MSDS NAME:TIN(IV) CHLORIDE, 99%, 20893-0
NIIN:00N014988
MSDS Number: BKNKN
=== Responsible Party ===
Company:ALDRICH CHEMICAL CO INC./SUB OF SIGMA-ALDRICH CORP
Address:1001 W. ST. PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53201
Country:US
Info Phone Num:414-273-3850/FAX -4979
Emergency Phone Num:414-273-3850
CAGE:60928
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
============= Composition/Information on Ingredients =============
LD50 LC50 Mixture:LD50:(IPR,MUS)99 MG/KG. (SEE SUPP DATA)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INGESTED, INHALED OR
ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE
OF MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN.
INHALATION MAY BE FATAL AS RESULT O F SPASM, INFLAMMATION & EDEMA
OF LARYNX& BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY EDEMA.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN.
ASSURE ADEQ FLUSHING BY SEPARATING LIDS W/FINGERS. SKIN:IMMED FLUSH
W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMD
CLT HG/SHOES. WASH CONTAMD CLTHG BEFORE REUSE. DISCARD CONTAMD
SHOES. INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF
RESP), CALL MD. INGEST:CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL POWDER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPRVD SCBA,
RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE &
PLACE IN CLOSED CNTNRS FOR DISPOSAL. VENTILATE AREA & WASH SPILL
SITE AFTER MATERIAL PIC KUP IS COMPLETE.
Neutralizing Agent:SEE WASTE DISPOSAL METHOD.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP TIGHTLY
CLOSED. AVOID PRLNGD/RPTD EXPOSURE. DO NOT GET IN EYES, ON SKIN OR
CLOTHING.
Other Precautions:MOISTURE SENSITIVE. HARMFUL LIQUID. CORROSIVE. REACTS
VIOLENTLY WITH ETHYLENE OXIDE, TURPENTINE OR ALKYL NITRATES.
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:CHEM WORKERS GOG & FULL LGTH FSHLD
Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LD50-LC50 MIX:LC50:(IHL,RAT)2300 MG/M3/10M. WASTE DISP METH:EXCESS
SULFIDE W/SODIUM HYPOCHLORITE. NEUTRALIZE SOLN BEFORE FLUSHING DOWN
DRAIN. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS. EYE PROT: FACES
HIELD (8-INCH MINIMUM).
================= Stability and Reactivity Data =================
STRONG BASES, ALCOHOLS.
Stability Condition to Avoid:MAY DECOMPOSE ON EXPOSURE TO MOIST AIR OR
WATER.
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS, TIN/TIN OXIDES.
Waste Disposal Methods:MATL SHOULD BE DISSOLVED IN 1)WATER; 2)ACID SOLN
OR 3)OXIDIZED TO WATER-SOLUBLE STATE. PRECIPITATE MATL AS SULFIDE,
ADJUSTING PH OF SOLN TO 7 TO COMPLETE PRECIPITATION. FILTER
INSOLUBLES & DISPOSE OF IN HAZ WASTE SITE. DESTROY ANY (SEE SUPP
DATA)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.