===================== Product Identification =====================
MSDS NAME:DIESELINE
NIIN:00-286-5297
MSDS Number: BKSQP
=== Responsible Party ===
Company:SHELL OIL COMPANY
Address:ENVIRONMENTAL AFFAIRS
Box:4320
City:HOUSTON
State:TX
ZIP:77210
Country:US
Info Phone Num:713-241-4819
Emergency Phone Num:713-473-9461
Preparer's Name:J.C. WILLETT
CAGE:54527
=== Contractor Identification ===
Company:SHELL OIL COMPANY
Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527
============= Composition/Information on Ingredients =============
Name:PETROLEUM OIL (NO. 2 DIESEL)
CAS:68334-30-5
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS MILDLY IRRITATING TO BODY
TISSUES. BREATHING VAPORS MAY PRODUCE CENTRAL NERVOUS SYSTEM
DEPRESSION, AND PROLONGED AND/OR REPEATED SKIN CONTACT MAY CAUSE
DERMATITIS.
Explanation of Carcinogenicity:MFR REPORTS WEAK TO MODERATE DERMAL
CARCINOGENIC RESPONSE IN BIOASSAYS WITH MIDDLE DISTILLATES.
Effects of Overexposure:EYE:IRRITATION, SKIN:MILD IRRITATION,POSSIBLE
DERMATITIS WITH PROLONGED/REPEATED CONTACT. INHALED:RESPIRATORY
IRRITATION, NAUSEA, DIZZINESS, HEADACHE. ASPIRATION OF LIQUID INTO
LUNGS MAY CAUSE CHEMIC AL PNEUMONIA. INGESTED:G/I
IRRITATION,NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:PEOPLE WITH PRE EXISTING SKIN OR
RESPIRATORY DISORDERS SHOULD USE EXTRA CAUTION WHEN HANDLING OR
USING THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH
SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE
REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF
NECESSARY. INGESTED:D O NOT INDUCE VOMITING. GIVE 2 LARGE GLASSES
OF MILK OR WATER AND GET IMMEDIATE MEDICAL CARE. GIVE NOTHING BY
MOUTH IF UNCONSCIOUS. IF IRRITATION PERSISTS OR IS SEVERE,SEE A
DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:125F,52C
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL. DO NOT USE DIRECT STREAM OF WATER;PRODUCT FLOATS; MAY
SPREAD FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG GROUND OR FLOOR, THEN 'FLASH BACK' FROM A DISTANT
IGNITION SOURCE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. MINOR: ABSORB
MATERIAL WITH CLAY, VERMICULITE, OR SIMILAR ABSORBENT MATERIAL.
PLACE IN DISPOSAL CONTAINERS. MAJOR: DIKE & CONTAIN SPILL. SHUT OFF
LEAKS. RECOVER LIQUID F OR RECLAIM. ABSORB REMAINDER FOR DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN FLAMMABLE/COMBUSTIBLE LIQUIDS
AREA. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR.
TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON
THEM. GROUND CONTAINERS BEFORE TRANSFERRING LIQUID. AVOID HAVING
OPEN ELECTRICAL EQ UIPMENT IN VAPOR AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR
ORGANIC VAPOR IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR 1910.134
FOR REGULATIONS PERTAI NING TO RESPIRATOR USE.
Ventilation:LOCAL AND MECHANICAL EXHAUST RECOMMENDED. USE EXPLOSION
PROOF VENTILATING EQUIPMENT.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GLASSES OR SPLASH GOGGLES D
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. WEAR
IMPERVIOUS CLOTHING AS NEEDED TO PREVENT PROLONGED/REPEATED SKIN
CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICES. AVOID
PROLONGED/REPEATED CONTACT. DO NOT EAT, DRINK OR SMOKE IN WORK
AREA.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:450F,232C
Vapor Density:>1
Spec Gravity:0.8762
Solubility in Water:NEGLIGIBLE
Appearance and Odor:YELLOW LIQUID, STRONG HYDROCARBON ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:SMOKE, CARBON MONOXIDE, CARBON DIOXIDE
AND OTHER HYDROCARBON COMPOUNDS DURING COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER MAKES NO SUGGESTIONS AS TO METHOD OF
DISPOSAL. HMIS SUGGESTS INCINERATION.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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