| MSDS | : | 8690 EPOXY FOR FIBER OPTIC CONNECTORS-PART B (SUPDAT) | | CAS | : | 4246-51-9
68610-56-0
68585-28-4
111-40-0 | | NAME | : | diethylene glycol, di(3-aminopropyl) ether; (bis(3-aminopropyl) ether of
diethylene triamine adduct; (epoxy resin/amine adduct)
epoxy resin/amine adduct
diethylenetriamine
efts of overexp: redness, swell, itch, pain, blisters, ulceration,
ing 5: rxn w/signs/symps:dfclty brthg, wheez, tightness of chest &
ing 6: emotional chgs, incoordination, tremors & sensory loss. irrit
ing 7: nose & throat, cough, sneeze. pulm edema w/signs/symps:cough,
ing 8: resp failure & death. ingest: gi efts w/signs/symps:abdom
ing 9: throat, dfclt swall & blood in sputum. irrit of gi tiss
ing 10: naus, blood in vomitus & blood in feces. burns of oral tiss
ing 11: & inside mouth, redness & tiss loss. bisphenol a epoxy
ing 12: (epoxycyclopentyl) ether & bisphenol a epoxy resins have been
ing 13: neither compound alone was found to be carcin.
first aid proc: call md immed. never give anything by mouth to uncon
spill proc: exting all ignit sources & vent area. follow msds
eye prot: & full length faceshield (fp n).
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3M GENERAL OFFICES -- 8690 EPOXY FOR FIBER OPTIC CONNECTORS-PART B
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Material Safety Data Sheet
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MSDS Num: BWNZP
MSDS NAME: 8690 EPOXY FOR FIBER OPTIC CONNECTORS-PART B (SUPDAT)
Kit Part: Y
Responsible Party
Name: 3M GENERAL OFFICES
Address: 3M CENTER
City: ST PAUL MN 55144-1000
Info Phone: 612-733-1110
Emergency Phone Number: 612-733-1110
Published: Y
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Contractor Summary
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Name: MINNESOTA MINING AND MFG CO, DBA 3M
Address: 3M CENTER BLDG 224-5S-04
City: SAINT PAUL MN 55144-1000
Phone: 866-556 5712 / 612-733-1110
Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Address: 3M CTR
City: SAINT PAUL MN 55144-1000
Phone: 612-737-4114
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Ingredients
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Cas: 4246-51-9
RTECS #: ID6475000
Name: DIETHYLENE GLYCOL, DI(3-AMINOPROPYL) ETHER; (BIS(3-AMINOPROPYL) ETHER OF
DIETHYLENE GLYCOL)
% Wt: 40-70
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 68610-56-0
Name: DIETHYLENE TRIAMINE ADDUCT; (EPOXY RESIN/AMINE ADDUCT)
% Wt: 10-35
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 68585-28-4
Name: EPOXY RESIN/AMINE ADDUCT
% Wt: 1-25
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 111-40-0
RTECS #: IE1225000
Name: DIETHYLENETRIAMINE
% Wt: 5-20
OSHA PEL: 1 PPM
ACGIH TLV: 1 PPM, S
------------------------------
Name: EFTS OF OVEREXP: REDNESS, SWELL, ITCH, PAIN, BLISTERS, ULCERATION,
SLOUGHING & SCAR FORM. INHAL: ALLERGIC RESP
-----------------------------
Name: ING 5: RXN W/SIGNS/SYMPS:DFCLTY BRTHG, WHEEZ, TIGHTNESS OF CHEST &
RESP FAILURE. NERVOUS SYS EFTS W/SIGNS/SYMPS:
-----------------------------
Name: ING 6: EMOTIONAL CHGS, INCOORDINATION, TREMORS & SENSORY LOSS. IRRIT
(UPPER RESP) W/SIGNS/SYMPS:SORENESS OF NOSE
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Name: ING 7: NOSE & THROAT, COUGH, SNEEZE. PULM EDEMA W/SIGNS/SYMPS:COUGH,
CONGESTION, DFCLTY BRTHG, WHICH CAN RSLT IN
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Name: ING 8: RESP FAILURE & DEATH. INGEST: GI EFTS W/SIGNS/SYMPS:ABDOM
PAIN. ESOPHAGEAL BURNS W/SIGNS/SYMPS:PAIN IN
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Name: ING 9: THROAT, DFCLT SWALL & BLOOD IN SPUTUM. IRRIT OF GI TISS
W/SIGNS/SYMPS:PAIN, VOMIT, ABDOM TENDERNESS,
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Name: ING 10: NAUS, BLOOD IN VOMITUS & BLOOD IN FECES. BURNS OF ORAL TISS
W/SIGNS/SYMPS: PAIN, BURNS OF TONGUE &
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Name: ING 11: & INSIDE MOUTH, REDNESS & TISS LOSS. BISPHENOL A EPOXY
RESINS IS POTNTL CANCER HAZ. MIXS OF BIS
-----------------------------
Name: ING 12: (EPOXYCYCLOPENTYL) ETHER & BISPHENOL A EPOXY RESINS HAVE BEEN
FOUND TO INDUCE SKIN TUMORS IN MICE.
-----------------------------
Name: ING 13: NEITHER COMPOUND ALONE WAS FOUND TO BE CARCIN.
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Name: FIRST AID PROC: CALL MD IMMED. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERSON.
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Name: SPILL PROC: EXTING ALL IGNIT SOURCES & VENT AREA. FOLLOW MSDS
RECOMMENDATIONS FOR CLEANUP SOLVENT.
-----------------------------
Name: EYE PROT: & FULL LENGTH FACESHIELD (FP N).
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: CHEM RELATED EYE BURNS (CHEM CORR)
W/SIGNS/SYMPS:CLOUDY APPEARANCE OF CORNEA, CHEM BURNS, PAIN, TEARING, ULCERS,
IMPAIRED/LOSSS OF VISION. SEV EYE IRRIT W/SIGNS/SYMPS:REDNESS, SWELL, PAIN,
TEARI NG CLOUDY APPEARANCE OF CORNEA; IMPAIRED VISION, POSS PERM. SKIN:
ALLERGIC RXN W/SIGNS/SYMPS:REDNESS, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: SWELL, BLISTERS & ITCH. SEV
IRRIT W/SIGNS/SYMPS:REDNESS, SWELL, ITCH, DRYNESS, CRACKING, BLISTERS &
PAIN. MAY BE ABSORBED THRU SKIN. WHILE FOLLOWING EFTS ARE ASSOC W/ONE OR MORE
OF INDIVIDUA L INGREDS IN PROD & ARE REQD BY OSHA TOBE INCL ON MSDS, THEY
ARE NOT EXPECTED EFTS:SKIN BURNS (CHEM CORR) WITH
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMED FLUSH W/LG AMTS OF WATER FOR AT LEAST 15 MIN. GET IMMED
MED ATTN. SKIN: IMMED WASH W/SOAP & LG AMTS OF WATER. REMOVE CONTAMD
CLTHG. IF SIGNS/SYMPS OCCUR, CALL MD. WASH CONTAMD CLTHG BEFORE REUSE &
DISPOSE OF CONTAMD SHOES. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLT, GET IMMED MED ATTN. INGEST: DO NOT INDUCE VOMIT.
DRINK TWO GLASSES OF WATER.
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Handling and Disposal
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Spill Release Procedures: REFER TO MSDS FOR INFO REGARDING PHYSICAL & HLTH
HAZS, RESP PROT, VENT & PERSONAL PROT EQUIP. CALL 612-733-1110 OR
612-733-6100 FOR 24-HR SPILL ASSISTANCE. COVER W/ABSORB MATL. CLEAN UP
RESIDUE W/APPR OP SOLV SUCH AS METHYL ETHYL KETONE.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL
IN A SANITARY LANDFILL.
Handling And Storage Precautions: STORE AWAY FROM HEAT. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point Text: >200F,>93C
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: BY-PRODS EXPECTED IN INCOMPLETE
PYROLYSIS/COMBUST OF EPOXY RESINS ARE MAINLY PHENOLICS, CARBON MONOXIDE &
WATER. THERMAL DECOMP PRODS OF EPOXY RESINS (SUPDAT)
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Control Measures
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Respiratory Protection: AVOID PROLONGED BREATHING OF VAPORS. USE NIOSH/MSHA
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: USE IN WELL-VENTILATED AREA. PROVIDE SUFFICIENT VENTILATION TO
MAINTAIN EMISSIONS BELOW RECOMMENDED EXPOSURE LIMITS.
Protective Gloves: NITRILE RUBBER GLOVES.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS
Other Protective Equipment: ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER
(FP N).
Work Hygienic Practices: WASH HANDS AFTER HANDLING AND BEFORE EATING.
Supplemental Safety and Health: MFR'S TRADE NAME/PART NO: (HARDENER). EXPLO
HAZ: THEREFORE SHOULD BE TREATED AS POTNTLY HAZ SUBSTANCES & APPROP
PRECS SHOULD BE TAKEN. HAZ DECOMP PRODS: WATER. THERMAL DECOMP PRODS OF EPOXY
RESINS TH EREFORE SHOULD BE TREATED AS POTNTLY HAZ SUBSTANCES & APPROP
PRECS SHOULD BE TAKEN.
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Physical/Chemical Properties
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B.P. Text: >300F,>149C
Vapor Pres: <1
Vapor Density: >2
Spec Gravity: 1.04 (H*2O=1)
Appearance and Odor: BLUE LIQUID, AMMONIACAL ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: BY-PRODS EXPECTED IN INCOMPLETE PYROLYSIS OR
COMBUST OF EPOXY RESINS ARE MAINLY PHENOLICS, CARBON MONOXIDE & (SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: 8690 EPOXY FOR FIBER OPTIC CONNECTORS-PART B (SUPDAT)
Company: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
City: SAINT PAUL MN
Zipcode: 55144-1000
Health Emergency Phone: 612-733-1110
Label Required IND: Y
Date Of Label Review: 02/01/1995
Status Code: C
Label Date: 02/01/1995
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. EYES: CHEMICAL RELATED EYE BURNS (CHEMICAL
CORROSIVITY), CLOUDY APPEARANCE OF CORNEA, CHEMICAL BURNS, PAIN, TEARING,
ULCERS, IMPAIRED/LOSS OF VISION, REDNESS, SWELLING, PAIN. SKIN: ALLERG IC
REACTION, REDNESS, SWELLING, ITCHING, DRYNESS, CRACKING, BLISTERS & PAIN.
MAY BE ABSORBED THROUGH SKIN. INGEST: BURNS, GI EFFECTS. DIFFICULTY
BREATHING, WHEEZING, TIGHTNESS OF CHEST & RESPIRATORY FAILURE,
INCOORDINATION, TREMORS & SENSORY LOSS. CHRONIC: POTENTIAL CANCER HAZARD
PER MANUFACTURER. INHAL: MAY CAUSE ALLERGIC RESPIRATORY REACTION (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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