===================== Product Identification =====================
MSDS NAME:SHELL JP-4
NIIN:01-250-6353
MSDS Number: BQQPV
=== Responsible Party ===
Company:SHELL OIL CO
Address:1 SHELL PLZ
Box:2463
City:HOUSTON
State:TX
ZIP:77001
Country:US
Info Phone Num:713-241-4201
Emergency Phone Num:713-473-9461,800-424-9300(CHEMTREC)
Preparer's Name:J. C. WILLETT
CAGE:SHELO
=== Contractor Identification ===
Company:SHELL OIL CO
Box:4320
City:HOUSTON
State:TX
ZIP:77210-5000
Country:US
Phone:713-473-9461/713-241-2252
CAGE:SHELO
Company:SHELL OIL COMPANY
Address:Box:2463
City:HOUSTON
State:TX
ZIP:77210
Country:US
Phone:800-231-6950
CAGE:54527
============= Composition/Information on Ingredients =============
Name:HYDROTREATED NAPHTHA, HEAVY
CAS:64742-48-9
Fraction by Wt: 88-95%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM (MFG,1988)
ACGIH TLV:300 PPM (MFG,1988)
Name:NAPHTHA, LIGHT
CAS:64742-46-4
Fraction by Wt: 5-12%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM (MFG 1988)
ACGIH TLV:300 PPM (MFG 1988)
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <2.5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:MINOR ADDITIVES
Fraction by Wt: <0.5%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES: MILDLY IRRITATING. SKIN:
PROLONGED AND REPEATED LIQUID CONTACT CAN CAUSE DEFATTING AND
DRYING RESULTING IN SKIN IRRITATION AND DERMATITIS.INHALATION: MAY
CAUSE IRRITATION OF NOSE, THROAT, RESPIR ATORY TRACT AND CNS
DEPRESSION. MAY PRODUCE LIVER AND KIDNEY DAMAGE. INGESTION: MAY BE
HARMFUL OR FATAL IF SWALLOWED.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:IRRITATION AS NOTED ABOVE. EARLY TO MODERATE
CNS DEPRESSION SIGNS MAY BE HEADACHE, DIZZINESS, GIDDINESS, AND
NAUSEA; IN EXTREME CASES, UNCONSCIOUSNESS & DEATH. KIDNEY DAMAGE
NOTED BY CHANGES IN URINE OUTPUT, APPEARANCE OR EDEMA. LIVER
DAMAGE NOTED BY LOSS OF APPETITE, JAUNDICE AND PAIN IN UPPER
ABDOMEN ON RIGHT SIDE.
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE. ALSO IMPAIRED
LIVER AND KIDNEY FUNCTIONS FROM PREEXISTING DISORDERS MAY BE
AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
Eyes: FLUSH WITH WATER FOR 15 MIN WHILE HOLDING EYELIDS OPEN.
GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH
AREA WITH SOAP AND WATER. IF IRRITATION PERSISTS GET MEDICAL
ATTENTION. IN HALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE
CPR. IF BREATHING DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATENTION.
===================== Fire Fighting Measures =====================
Flash Point:-10F TO 30F
Lower Limits:1.3
Upper Limits:8.0
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON
DIOXIDE. DO NOT USE DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND
REIGNITE.
Fire Fighting Procedures:EXTREMELY FLAMMABLE. CLEAR FIRE AREA &
ISOLATE. DO NOT ENTER SPACE WITHOUT FULL BUNKER GEAR & INCULDING
SCBA. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR, ACCUMULATE
IN LOW AREAS AND TRAVEL ALONG GROUND TO DISTANT SOURCES OF IGNITION
AND FLASHBACK.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. GROUND HANDLING
EQUIPMENT TO PREVENT SPARKING. DIKE TO CONTAIN SPILL. PUMP TO
SALVAGE CONTAINER. SOAK UP RESIDUE WITH AN ABSORBENT. PLACE IN
CONTAINER FOR DISPOSAL. FLUSH A REA WITH WATER. CONTAIN FLUSH WATER
FORDISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DANGER. EXTREMELY FLAMMABLE. AVOID
HEAT, SPARKS, OPEN FLAMES, INCLUDING PILOT LIGHTS & STRONG
OXIDIZING AGENTS. DO NOT SIPHON GASOLINE BY MOUTH.
Other Precautions:ALL HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT
SPARKING.DO NOT SIPHON GASOLINE BY MOUTH. FOR USE AS FUEL ONLY. DO
NOT USE AS A CLEANING SOLVENT OR OTHER NON-MOTOR FUEL USES.
REMEMBER EXPLOSION AND FIRE IS THE MOST IMMEDIATE DANGER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS USE A NIOSH-APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER A
FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRA TOR OR AIR-PURIFYING
RESPIRATOR.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:WEAR CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL GOGGLES IF CHANCE OF CONTACT.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING (VITON). EYE WASH
STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH WITH SOAP & WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNDER NORMAL WORKING CONDITIONS, A RESPIRATOR IS NOT WARRANTED. IF A
MAJOR SPILL OCCURS, GET UPWIND AND NOTIFY LOCAL EMERGENCY
PERSONNEL.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:>100F,>38C
Melt/Freeze Pt:M.P/F.P Text:-72F,-58C
Vapor Pres:14-21 PSIA
Vapor Density:3.5(AIR=1)
Spec Gravity:0.7796
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER COLOR, CLEAR AND BRIGHT LIQUID.
HYDROCARBON ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES. PREVENT
VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS CAN BE FORMED UPON COMBUSTION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. KEEP PRODUCT OUT OF SURFACE WATERS AND ANY WATER
COURSES OR SEWERS ENTERING OR LEADI NG TO SURFACE WATERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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