENYLAMINE; (4-AMINODIPHENYL) (SARA 313) (CERCLA). LD50: (ORAL,
RAT) 500 MG/KG.
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 91-94-1
RTECS #: DD0525000
Name: BENZIDINE, 3,3'-DICHLORO-; (3,3'-DICHLOROBENZIDINE) (SARA 313) (CERCLA).
LD50: (ORAL, RAT) 4740 MG/KG.
% Wt: 0.151
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Health Hazards Data
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LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF THE
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS AND COULD HAVE A SIMILAR EFFECT IN
HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE CONTRA-INDICATED E XCEPT FOR
LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS
(FP N). ALL (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: METHYLENE CHLORIDE: IARC MONO, SUPP, VOL 7, PG
194, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:ANTIC (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS - DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST: CALL MD IMMEDIATELY (FP N). EYE: FLUSH WITH COPIOUS AMOUNTS
OF WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER.
INHAL: REMOVE TO FRESH AIR - GIVE OXYGEN IF NECESSARY. CONTACT MD.
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Handling and Disposal
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Spill Release Procedures: DUE TO THE SMALL QUANTITY INVOLVED, SPILLS OR LEAKS
SHOULD NOT POSE A SIGNIFICANT PROBELM. A LEAKING BOTTLE MAY BE PLACED IN A
PLASTIC BAG AND NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY B E
ABSORBED ON VERMICULITE OR SAND.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS
CONCERNING DISPOSAL.
Handling And Storage Precautions: KEEP TIGHTLY CLOSED & STORE IN A COOL,
DRY PLACE. THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED IN THE
SAFE HNDLG OF HAZARDOUS CHEMICALS.
Other Precautions: NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE (FP N).
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Fire and Explosion Hazard Information
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Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL
AND PHOSGENE (FP N).
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Control Measures
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Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). USE
APPROP OSHA/MSHA APPRVD SFTY EQUIP. WEAR CHEM RESISTANT CLTHG
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLAN OF CARCIN:TO BE CARCIN. ANIMAL:LUNG,
LIVER, SALIVARY, MAMMARY GLAND (TUMORS). ACETAMIDE, N-FLUOREN-2-YL-: NTP 7TH
ANNUAL REPORT ON CARCINS, 1994:ANTIC TO BE CARCIN. OSHA REG CFR 29 1919.1014.
4 -BIPHENYLAMINE: IARC MONO, SUPP, VOL 7,PG 91, 1987:GROUP 1. NTP 7TH ANNUAL
REPORT ON CARCINS, 1994:KNOWN TO BE
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Physical/Chemical Properties
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HCC: T6
Appearance and Odor: LIQUID.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZERS.
Hazardous Decomposition Products: HCL, PHOSGENE (FP N).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: BASE NEUTRALS MIXTURE 3, US-114
Company: ULTRA SCIENTIFIC
Street: 250 SMITH STREET
City: NORTH KINGSTOWN RI
Zipcode: 02852-5000
Health Emergency Phone: 401-294-9400
Label Required IND: Y
Date Of Label Review: 03/20/1996
Status Code: C
Label Date: 03/20/1996
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TOXIC. IRRITANT. ACUTE: INHALATION OF VAPORS MAY
CONTRIUBTE TO THE OCCURRENCE OF IRREGULAR HEARTBEAT (FP N). CHRONIC: CANCER
HAZARD. CONTAINS METHYLENE CHLORIDE WHICH IS LISTED AS AN ANIMAL LUNG AND L
IVER CARCINOGEN, 2-ACETYLAMINOFLUORENE,4-BIPHENYLAMINE,
BENZIDINE,3,3'-DICHLORO-, ANILINE, N,N-DIMETHYL-P-PHENYLAZO-, BENZIDINE,
3,3'-DIMETHYL AND 2-NAPTHTHYLAMINE WHICH ARE LISTED AS ANIMAL LIVER CAR
CINOGENS, 1-NAPHTHYLAMINE WHICH IS LISTED AS AN ANIMAL CARCINOGEN,
P-ACETOPHENETIDIDE WHICH IS LISTED AS A HUMAN KIDNEY CARCINOGEN AND
O-TOLUIDINE WHICH IS LISTED AS AN ANIMAL KIDNEY CARCINOGEN (FP N) .
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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