===================== Product Identification =====================
MSDS NAME:V015 SODIUM AZIDE
NIIN:00F027579
MSDS Number: BQZTF
=== Responsible Party ===
Company:J T BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865-2219
Country:US
Info Phone Num:201-859-2151
Emergency Phone Num:201-859-2151
CAGE:DO803
=== Contractor Identification ===
Company:J T BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:1-800-582-2537
CAGE:DO803
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:SODIUM AZIDE, AZIDE
CAS:26628-22-8
RTECS #:VY8050000
Fraction by Wt: 90-100%
Other REC Limits:0.1 PPM
OSHA PEL:0.1 PPM
ACGIH TLV:C 0.29 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (MOUSE): 27 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. INHALATION: UPPER
RESPIRATORY TRACT IRRITATION W/HEADACHE, NAUSEA, DIZZINESS,
FATIGUE, CYANOSIS, WEAKNESS IN ARMS & LEGS. SKIN: ABSORPTION &
IRRITATION. INGESTION: NAUSEA, VOMITING, HEADACHE, DIZZINESS,
GASTROINTESTINAL IRRITATION, BLURRED VISION, LOWERING OF BLOOD
PRESSURE. POISON
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION/INHALATION: HARMFUL & MAY BE FATAL.
POISON
======================= First Aid Measures =======================
First Aid:INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER. INDUCE
VOMITING. INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE
ARITIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
EYES/SKIN: FL USH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL OR CO2. DON'T USE WATER.
Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT &
SELF-CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN
POSITIVE PRESSURE MODE. MOVE EXPOSED CONTAINERS FROM AREA.
Unusual Fire/Explosion Hazard:CAN REACT VIOLENTLY W/SHOCK, FRICTION OR
HEAT. DECOMPOSES AT MELTING POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES OR
SMOKING IN AREA. SHOVEL INTO CLEAN, DRY CONTAINER & COVER. FLUSH
SPILL AREA W/WATER. DON'T A LLOW TO ENTER DRAINS OR SEWER SYSTEM.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN COOL, DRY WELL-VENTILATED AREA AWAY FROM IGNITION SOURCES. DON'T
STORE NEAR ACIDS OR IN METAL CONTAINERS.
Other Precautions:WHEN USING SODIUM AZIDE IN ORGANIC SYNTHESIS
REACTIONS, PRODUCTION OF SIGNIFICANT AMOUNTS OF HYDRAZOIC ACID IS
POSSIBLE. HYDRAZOIC ACID IS A HIGH EXPLOSION RISK. DON'T GET IN
EYES, ON SKIN OR CLOTHING . DON'T BREATH DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS WHEN TLV
IS EXCEEDED
Ventilation:GENERAL OR LOCAL EXHAUST TO MEET TLV REQUIREMENTS
Protective Gloves:RUBBER
Eye Protection:SAFETY GOGGLES & FACE SHIELD
Other Protective Equipment:UNIFORM OR PROTECTIVE SUIT
Supplemental Safety and Health
INCOMPATIBLES (CONT'D): BARIUM CARBONATE, BROMINE, DIMETHYL SULFATE.
PRODUCT DECOMPOSES AT MELTING POINT.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:275C/527F
Decomp Temp:Decomp Text:275C/527F
Vapor Density:2.2
Spec Gravity:1.84
Solubility in Water:APPRECIABLE
Appearance and Odor:COLORLESS HEXAGONAL CRYSTALS, ODORLESS
Percent Volatiles by Volume:0%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, MINERAL ACIDS, HALOGEN ACIDS, HALOGEN
COMPOUNDS, COMMON METALS, CARBON DISULFIDE (SEE SUPP)
Stability Condition to Avoid:HEAT, FLAME, MOISTURE, SHOCK, FRICTION, &
OTHER IGNITION SOURCES
Hazardous Decomposition Products:AMMONIA, NITROGEN OXIDES, HYDRAZOIC
ACID FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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