===================== Product Identification =====================
MSDS NAME:UNLEADED GASOLINE N/O*
NIIN:00-148-7112
MSDS Number: BPKSN
=== Responsible Party ===
Company:U S OIL CO INC
Address:425 S WASHINGTON AVE
City:COMBINED LOCKS
State:WI
ZIP:54113-1049
Country:US
Info Phone Num:414-739-6100
Emergency Phone Num:414-739-6100
CAGE:46845
=== Contractor Identification ===
Company:U S OIL CO INC
Address:5 LAKE FANNY RD
Box:111
City:BEL AIR
State:MD
ZIP:21014
Country:US
Phone:301-879-7352
CAGE:46845
Company:U S OIL CO INC
Address:558 CARTER CT
Box:City:KIMBERLY
State:WI
ZIP:54136
Country:US
Phone:920-735-8287
CAGE:9V710
============= Composition/Information on Ingredients =============
Name:HYDROCARBONS
Fraction by Wt: >50%
Other REC Limits:NONE RECOMMENDED
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: .1-4.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CUMENE (SARA III)
CAS:98-82-8
RTECS #:GR8575000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:1,2,4-TRIMETHYLBENZENE (SARA III)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9293
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 12%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:THE PRODUCT CONTAINS PETROLEUM
HYDROCARBON, & AS WITH MANY PETROLEUM PRODUCTS, IT MAY CAUSE
IRRITATION TO THE EYES, SKIN & LUNGS AFTER PROLONGED OR REPEATED
EXPOSURE. A FEW STUDIES HAVE INDICATED THAT WORKERS EXPOSED MANY
YEARS TO HIGH CONCENTRATIONS OF BENZENE HAVE A SLIGHTLY HIGHER
INCIDENCE OF LEUKEMIA.
Explanation of Carcinogenicity:BENZENE IS A KNOWN HUMAN CARCINOGEN.
Effects of Overexposure:OVEREXPOSURE MAY CAUSE WEAKNESS, HEADACHE,
NAUSEA, CONFUSION, BLURRED VISION, DROWSINESS AND OTHER NERVOUS
SYSTEM EFFECTS; GREATER EXPOSURE MAY CAUSE DIZZINESS, SLURRED
SPEECH, FLUSHED FACE, UNCONSCIO USNESS OR CONVULSION. BENZENE CAN
ALSO BE TOXIC TO THE BLOOD AND BLOOD-FORMING TISSUES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MIN. CALL A PHYSICIAN. SKIN: IMMEDIATELY WASH SKIN WITH
SOAP AND WATER. IF IRRITATION DEVELOPS, GET MEDICAL HELP.
INHALATION: REMOVE T O FRESH AIR. IF NOT BREATHING, PERFORM CPR. IF
HARD TO BREATH, GIVE OXYGEN. CALL PHYSICIAN. INGESTION: DO NOT
INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-50F,-46C
Autoignition Temp:Autoignition Temp Text:536F
Lower Limits:<1
Upper Limits:8
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM. WATER MAY
BE INEFFECTIVE TO EXTINGUISH, USE WATER TO COOL FIRE EXPOSED
CONTAINER
Fire Fighting Procedures:IF LEAK/SPILL HAS NOT IGNITED, USE WATER SPRAY
TO DISPERSE THE VAPORS & TO PROTECT PERSONNEL ATTEMPTING TO STOP
LEAK. USE WATER SPRAY TO FLUSH SPILL FROM AREA.
Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE. DO NOT ENTER
ENCLOSED/CONFINED SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT
INCLUDING RESPIRATORY PROTECTION. FUMES OF CARBON MONOXIDE &
DIOXIDE.
================== Accidental Release Measures ==================
Spill Release Procedures:THIS MATERIAL IS FLAMMABLE. CONTAIN SPILL.
RECOVER AS MUCH OF PRODUCT AS POSSIBLE. NONRECOVERABLE PRODUCT,
CONTAMINATED SOIL, DEBRIS & OTHER MATERIAL SHOULD BE PLACED IN
PROPER CONTAINERS FOR ULTIMATE DISPOSAL. AVOID WMATERIAL ENTERING
SEWERS.
Neutralizing Agent:NA
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN ACCORDANCE WITH NATIONAL FIRE
PROTECTION ASSOCIATION REGULATIONS.
Other Precautions:NOTES TO PHYSICIAN: GASTRIC LAVAGE BY QUALIFIED
MEDICAL PERSONNEL MAY BE CONSIDERED, DEPENDING ON QUANTITY OF
MATERIAL INGESTED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT APPROPIATE NIOSH-APPROVED RESPIRATORY
PROTECTION WHERE NECESSARY TO MAINTAIN EXPOSURE BELOW THE
APPLICABLE LIMITS.
Ventilation:USE SUFFICIENT VENTILATION TO MAINTAIN ATMOSPHERIC
CONCENTRATIONS BELOW PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:NBR OR NEOPRENE GLOVES
Eye Protection:GOGGLES OR FACE SHIELD
Other Protective Equipment:SUFFICIENT PROTECTIVE CLOTHING TO MINIMIZE
SKIN EXPOSURE. L
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
AVOID CONTACT WITH EYES, SKIN, OR CLOTHING.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:85.0F,29.4C
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NA
Vapor Pres:275-475
Vapor Density:>1 AIR=1
Spec Gravity:0.70-.77
pH:NA
Viscosity:NA
Evaporation Rate & Reference:NA
Solubility in Water:MAY BE SLIGHTLY SOL.
Appearance and Odor:WATER WHITE TO STRAW YELLOE LIQUID; GASOLINE ODOR.
Percent Volatiles by Volume:100%
Corrosion Rate:NA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:UNDUE EXPOSURE TO AIR, HEAT, FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE MAY BE FORMED FROM
INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE AS MUCH OF THE RECOVERABLE PRODUCT AS
POSSIBLE. TREATMENT, STORAGE, TRAANSPORTATION & DISPOSAL MUST BE IN
ACCORDANCE WITH APPLICABLE FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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