===================== Product Identification =====================
MSDS NAME:CF12V30 CAREFREE RECHAGEABLE BATTERY
NIIN:01-060-1983
MSDS Number: BQFCS
=== Responsible Party ===
Company:EAGLE-PICHER INDUSTRIES INC ELECTRONICS DIV
Address:C AND PORTER STS
Box:130
City:JOPLIN
State:MO
ZIP:64801
Country:US
Info Phone Num:417-623-8000
Emergency Phone Num:417-623-8000
CAGE:0B3X4
=== Contractor Identification ===
Company:EAGLE-PICHER INDUSTRIES INC
Address:14212 BETHEL ROAD
Box:130
City:SENECA
State:MO
ZIP:64865
Country:US
Phone:417-776-2256
CAGE:0B3X4
Company:EAGLE-PICHER INDUSTRIES, INC.
Address:C AND PORTER STS
Box:47
City:JOPLIN
State:MO
ZIP:64801
Country:US
Phone:417-623-8000
CAGE:81855
============= Composition/Information on Ingredients =============
Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 50%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:LEAD OXIDE (LITHARGE)
CAS:1317-36-8
RTECS #:OG1750000
Fraction by Wt: 25%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.05 MG/M3 (PB)
ACGIH TLV:0.15 MG/M3 (PB)
Name:SULFURIC ACID (SARA III) (38% SOLUTION)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 18%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION OF SULFUR DIOXIDE
FUMES GENERATED FROM OVERCHARGING MAY BE HARMFUL. CONTACT OF SKIN
AND EYES WITH ELECTROLYTE MAY CAUSE BURNS. CHRONIC: LEAD CONTAINED
IN ELECTRODES IS KNOWN TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
Explanation of Carcinogenicity:LEAD IS LISTED BY NTP AS AN ANTICIPATED
CARCINOGEN; IARC LISTS LEAD AS A 2B, PROBABLE CARCINOGEN.
Effects of Overexposure:INHALED: COUGHING, SHORTNESS, TIGHTNESS IN
CHEST, CHEST PAIN. EYES: BURNING SENSATION, BURNS, PAIN, REDNESS,
TEARING, BLURRED VISION. SKIN: REDNESS, BURNS, SWELLING, BLISTERS,
PAIN, FELLING OF HEAT. I NGESTED(ELECTROLYTE): BURNS AROUND MOUTH,
IN THROAT AND ESOPHAGUS, SEVERE STOMACH PAIN, NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALED: MOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF
BREATHING STOPPED. GET MEDICAL ATTENTION. EYES: FLUSH WITH LOTS OF
WATER FOR 15 MINTES, HOLD LIDS OPEN. SEE DOCTOR. SKIN: REMOVE
CONTAMINATED CLOTHES. FLUSH WITH WATER UNTIL RESIDUE GONE. SEE
DOCTOR FOR IF BURNED. INGESTED: IF CONSCIOUS, GIVE WATER OR MILK,
FOLLOWED BY MILK OF MAGNESIA OR EGG WHITES. DO NOT INDUCE VOMITING!
SEE DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:EXPLOSION CAN RESULT FROM IMPROPER
CHARGING AND IGNITION OG CHARGING GASES. EXPLOSION CAN RESULT IF
CHARGED IN GAS TIGHT ENCLOSURES.
================== Accidental Release Measures ==================
Spill Release Procedures:NEUTRALIZE ACID IF BATTERY BROKEN OPEN. SCOOP
UP NEUTRALIZED MATERIAL AND PLACE IN A CONTAINER FOR LATER
DISPOSAL. FLUSH AREA WITH WATER. WEAR PROPER CLOTHING AND
EQUIPMENT.
Neutralizing Agent:BAKING SODA SOLUTION
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT CRACK BATTERY CASE, DO NOT
OVERCHARGE. DO NOT SHORT CIRCUIT BATTERY TERMINALS.
Other Precautions:KEEP LIGHTED CIGARETTES, SPARKS, AND FLAMES AWAY FROM
CHARGING BATTERIES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:USE NATURAL CONVECTION
Protective Gloves:RUBBER IF CASE DAMAGED
Eye Protection:SAFETY GLASSES
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. HMIS:EYE
WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
MANUFACTURER STATES ITEM AN ARTICLE UNDER 29 CFR 1900.1200.
================== Physical/Chemical Properties ==================
HCC:C1
Appearance and Odor:PLASTIC CASED, SEALED 12 VOLT BATTERY; 6.7 IN. X
6.7 IN. X 6.2 IN.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SOLVENT MAY DISSOLVE BATTERY CASE.
Stability Condition to Avoid:OVERCHARGING, SHORT CIRCUITING OF BATTERY
Hazardous Decomposition Products:SEVERE OVERCHARGE AND OVERHEATING MAY
GENERATE SULFUR DIOXIDE FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS FOR LEAD-ACID BATTERIES. DO NOT INCINERATE,
PUNCTURE, DISASSEMBLE, OR MUTILATE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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