===================== Product Identification =====================
MSDS NAME:GENETRON 114 DICHLOROTETRAFLUOROETHANE
NIIN:00-290-4379
MSDS Number: BJPSN
=== Responsible Party ===
Company:ALLIED-SIGNAL CORP,ENGINEERED MATERIALS DIV
Address:PARK AVE AND COLUMBIA RD
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
Info Phone Num:201-455-4157
Emergency Phone Num:201-455-4157
CAGE:40991
=== Contractor Identification ===
Company:ALLIED-SIGNAL CORP ENGINEERED MATERIALS DIV
Address:PARK AVE AND COLUMBIA RD
Box:City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
Phone:201-455-2000
CAGE:40991
============= Composition/Information on Ingredients =============
Name:DICHLOROTETRAFLUOROETHANE (SARA III)
CAS:76-14-2
RTECS #:KI1101000
Fraction by Wt: 100%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:LC50=72 PPH/30M (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALE: VAPORS ARE EELATIVELY NONTOXIC
BUT MAY ACT AS A NARCOTIC AND CNS DEPRESSANT AT HIGH
CONCENTRATIONS; SKIN: CONTACT OF LIQUID MATERIAL WITH SKIN MAY
CAUSE FROSTBITE, INDICATED BY PALLOR OR REDNE SS, LOSS OF SENSATION
& SWELLING OF AFFECTED TISSUE; EYE: SAME EFFECT FROM LIQUID CONTACT
AS FOR SKIN.
Effects of Overexposure:INHALE: LOSS OF COORDINATION, INCREASED PULSE
RATE, DEEPER RESPIRATION, NAUSEA AND DIZZINESS. EPINEPHRINE MAY
SENSITIZE THE MYOCARDIUM TO THIS SUBSTANCE.
Medical Cond Aggravated by Exposure:NONE STATED.
======================= First Aid Measures =======================
First Aid:INHALE: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH, USE OXYGEN AS
REQUIRED; SKIN/EYE: BATHE ANY FROSTBITE WITH LUKEWARM WATER. IF NO
WATER, C OVER WITH SOFT WOOL OR OTHER SUITABLE MATERIAL & CONTACT A
PHYSICIAN; INGEST: THIS IS HIGHLY UNLIKELY DUE TO THE LOW BOILING
POINT AND GASES STATE AT NORMAL TEMPERATURES AND PRESSURE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MATERIAL IS NON-FLAMMABLE. CHOOSE ANY STANDARD
AGENT APPROPRIATE FOR THE TYPE OF SURROUNDING FIRE.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS, APPROVED BY NIOSH, FOR PROTECTION AGAINST
SUFFOCATION & POSSIBLE TOXIC DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
================== Accidental Release Measures ==================
Spill Release Procedures:IF A LARGE QUANTITY IS RELEASED, EVACUATE
PERSONNEL AND ALLOW TO DISSIPATE. ANY RELEASE TO THE ENVIRONMENT OF
THIS MATERIAL MAY BE SUBJECT TO FEDERAL AND/OR STATE REPORTING
REQUIREMENTS.
Neutralizing Agent:NONE STATED.
====================== Handling and Storage ======================
Handling and Storage Precautions:THIS PRODUCT CAN CAUSE SERIOUS
PERSONAL INJURY OR DEATH, IF NOT HANDLED PROPERLY. FOLLOW OSHA
REGULATIONS FOR COMPRESSED GASES -REF.(4) & (C).
Other Precautions:NONE STATED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE GENERALLY REQUIRED FOR ADEQUATELY VENTED
SITUATIONS. WHEN EXCEEDING TWA/TLV, WEAR A SELF-CONTAINED BREATHING
APPARATUS OR SUPPLIED AIR RESPIRATOR, APPROVED BY NIOSH. AT HIGH
CONCENTRATIONS, ADD A FULL FACEPIECE.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Protective Gloves:PVA OR NEOPRENE TYPES.
Eye Protection:SAFETY GLASSES/SAFETY CHEMICAL GOGGLES.
Other Protective Equipment:PROVIDE CONVENIENT WATER SOURCE FOR
FIRST-AID TREATMENT IN CASE OF FROSTBITE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:=3.3C, 38.F
Melt/Freeze Pt:=-93.7C, -137.F
Vapor Pres:27.6 PSIA
Vapor Density:5.9
Spec Gravity:1.465
Evaporation Rate & Reference:LESS THAN ETHER.
Solubility in Water:0.013 WT%
Appearance and Odor:COLORLESS LIQUID WHICH RAPIDLY EVAPORATES,
ODORLESS.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ABRADED ALUMINUM SURFACES-CAUSE STRONG EXOTHERMIC
REACTION. AND OTHER ACTIVE METALS.
Stability Condition to Avoid:AVOID HIGH TEMPERATURES, LIGHTED
CIGARETTES, FLAMES, HOT SPOTS, WELDING.
Hazardous Decomposition Products:HALOGENS, HALOGEN ACIDS AND POSSIBLY
CARBONYL HALIDES SUCH AS PHOSGENE. THESE ARE TOXIC AND CORROSIVE.
==================== Disposal Considerations ====================
Waste Disposal Methods:TO COMPLY WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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