===================== Product Identification =====================
MSDS NAME:BRAZED TUNGSTEN CARBIDE TOOLS
NIIN:00-090-1337
MSDS Number: BLYYB
=== Responsible Party ===
Company:OHIO METAL WORKING PRODUCTS CO
Address:2501 WINFIELD WAY NE
Box:7069
City:CANTON
State:OH
ZIP:44705
Country:US
Info Phone Num:216-453-8438
Emergency Phone Num:216-453-8438
CAGE:0BZR8
=== Contractor Identification ===
Company:HANDY & HARMAN
Address:850 THIRD AVENUE
Box:City:NEW YORK
State:NY
ZIP:10022
Country:US
Phone:212-752-3400
CAGE:73977
Company:OHIO METAL WORKING PRODUCTS CO
Address:2501 WINFIELD WAY NE
Box:City:CANTON
State:OH
ZIP:44705
Country:US
Phone:216-453-8438
CAGE:0BZR8
============= Composition/Information on Ingredients =============
Name:TUNGSTEN CARBIDE
CAS:12070-12-1
RTECS #:YO7250000
Fraction by Wt: 30-97%
Other REC Limits:NONE SPECIFIED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Name:COBALT (SARA III)
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: 2-30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1 MG/M3;AS CO
ACGIH TLV:0.05 MG/M3;DUST 9293
Name:TANTALUM CARBIDE
CAS:12070-06-3
Fraction by Wt: 0.1-56%
Other REC Limits:NONE SPECIFIED
Name:CHROMIUM CARBIDE
CAS:12012-35-0
Fraction by Wt: <10%
Other REC Limits:NONE SPECIFIED
Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: <10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SILVER (SARA III)
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: <50%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: <15.5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: <15.5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 MG/M3 ZNO
ACGIH TLV:10 MG/M3; 9192 ZNO
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CADMIUM (SARA III)
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: <16.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE 1910.1027
ACGIH TLV:0.01 MG/M3 DUST;9394
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: <3.0%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION-IRRITATION,
TRANSIENT RESPIRATORY DISEASE,. EYES-IRRITATION. SKIN- IRRITATION,
ALLERGIC RASH. INGESTION-GIDDINESS, NAUSEA, DIARRHEA,ANEMIA, KIDNEY
MALFUNCTION. CHRONIC: INHALATION-PE RMANENT RESPIRATORY
DISEASE.SKIN- ALLERGIC RASH. ALSO SLEEPLESSNESS, LIVER DAMAGE, LOSS
OF SMELL.
Explanation of Carcinogenicity:NTP AND IARC LIST CHROMIUM, CADMIUM AS
KNOWN AND NICKEL AS SUSPECTED CARCINOGENS.
Effects of Overexposure:INHALATION: INFLAMMATION OF NOSE, THROAT.
COUGHING, WHEEZING,SHORTNES OF BREATH, AND CHEST TIGHTNESS. EYES:
REDNESS, BURNING. SKIN: RASH. INGESTION: NAUSEA, GIDDINESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
PRE-EXISTING SKIN AND RESPIRATORY AILMENTS MAY BE AGGRAVATED BY
OVEREXPOSURE TO DUSTS FROM GRINDING/MACHINING OPERATIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMS DEVELOP, REMOVE FROM EXPOSURE AND SEE
DOCTOR. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. SEE DOCTOR.
SKIN: WASH WITH SOAP AND WATER. IF SYMPTOMS PERSIST, SEE DOCTOR.
INGEST ION: DILUTE WITH LARGE AMOUNT OF WATER,INDUCE VOMITING AND
SEEK MEDICAL HELP.
===================== Fire Fighting Measures =====================
Extinguishing Media:FOR POWDER FIRES, USE DRY SAND, DRY DOLOMITE, DRY
GRAPHITE POWDER.
Fire Fighting Procedures:NOT A FIRE HAZARD. DUSTS PRODUCED IN GRINDING
OPERATIONS MAY IGNITE IF ALLOWED TO ACCUMULATE. USE SELF-CONTAINED
BREATHING APPARATUS FIGHTING POWDER FIRES.
Unusual Fire/Explosion Hazard:DUSTS MAY PRESENT A FIRE OR EXPLOSION
HAZARD UNDER RARE CONDITIONS OF PARTICLE SIZE, DISPERSION, AND
STRONG IGNITION SOURCE. NOT FOUND UNDER NORMAL CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP USING METHODS WHICH MINIMIZE DUST
GENERATION ( WET MOP OR VACUUM). CONTACT LOCAL ENVIRONMENTAL
MANAGER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING TO PREVENT
DUST BUILDUP DURING MACHINING. AVOID DUST INHALATION AND DIRECT
SKIN CONTACT WITH DUST.
Other Precautions:IF AIRBORN DUST GENERATED, USE APPROPRIATE USE
NIOSH/MSHA APPROVED RESPIRATOR. DO NOT SHAKE CLOTHING, RAGS, OR
OTHER ITEMS TO REMOVE DUST. REMOVE DUST BY WASHING, LAUNDERING OR
VACUMING (FILTERED) CLO THES AND RAGS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF DUSTY CONDITIONS DEVELOP, USE NIOSH/MSHA
APPROVED RESPIRATOR FOR DUSTS/MISTS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Protective Gloves:LEATHER WORK GLOVES
Eye Protection:SAFETY GLASSES
Other Protective Equipment:BARRIER CREAM CAN BE USED WITH THE GLOVES.
EYE WASH STATION SHOULD BE NEAR BY.
Work Hygienic Practices:WASH HANDS AFTER USE. LAUNDER CLOTHING BEFORE
REUSE. CLEAN FOOTWEAR BEFORE REUSE.
Supplemental Safety and Health
MSDS IS FOR BOTH THE TUNGSTEN CARBIDE AND THE BRAZING MATERIAL WHICH
HOLDS THESE TOOLS TOGETHER. MANUFACTURER SUPPLIED TWO MSDS'. HMIS
COMBINED THESE TWO MSDS'INTO ONE.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:5198F,2870C
Spec Gravity:9.5-15.5
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK GRAY METAL, ODORLESS
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. AVOID
BUILD-UP OF DUST TRHOUGH GOOD HOUSEKEEPING PRACTICES.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. CONTACT LOCAL ENVIRONMENTAL MANAGER.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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