===================== Product Identification =====================
MSDS NAME:CRUDE OIL
NIIN:00-111-3011
MSDS Number: BMYZZ
=== Responsible Party ===
Company:PHIBRO ENERGY INC SUB OF PHILLIP BROTHERS INC
Address:600 STEAMBOAT ROAD
City:GREENWICH
State:CT
ZIP:06830-7149
Country:US
Info Phone Num:203-661-4770
Emergency Phone Num:713-923-6641/800-424-9300
Preparer's Name:SUE BOTTOM
CAGE:2Y747
=== Contractor Identification ===
Company:PHIBRO ENERGY INC. - SUB OF PHILIPP BROTHERS INC
Address:600 STEAMBOAT RD
Box:City:GREENWICH
State:CT
ZIP:06830-7149
Country:US
Phone:203-661-4770
CAGE:2Y747
============= Composition/Information on Ingredients =============
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 0.1-5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 1-7% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9192
Name:CYCLOHEXANE (SARA III)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: <1-4% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CYCLOPENTANE
CAS:287-92-3
RTECS #:GY2390000
Fraction by Wt: <1-2% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:600 PPM
ACGIH TLV:600 PPM; 9192
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <1-3%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:N-HEPTANE
CAS:142-82-5
RTECS #:MI7700000
Fraction by Wt: 1-5% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9293
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 2-8% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:HYDROGEN SULFIDE (SARA III)
CAS:7783-06-4
RTECS #:MX1225000
Fraction by Wt: <0.1-3%
Other REC Limits:NONE SPECIFIED
OSHA PEL:(C),20 PPM
ACGIH TLV:10 PPM/15 STEL; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:METHYLCYCLOHEXANE
CAS:108-87-2
RTECS #:GV6125000
Fraction by Wt: 1-4% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:400 PPM; 9293
Name:NONANE
CAS:111-84-2
RTECS #:RA6115000
Fraction by Wt: 1-4% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM; 9192
Name:OCTANE
CAS:111-65-9
RTECS #:RG8400000
Fraction by Wt: 1-5% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM/375 STEL
ACGIH TLV:300 PPM/375STEL;9293
Name:PENTANE
CAS:109-66-0
RTECS #:RZ9450000
Fraction by Wt: 1-6% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM/750 STEL
ACGIH TLV:600 PPM/750STEL;9293
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 1-4% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
Name:SULFUR
CAS:7704-34-9
RTECS #:WS4250000
Fraction by Wt: <0.1-3%
Other REC Limits:NONE SPECIFIED
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <1-2% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <1-3% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:HEXANE (ISOMERS OTHER THAN N-HEXANE)
Fraction by Wt: 1-5% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:500 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:MAY CAUSE SEVERE EYE IRRITATION,
CONJUNCTIVITIS, MAY CAUSE MODERATE SKIN IRRITATION, DEFATTING,
DERMATITIS, NASAL AND RESPIRATORY TRACT IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS, POSSIBLE SECONDARY I NFECTION, ANEMIA, IRREGULAR
HEART RHYTHM, BEHAVIORAL CHANGES, HARMFUL OR FATAL IF SWALLOWED,
GASTROINTESTINAL DISTURBANE
Explanation of Carcinogenicity:BENZENE, A COMPONENT OF CRUDE OIL, IS
LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:EYE IRRITATION, REDNESS, TEARING, BLURRED
VISION, SKIN IRRITATION, CRACKING, REDNESS, ITCHING, INFLAMMATION,
EXCITATION, EUPHORIA, CONTRACTED EYE PUPILS, DIZZINESS, DROWSINESS,
FATIGUE, NAUSEA, HEADAC HE, LOSS OF REFLEXES, TREMORS, CONVULSIONS,
SEIZURES, LOSS OF CONSCIOUSNESS, COMA, DEPRESSION, DIARRHEA,
VOMITING.
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, HEART,
CENTRAL NERVOUS SYSTEM AND RESPIRATORY DISORDERS MAY BE AGGRAVATED
BY EXPOSURE TO THIS PRODUCT. IMPAIRED KIDNEY, LIVER AND BLOOD
DISORDERS MAY BE AGGRAVATED.
======================= First Aid Measures =======================
Eyes: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: WASH EXPOSED AREA THOROUGHLY WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. HIGH PRESSURE SKIN
INJECTION S ARE SERIOUS MEDICAL EMERGENCIES! GET IMMEDIATE MEDICAL
ATTENTION. INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY.
INGESTION: DO NOT INDUCE VOMITING. GIVE VEGETABLE OIL. GET MEDICAL
ATTENTION
===================== Fire Fighting Measures =====================
Flash Point:-40 TO 200F
Autoignition Temp:Autoignition Temp Text:500F
Lower Limits:0.4 %
Upper Limits:15 %
Extinguishing Media:DRY CHEMICAL, HALON, FOAM AND CARBON DIOXIDE ARE
PREFERRED. FOAM AND WATER FOG CAN CAUSE FROTHING.
Fire Fighting Procedures:PRODUCT WILL RELEASE FLAMMABLE VAPORS WHICH
CAN BURN IN OPEN OR BE EXPLOSIVE IN CONFINED SPACE. PUMP CONTENTS
FROM TANK AND COOL TANKS WITH WATER.
Unusual Fire/Explosion Hazard:IMPROPER USE OF WATER MAY CAUSE FROTHING
AND SPREAD FIRE OVER LARGER AREA. VAPOR OR GAS MAY SPREAD TO
DISTANT IGNITION SOURCES AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:STAY UPWIND AND AWAY FROM SPILL. DO NOT ENTER
OR STAY IN AREA UNLESS MONITORING INDICATES OK. ISOLATE HAZARD
AREA; RESTRICT ENTRY. RECOVER AS MUCH AS POSSIBLE. THEN ABSORB AND
HANDLE IAW ENVIRONMENTAL REGULATIONS. KEEP OUT OF
SEWERS/WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARK AND FLAMES.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL ON OR NEAR THIS
CONTAINER. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:SPECIAL H2S WARNING: CARE MUST BE TAKEN BY THOSE WHO
ARE RENDERING AID TO THE VICTIM BECAUSE H2S MAY BE IN AREA AND MAY
ALSO OVERCOME RESCUERS UNLESS IT HAS BEEN DETERMINED THAT THE AREA
IS FREE OF HY DROGEN SULFIDE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PROPER RESPIRATOR SELECTION SHOULD BE DETERMINED
BY ADEQUATELY TRAINED PERSONNEL, BASED ON THE CONTAMINANTS, THE
DEGREE OF POTENTIAL EXPOSURE AND PUBLISHED RESPIRATORY PROTECTION
FACTORS. THIS SHOULD BE AVAILABLE FOR ROUTINE AND NONROUTINE
Ventilation:USE IN WELL VENTILATED AREA. IN CONFINED SPACE, MECHANICAL
VENTILATION MAY BE NECESSARY TO KEEP BELOW PEL/TLVS
Protective Gloves:NEOPRENE, NITRILE-BUTADIENE RUBBER, ETC
Eye Protection:SAFETY GLASSES, CHEMICAL SPLASH GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING/BOOTS, EMERGENCY
EYEWASH/SHOWER. NOTTE: DO NOT CONTACT LENSES WHEN WORKING AROUND
THIS PRODUCT.
Work Hygienic Practices:LEATHER GOODS CONTAMINATED WITH THIS PRODUCT
SHOULD BE DISCARDED. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
VAPORS MAY ACCUMULATE IN LOW AREAS. VAPORS MAY CONCENTRATE IN CONFINED
AREAS. USE ADEQUATE GROUNDING TO PREVENT STATIC BUILDUP. RUNOFF TO
SEWER MAY CAUSE FIRE OR EXPLOSION HAZARD. CONTAMINATED CLOTHIN G,
RAGS OR SIMILAR ORGANIC MATERIAL STORED IN CLOSED SPACE MAY
SPONTANEOUSLY IGNITE.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:>1000F,>538
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:0.6 - 10
Vapor Density:> 1
Spec Gravity:0.7 - 1.1 @60F
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:SLIGHT
Appearance and Odor:DARK BROWN/BLACK LIQUID WITH HYDROCARBON/SULFIDE
ODOR
Percent Volatiles by Volume:40-60%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS (PEROXIDE, DICHROMATE, PERMANGANATE,
CHLORINE, ETC), STRONG ACIDS, CAUSTICS AND HALOGENS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, STATIC
ELECTRICITY OR OTHER POTENTIAL IGNITION SOURCES SHOULD BE AVOIDED.
DO NOT SWITCH LOAD.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
REACTIVE HYDROCARBONS (ALDEHYDES, AROMATICS, ETC) COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF MATERIAL IN ACCORDANCE WITH LOCAL,
COUNTY, STATE AND FEDRAL REGULATIONS. CONTACT STATE AND FEDERAL
REGULATORS TO DETERMINE WASTE CLASSIFICATION. USE LICENSED
TRANSPORTER AND DISPOSAL FACILI TY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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