hydrofluoric acid; (hydrogen fluoride) (sara iii) phosphoric acid (sara iii) sulfuric acid (sara iii) ethanol, 2-butoxy-; (ethylene glycol monobutyl ether) glycols, polyethylene, mono(nonylphenyl) ether; supdat:relevance of these studies/expos levels which might ing 6:animal studies clearly demonstrated dose-related ing 7:& liver, assoc w/admin of ethylene glycol monobutyl ing 8:no.90-118) . special note:msds data pertains to prod ing 9:would not be expected under rec cndtns of use first aid proc:ingest:do not induce vomit. if victim is spill proc:well w/water. waste disp meth:be disp of in chem/indus waste landfill. if ing 13:owned treatment works, neut of spent tank-solns ing 14:state & fed agencies for proper disposal method in other prot equip:when using this product or when working in hygiene pract:removed promptly & not reworn until eye prot:full length face shield .
Name:SUPDAT:RELEVANCE OF THESE STUDIES/EXPOS LEVELS WHICH MIGHT
PRDCE THESE EFTS IN HUMANS HAS NOT BEEN ESTABLISHED. (ING 7)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CORR TO EYES & SKIN ON CONT. EYE
CONT MAY CAUSE CORNEAL DMG/BLINDNESS. SKIN CONT MAY CAUSE DELAYED
BURNS W/LITTLE NOTICEABLE PAIN, TAKING UP TO 24 HRS TO APPEAR.
IMMED FIRST AID IS NEC IN CASE O F CONT. CONT RSLTS IN IMMED SKIN
ABSORPTION, WHICH MAY CAUSE HYPOCALCEMIA. SEV OVEREXP BY ABSORPTION
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID:IARC MONOGRAPHS ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 41, 1992:GRP 1. ANIMAL:PULM
IRRIT.
Effects of Overexposure:HLTH HAZ:CAN RSLT IN DEATH. INHAL CAN IRRIT
RESP TRACT LEADING TO INFLAMM & CHEM PNEUM. INGEST CAN CAUSE GI
TRACT BURNS & MAY ALSO CAUSE KIDNEY DISFUNC. CAN BE FATAL IF
INHALED/INGESTED. CHRONIC:RPTD/ PRLNG CONT W/ACID VAPS MAY CAUSE
NASAL ULCERATION, BRONCH IRRIT & FREQUENT ATTACKS OF BRONCH
INFECTION. IN (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:IMMED FLUSH CONT AREA W/LG AMT OF WATER FOR AT LST 15
MINS. IMMED GET MED ATTN WHILE IMMERSING/SOAKING SKIN W/13% SOLN OF
ZEPHIRAN CHLORIDE (DO NOT USE AROUND EYES). EYES:IMMED FLUSH
W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS LIFTINGUPPER & LOWER
LIDS. GET MED ATTN AT ONCE. INHAL:MOVE EXPOS PERS TO FRESH AIR AT
ONCE. IF BRTHG HAS STOPPED, PERFORM ARTF RESP. GET MED ATTN IMMED.
(ING 11)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
NON-COMBUSTIBLE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EXTREME HEAT MAY BREAK DOWN ACIDS &
RELEASE TOXIC FUMES.
Spill Release Procedures:OBSERVE SAFETY PRECS IN SPECIAL PROT INFO &
SPECIAL PRECS SECTIONS DURING CLEAN-UP. ABSORB SPILL ON INERT
ABSORB MATL (EG ZEP-O-ZORB); PICK UP & PLACE IN CLEAN DOT
SPECIFICATION CNTNR FOR DISP. WASH A REA THORO W/DETERGENT SOLN &
THEN RINSE(ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE TIGHTLY CLOSED CONTAINER IN DRY
AREA AT TEMPERATURES BETWEEN 40-120F. STORE AWAY FROM HIGHLY
ALKALINE PRODUCTS & OXIDIZING COMPOUNDS.
Other Precautions:KEEP PRODUCT AWAY FROM SKIN & EYES. DO NOT BREATHE
SPRAY MISTS OR VAPORS. KEEP OUT OF THE REACH OF CHILDREN.
Respiratory Protection:WHEN EXPOSURE LEVELS EXCEED PEL/TLV, USE
NIOSH/MSHA APPROVED ZEP MODEL 2245 RESPIRATOR (OR EQUIVALENT) AS
DIRECTED BY MFR.
Ventilation:PROVIDE LOCAL EXHAUST/VENTILATION AS NEEDED TO KEEP
CONCENTRATION OF VAPORS BELOW EXPOSURE LIMITS (PEL/TLV).
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORK GOGGS & (ING 18)
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER WHICH
MEET ANSI DESIGN CRITERIA . WEAR RUBBER RAINSUIT & RUBBER BOOTS
(ING 16)
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN HNDLG
THIS MATL. CLTHG/SHOES WHICH BECOME CONTAM W/SUBSTANCE SHOULD BE
(ING 17)
Supplemental Safety and Health
PH:<1 (CONC); 1-2 (USE DILUTION OF 1%). EFTS OF OVEREXP:EXTREME CASES,
TEETH EROSION COULD RSLT. RPTD/PRLNG EXPOS TO VAPS MAY CAUSE
CHRONIC EYE IRRIT/FREQUENT EYE INFECTIONS. PRLNG/RPTD EXPOS CAN
RSLT IN HYPOCALCEMIA & BONE/JOINT DESTRUCT.ANIMAL STUDIES INDICATE
POTNTL FOR LIVER, KIDNEY/RED BLOOD CELL DMG. (ING 6)
Waste Disposal Methods:LIQS CANNOT BE SENT TO LANDFILLS UNLESS
SOLIDIFIED. UNUSABLE PROD & SOME COLLECTED, SPENT USE-DILUTIONS MAY
REQ DISP AS HAZ WASTE AT PERMITTED TREATMENT/STOR/DISP FACILITY. IN
MOST STATES HAZ WASTES I N TOTAL AMTS OF 220 LBS/LESS PER MONTH
MAY(ING 13)
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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.