===================== Product Identification =====================
MSDS NAME:NORKOOL CONCENTRATE SLH 224C
NIIN:00F028334
MSDS Number: BRBVT
=== Responsible Party ===
Company:UNION CARBIDE CHEM & PLASTICS CO INC
Address:39 OLD RIDGEBURY RD
City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Info Phone Num:800-822-4357
Emergency Phone Num:203-794-6753
CAGE:0TAZ2
=== Contractor Identification ===
Company:UNION CARBIDE CORPORATION
Address:39 OLD RIDGEBURY RD
Box:City:DANBURY
State:CT
ZIP:06817-0001
Country:US
Phone:1-800-568-4000 / 732-563-5522
CAGE:0TAZ2
============= Composition/Information on Ingredients =============
Name:ETHYLENE GLYCOL, GLYCOL
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 90-95%
Other REC Limits:10 MG/CUM
ACGIH TLV:C 127 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 2-5%
Name:POTASSIUM PHOSPHATE, DIBASIC *93-1*
CAS:7758-11-4
Fraction by Wt: 1-3%
Name:POTASSIUM HYDROXIDE
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 1-2%
Other REC Limits:2 MG/CUM (CEILING)
OSHA PEL:2 MG/CUM (CEILING)
ACGIH TLV:2 MG/CUM (CEILING)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGESTION: ABDOMINAL DISCOMFORT/PAIN,
NAUSEA, VOMITING, DIZZINESS, DROWSINESS, BLURRED VISION, LUMBAR
PAIN, CNS EFFECTS & WEAKNESS OF FACIAL MUSCLES. INHALATION: NOSE &
THROAT IRRITATION, HEADACHE, NA USEA, VOMITING, HEADACHE &
DIZZINESS. SKIN: IRRITATION, DISCOMFORT & REDNESS. EYES:
IRRITATION, STINGING & REDNESS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION: MALAISE, OLIGURIA, UREMIA, IRREGULAR
EYE MOVEMENTS, CONVULSIONS, COMA, CARDIAC FAILURE & PULMONARY
EDEMA, KIDNEY DAMAGE & MAY BE FATAL. INHALATION: CENTRAL NERVOUS
SYSTEM EFFECTS, DIZZINESS , & NYSTAGMUS. SKIN: SWELLING,
SENSITIZATION W/DEVELOPMENT OF ALLERGIC CONTACT DERMATITIS. EYES:
EXCESS BLINKING.
Medical Cond Aggravated by Exposure:KIDNEY DISEASE
======================= First Aid Measures =======================
First Aid:INGESTION: IF CONSCIOUS, GIVE 2 GLASSES OF WATER & INDUCE
VOMITING. GIVE MODERATE VOLUMES OF ETHYLENE GLYCOL, THEN GIVE 3-4
OUNCES OF HARD LIQUID SUCH AS WHISKEY. SKIN/EYES: FLUSH W/WATER FOR
SEVERAL MINS. INHALATION: REMOVE TO FRESH AIR. NOTE TO PHYSICIAN:
ETHANOL IS ANTIDOTAL, ITS EARLY ADMINISTRATION MAY BLOCK FORMATION
OF NEPHROTOXIC METABOLITES OF ETHYLENE GLYCOL IN THE LIVER. (SEE
SUPP.)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:260F, 126.7C
Lower Limits:3.2%
Upper Limits:15.3%
Extinguishing Media:ALCOHOL-TYPE, ALL PURPOSE-TYPE FOAMS, WATER SPRAY,
CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DURING A FIRE, AMMONIA &
NITROGEN-CONTAINING COMPOUNDS MAY BE PRODUCED.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. FLUSH W/PLENTY OF
WATER. COLLECT FOR DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. USE W/ADEQUATE
VENTILATION. FOR INDUSTRY USE ONLY. DON'T SWALLOW. AVOID CONTACT
W/EYES, SKIN & CLOTHING. AVOID BREATHING VAPOR.
Other Precautions:SUDDEN RELEASE OF HOT ORGANIC CHEMICAL VAPORS OR
MISTS FROM PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURE &
PRESSURE OR SUDDEN INGRESS OF AIR INTO VACUUM EQUIPMENT, MAY RESULT
IN IGNITIONS WITHO UT PRESENCE OF OBVIOUS IGNITION SOURCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR W/ORGANIC
VAPOR CARTRIDGE & DUST/MIST PRE-FILTER WHEN EXPOSURE LIMITS ARE
EXCEEDED
Ventilation:GENERAL (MECHANICAL) ROOM: ADEQUATE. LOCAL EXHAUST IS
NEEDED AT POINTS WHERE VAPOR IS IN WORKPLACE
Protective Gloves:NATURAL RUBBER, NITRILE, NEOPRENE, PVC
Eye Protection:MONOGOGGLES OR FACESHIELD
Other Protective Equipment:EYE BATH OR SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN (CONT'D): ETHANOL SHOULD BE GIVEN INTRAVENOUSLY, AS A
5% SOLUTION IN SODIUM BICARBONATE, AT A RATE OF ABOUT 10ML ETHANOL
PER HOUR. A DESIRED THERAPEUTIC LEVEL OF ETHANOL IN BLOOD IS
100MG/DL. HEMODIALYSIS MAY BE REQUIRED.4-METHYLPYRAZOLE, A POTENT
INHIBITOR OF ALCOHOL DEHYDROGENASE HAS BEEN USED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:178C, 353F
Melt/Freeze Pt:M.P/F.P Text:<-59C, -75F
Vapor Pres:0.014
Vapor Density:2.22
Spec Gravity:1.13164
Evaporation Rate & Reference:(BU AC = 1): 0
Solubility in Water:COMPLETE
Appearance and Odor:TRANSPARENT GREENISH-BLUE LIQUID W/MILD ODOR
Percent Volatiles by Volume:95/WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & BASES AT ELEVATED TEMPERATURES, STRONG OXIDIZING AGENTS
& MATERIAL REACTIVE W/HYDROXYL COMPOUNDS
Hazardous Decomposition Products:CO, CO2, AMMONIA, &
NITROGEN-CONTAINING COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN FURNACE WHERE PERMITTED UNDER
FEDERAL, STATE, & LOCAL REGULATIONS. AT VERY LOW CONCENTRATION IN
WATER, ETHYLENE GLYCOL IS READILY BIODEGRADABLE IN BIOLOGICAL
WASTEWATER TREATMENT PLANT.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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