U S PAINT CORP -- AWL-GRIP AWLSTAR ANTI-FOULING GOLD LABEL-RED,
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BTYTM
MSDS NAME: AWL-GRIP AWLSTAR ANTI-FOULING GOLD LABEL-RED, BP701
Responsible Party
Name: U S PAINT CORP
Address: 831 S 21ST ST
City: ST LOUIS MO 63103
Info Phone: 314-621-0525
Emergency Phone Number: 800-424-9300 (CHEMTREC)
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: U S PAINT CORP
Address: 831 S 21ST STREET
City: ST LOUIS MO 63103
Phone: 314-621-0525
Name: US PAINT CORPORATION
Address: 831 SOUTH 21ST STREET
City: ST LOUIS MO 63103-3092
Phone: 314-621-0525
=======================================================
Ingredients
=======================================================
Name: ING 18: TANK. REMAINING LIQ MAY BE ABSORBED W/INERT MATL SUCH AS SAND,
CLAY, EARTH/FLOOR ABOSRB & SHOVELED INTO
-----------------------------
Name: ING 19:CNTNRS W/NON-SPK TOOLS. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER
BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY
-----------------------------
Name: ING 20: PROPER AUTHORITIES AS REQD THAT A SPILL HAS OCCURRED.
-----------------------------
Name: WASTE DISP METH: PARTICULATES EXPOSED TO MOIST AIR @ > 100C CAN RSLT
IN SPONT COMBUST. (CNDTNS MAY APPLY WHEN SANDING.)
-----------------------------
Name: OTHER PREC: "EMPTY" CNTNRS MAY BE HAZ BECAUSE OF RESIDUES OF PROD. ALL
PREC MUST BE FOLLOWED.
-----------------------------
Name: EYE PROT: W/SPLASH GUARDS.
-----------------------------
Cas: 100-41-4
RTECS #: DA0700000
Name: BENZENE, ETHYL-; (ETHYL BENZENE) (SARA III) VP @ 20C: 5
% Wt: 1
OSHA PEL: 100 PPM; 125 STEL
ACGIH TLV: 100 PPM; 125 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1314-13-2
RTECS #: ZH4810000
Name: ZINC OXIDE
% Wt: 12
OSHA PEL: 15MG/M3 TDUST;5 FUME
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE; (TITANIUM DIOXIDE)
% Wt: 2
OSHA PEL: 10 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 1317-39-1
RTECS #: GL8050000
Name: COPPER (I) OXIDE; (CUPROUS OXIDE, CONTAINING ING 7)
% Wt: 42-47
OSHA PEL: 1 MG/M3 (CU) (MFR)
ACGIH TLV: 1 MG/M3 (CU) (MFR)
------------------------------
Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER (SARA III)
% Wt: >48
OSHA PEL: 0.1MG/M3 FUME;1 DUST
ACGIH TLV: 0.2 MG/M3 FUME
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUNDS: 391 G/L
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: MATLS TO AVOID: BUT NOT LIMITED TO ALUMINUM & MAGNESIUM. ALSO
PERMANGANATE, CHROMIUM DIOXIDE.
-----------------------------
Name: HAZ DECOMP PRODS: OXIDES OF NITROGEN. WHEN HEATED TO DECOMPOSITION EMITS
TOXIC FUMES.
-----------------------------
Name: EFTS OF OVEREXP:NAUS, VOMIT & DIARR. CHRONIC: PRLNG & RPTD BRTHG
OF SPRAY MIST &/OR SANDING DUST OVER PERIOD OF
-----------------------------
Name: ING 11: YRS MAY CAUSE LUNG DISEASES. CAN CAUSE IRRIT TO MUC MEMB. HIGH
VAP MAY RSLT IN CNS DEPRESS. HEMORR INTO
-----------------------------
Name: ING 12: VARIOUS VITAL ORGANS HAVE BEEN NOTED. MAY CAUSE KIDNEYS, LIVER,
LUNGS & CARDIOVASCULAR SYS INJURY.
-----------------------------
Name: ING 13: CORNEAL EFTS MAY OCCUR. COMA MAY RSLT FROM OVEREXP. CAN CAUSE GI
IRRIT. NARCTC EFTS NOTED. MAY CAUSE
-----------------------------
Name: ING 14: BLOOD DISORDERS. REPORTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREX
TO SOLV W/PERM BRAIN & NERVOUS SYS DMG.
-----------------------------
Name: ING 15: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING
CONTENTS MAY BE HARMFUL OR FATAL.
-----------------------------
Name: FIRST AID PROC: IMMED. IF BRTHG CEASES RESTORE USING CPR TECHNIQUES &
SUMMON MED HELP IMMED.
-----------------------------
Name: SPILL PROC: CLEAN-UP COMPLETED. STOP SPILL AT SOURCE, CNTN AREA OF SPILL
TO PVNT SPREADING, PUMP LIQ TO SALVAGE
-----------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
Name: XYLENE (SARA III) VP @ 20C: 6 LD50: (ORAL, RAT) 43 G/KG
% Wt: 8
OSHA PEL: 100 PPM; 150 STEL
ACGIH TLV: 100 PPM; 150 STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 71-36-3
RTECS #: EO1400000
Name: BUTYL ALCOHOL; (NORMAL-BUTYL ALCOHOL) (SARA III) VP @ 20C: 10 LD50:
(ORAL, RAT) 25 G/KG
% Wt: 11
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM, S, C
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGS 1 & 2
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES:CAN CAUSE SEV IRRIT, REDNESS, TEARING &
BLURRED VISION, PAIN & INFLAMM OF TISS. SKIN:PRLNG/RPTD CNTCT CAN CAUSE
MOD IRRIT, DEFAT & DERM. OVEREXP TO COPPER CAN CAUSE SKIN IRRIT. SOLV CAN
PE NETRATE SKIN CAUSING EFTS SIMILAR TO ACUTE INHAL SYMPS. INHAL: EXCESSIVE
INHAL OF VAPS CAN CAUSE NASAL (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:& RESP IRRIT, CONGESTION,
DIZZ, WEAK, CHILLS, FEVER FATIGUE, MUSC ACHES, NAUS, HDCH, POSS UNCON &
EVEN ASPHY. MAY ALSO CAUSE TIGHTNESS IN CHEST. INHAL OF EXCESSIVE QTYS OF
FUMES MAY CAUSE FLU -LIKE SYMPS CALLED "METAL-FUME FEVER." INGEST:HARMFUL
& CAN CAUSE BURNING SENSATION, SORE THROAT, ABDOM PAIN,
Medical Cond Aggravated By Exposure: PRE-EXISTING LUNG DISEASES MAY BE
AGGRAVATED BY EXPOSURE. MAY RESULT IN RESPIRATORY DISEASE IF OVEREXPOSED ON A
CHRONIC BASIS.
First Aid: SKIN: WASH THORO W/SOAP & WATER. REMOVE SOILED CLTHG. GET MED
ASSISTANCE IF IRRIT PERSISTS. WASH CLTHG BEFORE REUSE. EYES: FLUSH W/LG AMTS
WATER FOR @ LEAST 15 MIN. GET MED ASSISTANCE. INGEST: GET MED ATTN IMMED. DO
NOT INDUCE VOMIT. ASPIROF MATL INTO LUNGS CAN CAUSE CHEM PNEUM WHICH MAY BE
FATAL. INHAL: IF DFCLTY BRTHG, LEAVE AREA FOR FRESH AIR. IF CONTINUED DFCLTY
SUMMON MED ASSISTANCE
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SM SPILL:ABSORB LIQ ON INERT MATL SUCH AS PAPER,
VERMICULITE, FLOOR ABSORB & TRANSFER TO HOOD. LG SPILL:ELIM ALL IGNIT
SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPK). PERS NOT WEARING PROT
EQUIP SHOULD BE EXCLUDED FROM SPILL AREA UNTIL
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: ALLOW TO EVAP IN HOOD BEING SURE TO ALLOW SUFFICIENT
TIME FOR VAP TO COMPLETELY CLEAR HOOD DUCT WORK. DISPOSE OF CONTAMD ABOSRB,
CNTNRS & UNUSED CONTENTS I/A/W LOCAL, STATE & FED REGS. DO NOT INCIN
CL SD CNTNRS. LG MASSES OF CUPROUS OXIDE
Handling And Storage Precautions: KEEP CLOSURE TIGHT & UPRIGHT TO PVNT
LEAK. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT STORE > 120F. DO NOT
TRANSFER CONTENTS TO BOTTLES/UNLABELED CNTNRS.
Other Precautions: PROD MAY BE BLENDED W/OTHER PRODS PRIOR TO USE. READ ALL
WARNINGS & PREC ON LABELS OF ALL PROD BEING BLENDED AS COMBINATION MAY
CNTN HAZ OF EACH CMPD. FOR INDUS USE ONLY. NOT INTENDED FOR SALE TO/USE BY
GENERAL PUBLIC.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 82.0F,27.8C
Lower Limits: 1.10%
Upper Limits: 12%
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE OR FOAM OR OTHER APPROVED
METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP
N). TOX GASES & SMOKE ARE PRESENT FROM DECOMP/COMBUST. CLSD CNTNRS MAY
EXPLODE WHEN EXPOS TO EXTREME HEAT.
Unusual Fire/Explosion Hazard: KEEP AWAY FROM HEAT,SPK & FLAME. DO NOT
SMOKE. EXTING ALL PILOT LIGHTS & TURN OFF ALL SOURCES OF IGNIT INCL
HEATERS, FANS & OTHER NON-EXPLOS-PROOF ELEC (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE W/ADEQ VENT. WEAR APPROP PROPERLY FITTED NIOSH/MSHA
APPRVD RESP DURING & AFTER APPLICATN UNLESS AIR MONITORING DEMONSTRATES
VAP, MIST & PARTICULATE LEVELS BELOW APPLIC LIM. ENGINEER/ADMIN CONTROLS
SHOULD BE IMPLEMENTED TO REDUCE EXPOS.
Ventilation: MAINTAIN CONTINUOUS FLOW OF FRESH AIR. PROVIDE SUFFICIENT MECH
(GEN &/OR LOC EXHST) VENT TO MAINTAIN EXPOS BELOW TLV(S).
Protective Gloves: SOLVENT IMPERMEABLE GLOVES.
Eye Protection: ANSI APPVD SOLV RESIST SFTY EYEWR (ING24
Other Protective Equipment: DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. SOLVENT
IMPERMEABLE CLOTHING & BOOTS ARE RECOMMENDED TO PREVENT SKIN CNTCT.
Work Hygienic Practices: DO NOT BREATHE VAPORS, MISTS, DUSTS.
Supplemental Safety and Health: EXPLO HAZ:EQUIP DURING USE & UNTIL ALL VAP
GONE. VAPS MAY IGNITE EXPLO; MAY SPREAD LONG DIST & BEYOND CLSD DOORS.
PVNT BUILD UP OF VAP BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. WHEN
SANDING, TAKE C ARE DUE TO SPONT COMBUST OF CUPROUS OXIDE PARTICULATES WHEN
EXPOS TO MOIST AIR @ TEMP > 100C. GROUNDING & BONDING REQD.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >241F,>116C
M.P/F.P Text: 2255F,1235C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 1.93
Evaporation Rate & Reference: SLOWER THAN ETHER
Appearance and Odor: VISCOUS LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume: 47
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXCESS HEAT AND/OR OXIDIZING MATERIALS.
Materials To Avoid: UNDER CERTAIN CNDTNS CUPROUS OXIDE MAY REACT VIOLENTLY
W/STRONG REACTANTS SUCH AS ACIDS, BASES & METALS SUCH AS
Hazardous Decomposition Products: COPPER FUMES WILL BE RELS IF CUPROUS OXIDE IS
HEATED > MP:2255F. DECOMPOSES INTO FUMES CONTAINING CO, CO*2 &
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: AWL-GRIP AWLSTAR ANTI-FOULING GOLD LABEL-RED, BP701
Assigned IND: Y
Company: U S PAINT CORP
Street: 831 S 21ST STREET
City: ST LOUIS MO
Zipcode: 63103
Health Emergency Phone: 800-424-9300 (CHEMTREC)
Label Required IND: Y
Date Of Label Review: 02/24/1994
Status Code: C
Label Date: 02/24/1994
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. MAY REACT VIOLENTLY W/MOIST AIR, ACIDS,
BASES, METALS. ACUTE: EYES:IRRIT, REDNESS, TEARING, BLURRED VISION, PAIN,
INFLAMM. SKIN:IRRIT, DEFAT, DERM. INHAL:NASAL/RESP IRRIT, CONGESTION, DIZZ,
WEAK, CHILLS, FEVER, MUSC ACHES, NAUS,HDCH, POSS UNCON & ASPHY.
INGEST:BURNING SENSATION, SORE THROAT, ABDOM PAIN, NAUS, VOMIT & DIARR.
CHRONIC: LUNG DISEASE. CNS DEPRESS, HEMORR INTO VITAL ORGANS, K IDNEY, LIVER,
LUNGS & CARDIOVASCULAR INJURY. CORNEAL EFTS, COMA, GI IRRIT, NARCTC EFTS,
BLOOD DISORDERS. RPTS ASSOC OCCUP OVEREXP TO SOLV W/PERM BRAIN & NERVOUS
SYS DMG. INTENTIONAL MISUSE MAY BE HARM FUL/FATAL.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
|
|