===================== Product Identification =====================
MSDS NAME:SULFURIC ACID 66 DEGREE
NIIN:00-975-0707
MSDS Number: BMTPL
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:614-790-3333, 800-274-5263
CAGE:5A188
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:City:DUBLIN
State:OH
ZIP:43017
Country:US
Phone:614-889-4505
CAGE:5A188
Company:SANCHEZ & ASSOCIATES
Address:476 WEST FOGG STREET
Box:1649
City:COLTON (MAY BE OUT OF BUSINESS !)
State:CA
ZIP:92324
Country:US
Phone:714-370-3921/FAX824-0341 ALL WRONG#
CAGE:0HF19
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 93%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT = 2140 MG/KG BODY WEIGHT
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE - INGESTION: CAUSES MOUTH,
THROAT, ESOPHAGUS, STOMACH BURNS, GASTRIC PERFORATION AND DEATH.
INHALATION: SEVERE IRRITATION OF THE RESPIRATORY TRACT, LUNG
DAMAGE. SKIN: SEVERE BURNS. EYES: IRREVER SIBLE DAMAGE AND POSSIBLY
BLINDNESS. CHRONIC - DERMATITIS, BRONCHITIS, ULCERATION.
Effects of Overexposure:IRRITATION TO THE EYES AND RESPIRATORY TRACT.
ULCERATION AND SEVERE BURNS TO ALL TISSUES, PAIN AND DISCOMFORT.
Medical Cond Aggravated by Exposure:EXISTING SKIN LESIONS, BREATHING OF
SPRAYS (SULFURIC ACID MISTS) MAY AGGRAVATE ASTHMA AND OTHER CHRONIC
PULMONARY DISEASES.
======================= First Aid Measures =======================
First Aid:START FIRST AID AND GET MEDICAL CARE AT ONCE. EYES: HOLD
EYELID OPEN AND FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN:
WIPE EXCESS WITH A DRY CLOTH, THEN WASH WITH PLENTY OF WATER AND
SOAP. INHALATI ON: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: IF CONSCIOUS, DRINK 2 TO 3 GLASSES OF WATER. DO NOT
INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Flash Point:NONCOMBUSTIBLE
Extinguishing Media:DRY CHEMICAL. EXPECT VIOLENT REACTION WITH WATER.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. FIGHT FIRE FROM A
SAFE DISTANCE. USE ACID RESISTANT EQUIPMENT.
Unusual Fire/Explosion Hazard:REACTS WITH METALS TO PRODUCE EXPLOSIVE
HYDROGEN GAS. REACTS VIOLENTLY WITH WATER, PRODUCING HEAT AND
SPATTERING, CAUSING NEARBY COMBUSTIBLES TO IGNITE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT.STOP LEAK IF
POSSIBLE.SMALL SPILLS SHOULD BE COVERED WITH NA BICARBONATE,SODA
ASH,OR LIME.AVOID FOAMING/SPATTERING.PICK UP WITH ABSORBING
MATERIAL & TRANSFER TO A SUITABLE CH EMICAL WASTE CONTAINER.DON'T
WASH IT DOWN TO SEWER
Neutralizing Agent:LIME OR SODA
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA IN A TIGHTLY CLOSED CONTAINER AWAY FROM SUNLIGHT.
Other Precautions:KEEP IN AN AREA WITH AN ACID RESISTANT CEMENT FLOOR.
DO NOT BREATHE SPRAYS OR MISTS. DO NOT INGEST, GET IN EYES, ON
SKIN, OR ON CLOTHING. DILUTE ACID BY ADDING IT SLOWLY TO WATER AND
MIXING AND COOLIN G IT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED MIST FILTER, ACID GAS
CARTRIDGE RESPIRATOR. USE POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS FOR EMERGENCY CONDITIONS WHERE EXPOSURE LIMITS
ARE EXCEEDED.
Ventilation:LOCAL EXHAUST
Protective Gloves:RUBBER
Eye Protection:SPLASH-PROOF SAFETY GOGGLES/FACE SHIELD
Other Protective Equipment:SINK, SAFETY SHOWER, EYEWASH FOUNTAIN,
OXYGEN, FULL-BODY PROTECTIVE CLOTHING
Work Hygienic Practices:WASH HANDS BEFORE EATING OR DRINKING.
Supplemental Safety and Health
DANGER! CAUSES SEVERE BURNS. REACTS VIOLENTLY WITH WATER. HIGHLY
REACTIVE AND CAPABLE OF IGNITING COMBUSTIBLE MATERIALS ON CONTACT.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:535F,279C
Vapor Pres:< 0.01
Spec Gravity:1.836
pH:< 1
Evaporation Rate & Reference:< 1 (ETHER = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS TO CLOUDY, OILY LIQUID. ODORLESS.
Percent Volatiles by Volume:5-10
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, COMBUSTIBLES, POWDERED METALS, ORGANIC MATERIALS.
Stability Condition to Avoid:WHEN DILUTING, ACID SHOULD BE ADDED TO
DILUENT. DO NOT ADD DILUENT TO SULFURIC ACID.
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN SULFIDE,
HYDROGEN GAS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE, AND FEDERAL REGULATIONS. THIS MATERIAL IS RCRA
HAZARDOUS WASTE D002, CORROSIVE AND D003, REACTIVE. SPILLS ARE
SUBJECT TO REPORTING REQUIREMEN TS OF SECTION 313 OF SARA TITLE
III. RQ= 1000 LBS
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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