2-propenoic acid, 2-cyano-, ethyl ester; (ethyl cyanoacrylate) ethylene copolymer rubber silica, amorphous (fumed); (silica, amorphous treated) carbon black polymethylmethacrylate; (poly (methyl methacrylate)) hydroquinone (sara 302/313) (cercla) phthalic anhydride (sara 313) (cercla) lel: 1.7%. uel: 10.5%. supdat: roll surfs apart w/aid of blunt edge, e.g. spatula/tsp handle; ing 8: water. do not try to pull surfs apart w/direct opposing action. ing 9: thoro w/warm water & apply gauze patch. eye will open w/out ing 10:residual dmg. do not try to open eyes by manipulation. adhesive on ing 11: eyes will attach itself to eye protein & will disassoc from ing 12: several hrs; will cause periods of weeping until clearance ing 13: vision may be experienced together w/lachrymatory eft, & it ing 14:disassoc will norm occur w/in hrs, even w/gross contam. mouth:if ing 15: water to lips & encourage max wetting & press from saliva ing 16:to pull lips w/direct opposing action. it's almost imposs to ing 17: & adheres in mouth. saliva will lift adhesive in one half to ing 18: position patient to pvnt ingest of lump when it detaches. burns: ing 19: solidification. in rare cases a lg drop will incr in temp enough ing 20: normally after lump of cyanoacrylate is relsd from tiss. surgery: ing 21: drastic method to separate accidentally bonded skin.
LOCTITE CORP -- PRISM 426 BLACK TOUGHENED INST ADH, 17451
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: BWFVN
MSDS NAME: PRISM 426 BLACK TOUGHENED INST ADH, 17451
Responsible Party
Name: LOCTITE CORP
Address: 705 N MOUNTAIN RD
City: NEWINGTON CT 06111
Info Phone: 203-278-1280
Emergency Phone Number: 203-278-1280
Preparer's Name: STEPHEN REPETTO
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: LOCTITE CORP
Address: 705 N MT RD
City: NEWINGTON CT 06111
Phone: 312-689-6200
Name: LOCTITE CORPORATION
Address: 1001 TROUT BROOK CROSSING
City: ROCKY HILL CT 06067-3910
Phone: 860-571-5100
=======================================================
Ingredients
=======================================================
Cas: 7085-85-0
RTECS #: UD3330000
Name: 2-PROPENOIC ACID, 2-CYANO-, ETHYL ESTER; (ETHYL CYANOACRYLATE)
% Wt: 80-85
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 54545-50-5
Name: ETHYLENE COPOLYMER RUBBER
% Wt: 5-10
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 112945-52-5
RTECS #: VV7310000
Name: SILICA, AMORPHOUS (FUMED); (SILICA, AMORPHOUS TREATED)
% Wt: 3-5
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 1333-86-4
RTECS #: FF5800000
Name: CARBON BLACK
% Wt: 1-3
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
Cas: 9011-14-7
RTECS #: TR0400000
Name: POLYMETHYLMETHACRYLATE; (POLY (METHYL METHACRYLATE))
% Wt: 1-3
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 123-31-9
RTECS #: MX3500000
Name: HYDROQUINONE (SARA 302/313) (CERCLA)
% Wt: 0.1-1
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 85-44-9
RTECS #: TI3150000
Name: PHTHALIC ANHYDRIDE (SARA 313) (CERCLA) LEL: 1.7%. UEL: 10.5%.
% Wt: 0.1-1
OSHA PEL: 2 PPM
ACGIH TLV: 1 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Name: SUPDAT: ROLL SURFS APART W/AID OF BLUNT EDGE, E.G. SPATULA/TSP HANDLE;
THEN REMOVE ADHESIVE FROM SKIN W/SOAP &
-----------------------------
Name: ING 8: WATER. DO NOT TRY TO PULL SURFS APART W/DIRECT OPPOSING ACTION.
EYELID TO EYELID/EYEBALL ADHESION: WASH
-----------------------------
Name: ING 9: THORO W/WARM WATER & APPLY GAUZE PATCH. EYE WILL OPEN W/OUT
FURTHER ACTION, TYPICALLY IN 1-4 DAYS W/NO
-----------------------------
Name: ING 10:RESIDUAL DMG. DO NOT TRY TO OPEN EYES BY MANIPULATION. ADHESIVE ON
EYEBALL:CYANOACRYLATE INTRODUCED INTO
-----------------------------
Name: ING 11: EYES WILL ATTACH ITSELF TO EYE PROTEIN & WILL DISASSOC FROM
IT OVER INTERMITTENT PERIODS, COVERING
-----------------------------
Name: ING 12: SEVERAL HRS; WILL CAUSE PERIODS OF WEEPING UNTIL CLEARANCE
ACHIEVED. DURING PERIOD OF CONTAM, DOUBLE
-----------------------------
Name: ING 13: VISION MAY BE EXPERIENCED TOGETHER W/LACHRYMATORY EFT, & IT
IS IMPORTANT TO UNDERSTAND CAUSE & REALIZE
-----------------------------
Name: ING 14:DISASSOC WILL NORM OCCUR W/IN HRS, EVEN W/GROSS CONTAM. MOUTH:IF
LIPS STUCK TOGETHER, APPLY LOTS OF WARM
-----------------------------
Name: ING 15: WATER TO LIPS & ENCOURAGE MAX WETTING & PRESS FROM SALIVA
INSIDE MOUTH. PEEL/ROLL LIPS ARAT. DO NOT TRY
-----------------------------
Name: ING 16:TO PULL LIPS W/DIRECT OPPOSING ACTION. IT'S ALMOST IMPOSS TO
SWALLOW CYANOACRYLATE. ADHESIVE SOLIDIFIES
-----------------------------
Name: ING 17: & ADHERES IN MOUTH. SALIVA WILL LIFT ADHESIVE IN ONE HALF TO
2 DAYS. IN CASE LUMP FORMS IN MOUTH,
-----------------------------
Name: ING 18: POSITION PATIENT TO PVNT INGEST OF LUMP WHEN IT DETACHES. BURNS:
CYANOACRYLATES GIVE OFF HEAT ON
-----------------------------
Name: ING 19: SOLIDIFICATION. IN RARE CASES A LG DROP WILL INCR IN TEMP ENOUGH
TO CAUSE BURN. BURNS SHOULD BE TREATED
-----------------------------
Name: ING 20: NORMALLY AFTER LUMP OF CYANOACRYLATE IS RELSD FROM TISS. SURGERY:
IT SHOULD NEVER BE NEC TO USE SUCH A
-----------------------------
Name: ING 21: DRASTIC METHOD TO SEPARATE ACCIDENTALLY BONDED SKIN.
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL) > 5000 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY &
STRONGLY. SKIN & EYE IRRITANT. VAPOR IS IRRITATING TO EYES & MUCOUS
MEMBRANES ABOVE TLV. PROLONGED & REPEATED OVEREXPOSURE TO VAPORS MAY
PRODUCE ALLE RGIC REACTIONS WITH ASTHMA-LIKE SYMPTOMS IN SENSITIVE
INDIVIDUALS.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHAL: REMOVE TO FRESH AIR. IF SYMPS PERSIST, OBTAIN MED ATTN. PROD
IS VERY FAST SETTING & STRONG ADHESIVE. BONDS HUMAN TISS INCL SKIN IN
SECONDS. ACCIDENTS HNDLD BEST BY PASSIVE NONSURGICAL FIRST AID : SKIN CNTCT:
REMOVE EXCESS ADHESIVE. SOAK IN WARM, SOAPY WATER. ADHESIVE WILL COME LOOSE
FROM SKIN IN SEVERAL HRS. CURED ADHESIVE DOES NOT PRESENT HLTH HAZ EVEN WHEN
BONDED TO SKIN. AVOID (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLOOD WITH WATER TO POLYMERIZE COMPLETELY. SOLID
POLYMER IS NON-HAZARDOUS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: AFTER POLYMERIZATION, INCINERATE FOLLOWING EPA,
FEDERAL, STATE AND LOCAL REGULATIONS. PHTHALIC ANHYDRIDE IS LISTED BY EPA AS
A HAZARDOUS WASTE.
Handling And Storage Precautions: STORE BELOW 75F TO MAXIMIZE SHELF LIFE. AVOID
CONTACT W/SKIN AND EYES. AVOID BREATHING VAPOR.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >150F,>66C
Lower Limits: SEE ING 7
Upper Limits: SEE ING 7
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: POSITIVE DOWN-DRAFT EXHAUST VENTILATION SHOULD BE PROVIDED TO
MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Protective Gloves: NITRILE OR POLYETHYLENE GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: EMERGENCY EYE WASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). NITRILE OR POLYETHYLENE APRONS.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: FIRST AID PROC: CNTCT W/CLTHG, FABRICS,
RAGS/TISS. CNTCT W/THESE MAY CAUSE POLYM. POLYM OF LG AMTS OF ADHESIVE WILL
GENERATE HEAT CAUSING SMOKE, SKIN BURNS & STRONG, IRRIT VAPS. WEAR
NITRILE/POLYETHYL ENE GLOVES & APRON WHEN HDNLG LG AMTS. SKIN ADHESION:
FIRST IMMERSE BONDED SURFS IN WARM, SOAPY WATER. PEEL OR
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >300F,>149C
Vapor Pres: <0.2
Vapor Density: APPROX 3
Spec Gravity: 1.05
Solubility in Water: POLYMERIZED BY WATER
Appearance and Odor: BLACK GEL; SHARP, IRRITATING ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: POLYMERIZED BY CONTACT WITH WATER, ALCOHOLS, AMINES,
ALKALIES.
Hazardous Decomposition Products: IRRITATING ORGANIC VAPORS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PRISM 426 BLACK TOUGHENED INST ADH, 17451
Company: LOCTITE CORP
Street: 705 N MT RD
City: NEWINGTON CT
Zipcode: 06111
Health Emergency Phone: 203-278-1280
Label Required IND: Y
Date Of Label Review: 01/05/1995
Status Code: C
Label Date: 01/05/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. POLYMERIZES WITH WATER. ACUTE: SKIN
CONTACT MAY CAUSE BURNS. BONDS SKIN RAPIDLY AND STRONGLY. SKIN AND EYE
IRRITANT. VAPOR IS IRRITATING TO EYES AND MUCOUS MEMBRANES ABOVE TLV.
CHRONIC: P ROLONGED AND REPEATED OVEREXPOSURE TO VAPORS MAY PRODUCE ALLERGIC
REACTIONS WITH ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.