===================== Product Identification =====================
MSDS NAME:REGULAR UNLEADED GASOLINE
NIIN:00-264-6217
MSDS Number: BMZCP
=== Responsible Party ===
Company:DIAMOND SHAMROCK REFINING AND MARKETING CO
Address:9830 COLONNADE BLVD
Box:696000
City:SAN ANTONIO
State:TX
ZIP:78269-6000
Country:US
Info Phone Num:512-641-8800
Emergency Phone Num:512-641-8800
CAGE:3P045
=== Contractor Identification ===
Company:DIAMOND SHAMROCK REFINING AND MARKETING CO
Address:9830 COLONNADE BLVD
Box:696000
City:SAN ANTONIO
State:TX
ZIP:78269-6000
Country:US
Phone:210-641-8601
CAGE:3P045
============= Composition/Information on Ingredients =============
Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: < 9% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9192
Name:PENTANE
CAS:109-66-0
RTECS #:RZ9450000
Fraction by Wt: < 2% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM/750 STEL
ACGIH TLV:600 PPM/750STEL;9293
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: < 3% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:HEXANE (ISOMERS OTHER THAN N-HEXANE)
Fraction by Wt: < 6.5% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:500 PPM
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: < 3.5% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: < 9% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: < 2% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: < 9% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TRIMETHYL BENZENE (SARA III)
CAS:25551-13-7
RTECS #:DC3220000
Fraction by Wt: < 4.5% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9192
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 0 - 15%
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 0-11%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:RESPIRATORY TRACT IRRITATION, CENTRAL
NERVOUS SYSTEM STIMULATION, COMA, RESPIRATORY ARREST, DEFATTING OF
SKIN, SKIN IRRITATION, SEVERE EYE IRRITATION, IRRITATION OF
GASTROINTESTINAL TRACT, DEPRESSION.
Explanation of Carcinogenicity:BENZENE, A COMPONENT OF THIS PRODUCT, IS
CLASSIFIED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:UPPER RESPIRATORY TRACT IRRITATION, DEPRESSION,
DIZZINESS, HEADACHE, INCOORDINATION, ANESTHESIA, COMA, RESPIRATORY
ARREST, DEFFATING OF THE SKIN, BURNING SENSATION OF THE SKIN,
SEVERE BURNING SENSATIO N IN THE EYES WITH TEMPORARY IRRITATION&
SWELLING OF LIDS, IRRITATION OF THROAT, ESOPHAGUS, STOMACH, NAUSEA,
VOMITING.
Medical Cond Aggravated by Exposure:PREEXISITING RESPIRATORY CONDITIONS
AND/OR SKIN DISORDERS.
======================= First Aid Measures =======================
Eyes: FLUSH MATERIAL OUT THEN SEEK MEDICAL ATTENTION.
IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.
SKIN: WASH CONTAMINATED AREAS WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING . INHALATION: REMOVE TO FRESH AIR. IF
BREATHING HAS STOPPED, RESUSCITATE. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH IF
UNCONSCIOUS. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:<-40F,<-40C
Lower Limits:1 %
Upper Limits:8 %
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER
SPRAY. WATER MAY BE INEFFECTIVE BUT USE TO KEEP CONTAINERS COOL.
Fire Fighting Procedures:PRESSURE-DEMAND, SELF-CONTAINED BREATHING
APPARATUS SHOULD BE PROVIDED FOR FIRE FIGHTERS IN BUILDINGS OR
CONFINED SPACES WHERE PRODUCT IS STORED.
Unusual Fire/Explosion Hazard:CLOTHING, RAGS OR SIMILAR ORGANIC
MATERIAL CONTAMINATED WITH THIS PRODUCT AND STORED IN A CLOSED
SPACE MAY UNDERGO SPONTANEOUS COMBUSTION. USE GROUNDED CONTAINR
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN LIQUIDS AND PREVENT DISCHARGES TO
STREAMS OR SEWER SYSTEMS. CONTROL OR STOP THE LOSS OF VOLATILE
MATERIALS TO THE ATMOSPHERE. SPILLS OR RELEASES SHOULD BE REPORTED
TO THE APPROPRIATE LOCAL, ST ATE AND FEDERAL REGULATORY AGENCIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICAL
DAMAGE. OUTSIDE OR DETACHED STORAGE IS PREFERRED. SEPARATE FROM
OXIDIZING MATERIALS.
Other Precautions:STORE IN COOL, WELL-VENTILATED AREA OF
NON-COMBUSTIBLE CONSTRUCTION AWAY FROM POSSIBLE SOURCES OF
IGNITION. NOTE TO PHYSICIAN: GASTRIC LAVAGE ONLY IF LARGE QUANTITY
HAS BEEN INGESTED. GUARD AGAINST A SPIRATION INTO THE LUNGS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION FOLLOWING MANUFACTURER'S
RECOMMENDATION WHERE SPRAY, MIST OR VAPOR MAY BE GENERATED.
POSITIVE PRESSURE SUPPLIED AIR REQUIR ED FOR IDLH AREAS.
Ventilation:WORK IN WELL VENTILATED AREAS. USE GOOD ENGINEERING TO
PROCESS, TRANSFER AND STORE.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:FACE SHIELD AND GOGGLES OR CHEMICAL GOGS
Other Protective Equipment:STANDARD WORK CLOTHING. SHOES CONTAMINATED
WITH THIS PRODUCT THAT CAN NOT BE DECONTAMINATED SHOULD BE
DISCARDED.
Work Hygienic Practices:WEAR IMPERVIOUS GLOVES WHEN "DIP-STICKING
STORAGE TANKS". WORK UPWIND OF SMALL SPILLS.
Supplemental Safety and Health
DO NOT USE THIS PRODUCT AS A SOLVENT FOR CLEANING EQUIPMENT OR SKIN.
STORE SMALL QUANTITIES ONLY IN SAFETY CANS. ALLOW CONTAMINATED RAGS
TO DRY IN WELL-VENTILATED AREA BEFORE STORAGE. PRODUCT SPREADS
EASILY AND CAN FLASH BACK ALONG VAPOR TRAILS.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:B.P. Text:80 - 437F
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:4-7 PSI
Vapor Density:3.4
Spec Gravity:0.68 -0.76
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:TRACE
Appearance and Odor:COLORED LIQUID WITH PUNGENT ODOR; ODOR THRESHOLD
0.1 PPM.
Percent Volatiles by Volume:100 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS
Stability Condition to Avoid:IGNITION SOURCES, EXTREME HEAT
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:SHIPMENT, STORAGE AND/OR DISPOSAL OF WASTE
MATERIALS MUST MEET ALL APPLICABLE LOCAL, STATE, AND FEDERAL RULES
AND REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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