| MSDS | : | A416, 2-PROPANOL | | CAS | : | 67-63-0 | | NAME | : | isopropyl alcohol; (2-propanol) (sara iii)
supdat:tank/rail car/tank truck is involved in fire. exting
ing 2:amts as fog, solid streams may not be eftive. cool
ing 3:as possible.
eft of overexp:which substances are responsible. skin:narc.
ing 5:in few sensit individuals. may be dermally absorb
ing 6:chronic:rptd/prlng expos may cause derm due to defat.
ing 7:caused mild transitory injury & 50% aqueous soln
ing 8:irrit & corneal opacity. chronic:prlng/rptd expos to
ing 9:abdom pain, naus, vomit & hemorr, cns depress may
ing 10:hypotension & refractory narcos, oliguria followed
ing 11:hypoglycemia, tenderness & edema of muscles &
ing 12:resp & death due to resp paral may occur. sev &
ing 13:no adverse efts resulted in humans following daily
ing 14:rabbits produced anesthesia & death. reproductive
first aid proc:upper & lower lids, until no evid of chem
ing 16:resp depress, give o*2 by artf resp. give activated
ing 17:if delayed. do not try emesis if resp is depress.
spill proc:smoking, flames/flares in haz area. keep unnec
other prec:containers which meet bonding & grounding
ing 20:incompatible substances.
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===================== Product Identification =====================
MSDS NAME:A416, 2-PROPANOL
NIIN:01-019-4699
MSDS Number: BNTNX
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410-2802
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:ISOPROPYL ALCOHOL; (2-PROPANOL) (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 100%
OSHA PEL:400 PPM;500 PPM STEL
ACGIH TLV:400 PPM;500 PPM STEL
Name:SUPDAT:TANK/RAIL CAR/TANK TRUCK IS INVOLVED IN FIRE. EXTING
ONLY IF FLOW CAN BE STOPPED; USE H*2O IN FLOODING (ING 3)
RTECS #:9999999ZZ
Name:ING 2:AMTS AS FOG, SOLID STREAMS MAY NOT BE EFTIVE. COOL
CNTNRS W/FLOODING QTYS OF H*2O, APPLY FROM AS FAR DIST (ING 4)
RTECS #:9999999ZZ
Name:ING 3:AS POSSIBLE.
RTECS #:9999999ZZ
Name:EFT OF OVEREXP:WHICH SUBSTANCES ARE RESPONSIBLE. SKIN:NARC.
ACUTE:MAY CAUSE SLIGHT IRRIT. CONT DERM HAS BEEN RPTD(ING 6)
RTECS #:9999999ZZ
Name:ING 5:IN FEW SENSIT INDIVIDUALS. MAY BE DERMALLY ABSORB
RESULTING IN SYSTEMIC TOX AS DETAILED IN ACUTE INGEST. (ING 7)
RTECS #:9999999ZZ
Name:ING 6:CHRONIC:RPTD/PRLNG EXPOS MAY CAUSE DERM DUE TO DEFAT.
EYE:ACUTE:MAY CAUSE IRRIT. IN RABBIT EYES, DROP (ING 8)
RTECS #:9999999ZZ
Name:ING 7:CAUSED MILD TRANSITORY INJURY & 50% AQUEOUS SOLN
AFTER 3 MIN CAUSED MOD IRRIT. CONT W/70% SOLN CAUSED CONJ,(ING 9)
RTECS #:9999999ZZ
Name:ING 8:IRRIT & CORNEAL OPACITY. CHRONIC:PRLNG/RPTD EXPOS TO
VAPS MAY CAUSE CONJ. INGEST:NARC. ACUTE:MAY CAUSE (ING 10)
RTECS #:9999999ZZ
Name:ING 9:ABDOM PAIN, NAUS, VOMIT & HEMORR, CNS DEPRESS MAY
OCCUR W/HDCH, DIZZ, FLUSHING, INCOORD, STUPOR, CONFSN, (ING 11)
RTECS #:9999999ZZ
Name:ING 10:HYPOTENSION & REFRACTORY NARCOS, OLIGURIA FOLLOWED
BY DIURESIS & COMA MAY OCCUR. OTHER SYMPS MAY INCL (IN 12)
RTECS #:9999999ZZ
Name:ING 11:HYPOGLYCEMIA, TENDERNESS & EDEMA OF MUSCLES &
ARRHYTHMIAS. VOMIT W/ASPIR MAY CAUSE ASPIR PNEUM. DEPRESSED(ING 13)
RTECS #:9999999ZZ
Name:ING 12:RESP & DEATH DUE TO RESP PARAL MAY OCCUR. SEV &
PRLNG SHOCK MAY LEAD TO SERIOUS/FATAL RENAL DMG. CHRONIC:(ING 14)
RTECS #:9999999ZZ
Name:ING 13:NO ADVERSE EFTS RESULTED IN HUMANS FOLLOWING DAILY
INGEST. RATS SHOWED DECR BODY WT. PRLNG INGEST IN (ING 15)
RTECS #:9999999ZZ
Name:ING 14:RABBITS PRODUCED ANESTHESIA & DEATH. REPRODUCTIVE
EFFECTS HAVE BEEN REPORTED IN ANIMALS.
RTECS #:9999999ZZ
Name:FIRST AID PROC:UPPER & LOWER LIDS, UNTIL NO EVID OF CHEM
REMAINS (APPROX 15-20 MIN). GET MD IMMED. INGEST:IN (ING 17)
RTECS #:9999999ZZ
Name:ING 16:RESP DEPRESS, GIVE O*2 BY ARTF RESP. GIVE ACTIVATED
CHARCOAL. GASTRIC LAVAGE W/PROT AIRWAY IS USEFUL EVEN(ING 18)
RTECS #:9999999ZZ
Name:ING 17:IF DELAYED. DO NOT TRY EMESIS IF RESP IS DEPRESS.
MAINT BLOOD PRESS. TREATMENT SHLD BE ADMIN BY QUALIFIED MD.
RTECS #:9999999ZZ
Name:SPILL PROC:SMOKING, FLAMES/FLARES IN HAZ AREA. KEEP UNNEC
PEOPLE AWAY; ISOLATE HAZ AREA & DENY ENTRY.
RTECS #:9999999ZZ
Name:OTHER PREC:CONTAINERS WHICH MEET BONDING & GROUNDING
GUIDELINES SPECIFIED IN NFPA 77-1983. STORE AWAY FROM (ING 21)
RTECS #:9999999ZZ
Name:ING 20:INCOMPATIBLE SUBSTANCES.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)5045 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:IRRIT/NARC, 12,000 PPM IDLH.
ACUTE:HUMAN SUBJS EXPOS TO 400 PPM FOR 3-5 MINS HAD MILD IRRIT OF
NOSE & THROAT. @ 800 PPM IRRIT WAS NOT SEV BUT UNCOMFORTABLE.
HIGHER CONCS MAY CAUSE EFTS AS DETAIL ED IN ACUTE INGEST. LGTH OF
TIME TO PRDCE NARCOS IN ANIMALS WAS INVERSELY PROPORTIONAL TO CONC.
CHRONIC:(EFT OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:IN ANIMAL STUDIES, REVERSIBLE FATTY
CHANGES WERE OBSERVED IN LIVER. MALE MICE EXHIBITED HYALINE DROPLET
NEPHROPATHY. REPRO EFTS HAVE BEEN RPTD IN ANIMALS. THERE HAS BEEN
INCR INCIDENCE OF CAN CER OF PARANASAL SINUSES & POSS OF LARYNX, IN
MFR OF ISOPROPYL ALCOHOL BY STRONG ACID PROCESS, IT IS NOT CLEAR
(ING 5)
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS, IMPAIRED LIVER, RENAL &/OR PULMONARY FUNCTION.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED.IF BRTHG HAS
STOPPED, PERFORM ARTF RESP. KEEP PERS WARM & @ REST. TREAT
SYMPTOMATICALLY & SUPPORTIVELY. GET MD IMMED. SKIN:REMOVE CONTAM
CLTHG & SHOES I MMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG
AMTS OF H*2O UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MINS), GET
MD IMMED. EYE:WASH IMMED W/LG AMTS OF H*2O/NORM SALINE, OCCAS
LIFTING (ING 16)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:53.0F,11.7C
Lower Limits:2%
Upper Limits:12% @ 93C
Extinguishing Media:DRY CHEM/CO*2/H*2O SPRAY/ALCOHOL-RESISTANT FOAM.
FOR LGR FIRES, USE H*2O SPRAY/FOG/ALCOHOL-RESISTANT FOAM. ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. APPLY
COOLING H*2O TO SIDES OF CNTNRS EXPOS(SUPDAT)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZ WHEN EXPOS TO
HEAT/FLAME. VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO
SOURCE OF IGNIT & FLASH BACK. VAP-AIR MIXTS ARE EXPLO >FL PT.
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGNIT SOURCES, STOP LEAK IF YOU CAN
DO IT W/OUT RISK. USE H*2O SPRAY TO REDUCE VAPS. FOR SM SPILLS,
TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER
DISP. FOR LGR SPILLS, DIKE F AR AHEAD OF SPILL FOR LATER DISP. NO
(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONT W/HEAT, SPKS, FLAMES/OTHER
SOURCES OF IGNIT. VAPS MAY BE EXPLO & POISONOUS; DO NOT ALLOW UNNEC
PERS IN AREA. DO NOT OVERHEAT CNTNRS.
Other Precautions:CNTNRS MAY VIOLENTLY RUPTURE & TRAVEL CONSIDERABLE
DIST IN HEAT OF FIRE. OBSERVE ALL FED, STATE & LOC REGS WHEN
STORING SUBSTANCE. SUBSTANCES W/LOW ELECTROCONDUCTIVITY, WHICH MAY
BE IGNITED BY ELECTRO STATIC SPKS, SHLD BE STORED IN (ING 20)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPEC RESP SELECTED MUST BE BASED ON CONTAM
LEVELS FOUND IN WORKPLACE, MUST NOT EXCEED WORKING LIMS OF RESP &
BE JOINTLY APPRVD BY NIOSH/MSHA. FOR COMPLETE LIST OF RESPIRATORS
CONTACT NEHC .
Ventilation:PROVIDE GENERAL DILUTION VENTILATION TO MEET PELS.
VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:IMPERVIOUS CLTHG & EQUIP TO PVNT RPTD/PRLNG
SKIN CONT W/SUBSTANCE. EYE WASH FOUNTAIN W/IN THE IMMEDIATE WORK
AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM
ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE
HOLDER/MONITOR NOZZ; IF IMPOSS, W/DRAW FROM AREA & LET FIRE BURN .
W/DRAW IMMED IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE/ANY
DISCOLORATION. ISOLATE FOR 1/2 MILE IF (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:180F,82C
Melt/Freeze Pt:M.P/F.P Text:-129F,-89C
Vapor Pres:40 @ 23.8C
Vapor Density:2.1
Spec Gravity:0.785
Evaporation Rate & Reference:2.88 (BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT, COLORLESS, MOBILE LIQ W/CHARACT MILD
ALCOHOLIC ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, COATINGS, HALOGENS, KETONES, OXIDIZERS. FOR COMPLETE LISTING OF
MATLS TO AVOID CONTACT NEHC .
Stability Condition to Avoid:MAY SLOWLY PEROXIDISE ON EXPOS TO AIR.
EXPLO HAZ IF DISTILLED/ALLOWED TO EVAPORATE TO DRYNESS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W STANDARDS APPLICABLE TO
GENERATIONS OF HAZ WASTE, 40 CFR 262, EPA HAZ WASTE #D001. OBSERVE
ALL FED, STATE & LOC REGS WHEN DISP OF SUBSTANCE. FOR ASSISTANCE,
CONT DISTRICT DIRECT OR OF EPA.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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