first aid proc:lids, until no evidence of chem remains ing 14:discovered w/in 2 hrs, give syrup of ipecac. lavage ing 15:(20 g/l) added. get med attn immed. lavage should be ing 16:whether severity of poisoning req admin of antidote ing 17:pers. methanol poisoning:give ethanol, 50% (100 ing 18:soln, followed by 0.5-1 ml/kg every 2 hrs ing 19:& to allow time for its excretion. blood ethanol ing 20:admin of 4-methylpyrazole inhibits alcohol ing 21:methanol or ethylene glycol poisoning. resorcinol (sara iii) naphthalene (sara iii) anthracene (sara iii) methanol; (methyl alcohol) (sara iii) supdat:conj redness in rabbits' eyes. drop of methanol in ing 5:rptd/prlng expos may cause visual impairment, poss ing 6:375ppm caused recurrent hdch. 4 yr expos to ing 7:liver. fetal developmental abnorm & efts on ing 8:by pregnant rats. skin:rptd/prlng cntct w/liq may ing 9:derm. chronic absorption may rslt in visual ing 10:rptd/prlng cntct may cause conj. visual impairment ing 11:absorption. ingest:may cause visual impairment & ing 12:efts on newborn reported after prlng expos to methyl
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:NEUROTOXIN; CNS DEPRESS.
ACUTE:INHAL/INGEST:INTOXICATION MAY RSLT IN INEBRIATION.
BLURRED/DIMMED VISION, DILATED, UNRESPONSIVE PUPILS, EYE PAIN,
CONCENTRIC CONSTRICTION OF VISUAL FIELDS, PHOTOPHOBIA & OPTIC
NERVE ATROPHY, FOLLOWED BY TRANSIENT/PERM BLINDNESS MAY OCCUR.
ACIDOSIS MAY RSLT IN RAPID & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SHALLOW RESP, CYANOSIS, COMA &
HYPOTENSION. MILD TACHY, CARD DEPRESS & PERIPHERAL NEURITIS POSS AS
WELL AS LIVER & KIDNEY DMG & CEREBRAL & PULM EDEMA. DEATH POSS FROM
RESP FAILURE/CIRCULATORY COLLAPSE. IRREVERSIBLE CNS EFTS INCL
MOTOR DYSFUNC W/RIGIDITY, SPASTICITY & HYPOKINESIS HAVE BEEN
REPORTED. (SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC RESPIRATORY,
LIVER, KIDNEY, EY OR SKIN DISEASES ARE AT INCREASED RISK FROM
EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, PERFORM
ARTF RESP. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY &
SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE CONTAMD CLTHG & SHOES
IMMED. WASH AFFEC TED AREA W/SOAP/MILD DETERGENT & LG AMTS WATER
UNTIL NO EVID OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN
IMMED. EYES:WASH IMMED W/LG AMTS WATER/NORM SALINE, OCCAS LIFTING
UPPER & LOWER (ING 14)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:52.0F,11.1C
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR
STANDARD FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
Spill Release Procedures:SHUT OFF IGNITION SOURCES. STOP LEAK IF YOU
CAN DO IT WITHOUT RISK. TAKE UP WITH SAND/OTHER ABSORBENT MATERIAL
& PLACE IN OTHER CONTAINERS FOR LATER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM TEMPERATURE EXTREMES &
DIRECT SUNLIGHT. SHOULD BE STORED IN AN ACCEPTABLY PROTECTED &
SECURE FLAMMABLE LIQUID STORAGE ROOM.
Other Precautions:GROUND & BOND METAL CONTAINERS TO MINIMIZE STATIC
SPARKS.
Respiratory Protection:FOR LARGE AMOUNTS USE NIOSH/MSHA APPROVED SELF
CONTAINED BREATHING APPARATUS WITH FULL FACEPLATE OPERATED IN
PRESSURE-DEMAND MODE.
Ventilation:LOCAL & MECHANICAL EXHAUST.
Protective Gloves:GLOVES IMPERVIOUS TO ALCOHOLS.
Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES .
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH FOUNTAINS &
SAFETY SHOWERS SHOULD BE AVAILABLE IN THE VICINITY OF ANY POTENTIAL
EXPO.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:USUAL FATAL DOSE IS 100-250 ML. SKIN:CNTCT W/LIQ MAY
CAUSE IRRIT. MAY BE ABSORBED TO CAUSE SYSTEMIC EFTS INCL CNS
DEPRESS, NARCOS, OPTIC NEURITIS & ACIDOSIS. LETHAL AMTS MAY BE
ABSORBE D THRU INTACT SKIN. EYES:DILUTED SOLNS MAY CAUSE MILD IRRIT
& UNDILUTED LIQ MAY CAUSE MOD CORNEAL OPACITY & (ING 5)
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . EPA HAZARDOUS WASTE NUMBER D001.
DISPOSE OF AS AN EPA HAZARDOUS WASTE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.