============= Composition/Information on Ingredients =============
Name:TRICLOPYR (3,5,6-TRICHLORO-2-PYRIDINYLOXYACETIC ACID), AS
THE TRIETHYLAMINE SALT
CAS:57213-69-1
RTECS #:AJ8974000
Fraction by Wt: 44.4%
Other REC Limits:DOW;4MG/M3 SKIN
RTECS #:9999999ZZ
Fraction by Wt: 55.6%
Other REC Limits:NONE SPECIFIED
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Other REC Limits:NONE SPECIFIED
Name:PROPRIETARY EMULSIFIERS
Other REC Limits:NONE SPECIFIED
LD50 LC50 Mixture:LD50 DERMAL: >3980 MG/KG RABBIT. *
Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYE: SEVERE IRRITATION W/CORNEAL
INJURY (PERMANENT VISION IMPAIRMENT, BLINDNESS). SKIN:
PROLONGED/REPEATED: IRRITATION, BURN. INGESTION: AMTS INGESTED
INCIDENTAL TO INDUSTRIAL HANDLING NOT LIKELY TO C AUSE INJURY;
INGESTION OF LARGER AMTS MAY CAUSE INJURY. GASTROINTESTINAL
IRRITATION OR ULCERATION.
Explanation of Carcinogenicity:AVAIL DATA ON ETHANOL INADEQUATE TO
EVALUATE CARCINOGENICITY. ACTIVE INGRED DIDN'T CAUSE CANCER (LONG
TERM ANIMAL STUDY)
Effects of Overexposure:SYSTEMIC (OTHER TARGET ORGAN) EFFECTS:
EXCESSIVE EXPOSURE MAY CAUSE LIVER OR KIDNEY EFFECTS. ETHANOL, A
MINOR COMPONENT, HAS CAUSED CNS AND LIVER EFFECTS.* ORAL LD50: 2574
MG/KG MALE RATS, 1847 MG/KG FEMALE RATS.
======================= First Aid Measures =======================
Eyes: IRRIGATE W/FLOWING WATER IMMED 15 MIN. SEEK MEDICAL
PERSONNEL. SKIN: WASH OFF IN FLOWING WATER OR SHOWER. INGESTION:
DONT INDUCE VOMITING. GIVE LARGE AMOUNTS OF WATER OR MILK IF
AVAILABLE & TRAN SPORT TO MEDICAL FACILITY. NOTE TO DR: IF BURN,
TREAT AS THERMAL BURN, AFTER DECONTAM. NO SPECIFIC ANTIDOTE.
SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF DR IN RESPONSE TO
REACTIONS OF THE PATIENT.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:110F,43C
Extinguishing Media:ALCOHOL FOAM, AND CO2
Fire Fighting Procedures:USE POSITIVE PRESSURE SELF-CONTAINED BREATHING
EQUIPMENT.
Unusual Fire/Explosion Hazard:IRRITATING VAPORS UNDER FIRE CONDITIONS.
Spill Release Procedures:DIKE LARGE SPILLS. KEEP OUT OF STREAMS &
DOMESTIC WATER SUPPLIES. ABSORB SMALL SPILLS IN INERT MATERIAL SUCH
AS SAND.
====================== Handling and Storage ======================
Handling and Storage Precautions:SEE LABEL. AVOID BREATHING SPRAY MIST.
DONT SWALLOW. AVOID SKIN CONTACT. PREVENT EYE CONTACT. WASH
THOROUGHLY AFTER HANDLING. KEEP AWAY FROM CHILDREN.
Other Precautions:DO NOT CONTAMINATED DOMESTIC WATER SUPPLIES OR WATER
USED FOR IRRIGATION.
Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW
THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR
HANDLING CONCENTRATE UNDER CERTAIN OPERATIONS, USE A NIOSH APPROVED
AIR-PURIFYING RESP IRATOR.
Ventilation:CONTROL AIRBORNE CONC BELOW EXPOSURE GUIDLINE. GOOD GENERAL
VENT SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST IF NEEDED
Protective Gloves:IMPERVIOUS GLOVES FOR PROLONGED/FREQUENT
Eye Protection:CHEMICAL GOGGLES IF HANDLING CONCENTRATE
Other Protective Equipment:FOR BRIEF CONTACT, CLEAN BODY-COVERING
CLOTHING. EYE WASH FOUNTAINS SHOULD BE LOCATED IN IMMEDIATE WORK
AREA.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
Supplemental Safety and Health
HCC:T5
Spec Gravity:1.135 (68/68F)
Solubility in Water:HIGH
Appearance and Odor:AMBER LIQUID
================= Stability and Reactivity Data =================
ANY OXIDIZING AGENT. CONSULT MANUFACTURER FOR SPECIFIC CASES.
Stability Condition to Avoid:COMBUSTIBLE. AVOID SOURCES OF IGNITION IF
TEMPERATURES IS NEAR OR ABOVE FLASH POINT.
Hazardous Decomposition Products:IRRITATING VAPORS UNDER FIRE
CONDITIONS.
Waste Disposal Methods:IN CASE OF LARGE SPILLS, CONTACT THE DOW
CHEMICAL COMPANY. BURY CLEAN-UP MATERIAL FROM SMALL SPILLS IN
NON-CROP AREA AWAY FROM WATER SUPPLIES, IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.