===================== Product Identification =====================
MSDS NAME:MURIATIC ACID
NIIN:01-046-9843
MSDS Number: BWGLC
=== Responsible Party ===
Company:OCCIDENTAL CHEMICAL CORP
Address:345 3RD ST
Box:728
City:NIAGARA FALLS
State:NY
ZIP:14302
Country:US
Info Phone Num:716-278-7000
Emergency Phone Num:716-286-3000
CAGE:91784
=== Contractor Identification ===
Company:OCCIDENTAL CHEMICAL CORP (OXYCHEM)SHORT ABBREVIAT
Address:360 RAINBOW BLDVD SOUTH
Box:728
City:NIAGARA FALLS
State:NY
ZIP:14302
Country:US
Phone:1-800-733-3665
CAGE:91784
============= Composition/Information on Ingredients =============
Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID); (HCL:20BE) (SARA
III)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 31.4%
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID); (HCL:22BE) (SARA
III)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 35.2%
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER %:64.8-68.6
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: >64.8%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT:PROMPT MED ATTN. WASH CLTHG BEFORE REUSE. INGEST:IF
CONSCIOUS IMMED ADMIN LG QTYS OF WATER. DO NOT INDUCE (ING 5)
RTECS #:9999999ZZ
Name:ING 4:VOMIT. AVOID HAVING AN UNCON PERSON VOMIT. GET IMMED
MED ATTN. INHAL:MOVE EXPOS PERSON TO FRESH AIR AT (ING 6)
RTECS #:9999999ZZ
Name:ING 5:ONCE. IF BRTHG HAS STOPPED PERFORM ARTF RESP. KEEP
AFFECTED PERSON WARM & AT REST. GET MED ATTN AS SOON AS POSS.
RTECS #:9999999ZZ
Name:OTHER PREC:AS WELL AS CIVIL PENALTIES & FINES TO BE LEVIED.
SPILLS OF MURIATIC ACID OF 5000/MORE POUNDS MUST BE (ING 8)
RTECS #:9999999ZZ
Name:ING 7:REPORTED TO NATIONAL RESPONSE CENTER, 1-800-424-8802.
MURIATIC ACID IS DESIGNATED A HAZ SUBSTENCE BY 29 (ING 9)
RTECS #:9999999ZZ
Name:ING 8:CFR 1910 SUBPART Z. TOX & HAZ SUBSTANCES, OSHA; &
ACGIH. MURIATIC ACID IS A GEN RECOGNIZED AS SAFE (GRAS) (ING 10)
RTECS #:9999999ZZ
Name:ING 9:SUBSTANCE & AS SUCH CERTIFIED FOOD GRADE MATL CAN BE
USED AS A FOOD ADDITIVE AS EXEMPTED BY THE FOOD, (ING 11)
RTECS #:9999999ZZ
Name:ING 12:DRUG & COSMETIC ACT 21 CFR 582.
RTECS #:9999999ZZ
Name:PROT GLOVES:NEOPRENE TO MINIMIZE SKIN CONTACT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL,RAT):900 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HYDROCHLORIC ACID WILL PRDCE IRRIT &
BURNS OF SKIN & MUCOUS MEMBRANES, SEVERITY BEING DETERM BY CONC OF
SOLN & DURATION OF EXPOS. CONT W/EYES MAY CAUSE SEV BURNS. UNLESS
REMOVED QUICKLY BY THORO IRRIG ATION W/WATER, PRLNGD/PERM VISUAL
IMPAIRMENT/LOSS OF SIGHT MAY RESULT. VAPS HAVE AN IRRIT EFT ON RESP
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:TRACT CAUSING COUGHING, BURNING OF
THROAT, CHOKING SENSATION, BRONCHITIS & PULM EDEMA. INGEST OF
CONCENTRATED HYDROCHLORIC ACID CAUSES SEVERE BURNS OF MOUTH,
ESOPHAGUS & STOMACH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/DIRECTED STREAM OF WATER FOR AT LST 15 MIN.
FORCIBLY HOLD EYELIDS APART TO ENSURE COMPLETE IRRIGATION OF ALL
EYE & LID TISS. GET IMMED MED ATTN. CONT LENSES SHOULD NOT BE WORN
WHEN W ORKING W/THIS CHEM. SKIN:IMMED FLUSH CONTAM SKIN W/WATER &
WASH W/SOAP & WATER. IF LG AREAS OF BODY ARE CONTAM/IF CLTHG IS
PENETRATED, IMMED USE SFTY SHOWER PREFERABLY REMOVING CLTHG WHILE
(SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:WATER SPRAY, FOG, FOAM, DRY CHEMICALS, CO*2, OR
OTHER AGENTS AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:REACTS WITH ACTIVE METALS (POTASSIUM,
SODIUM, CALCIUM, POWDERED ALUMINUM, ZINC, MAGNESIUM) TO PRODUCE
FLAMMABLE HYDROGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:GET PROT EQUIP. CNTN SPILL & PUMP INTO MARKED
CNTNRS FOR RECLAMATION/DISP. SM SPILLS:NEUT W/SODA ASH/DILUTE
CAUSTIC SODA SOLN & FLUSH TO SEWER SYS IN ACCORD W/REG PERMIT REQ.
IF POSS, CLEAN UP SPILL A REA ON A DRY BASIS & THEN FLUSH W/PLENTY
OF WATER.
Neutralizing Agent:SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA AWAY FROM HEAT AND OXIDIZING AGENTS. USE EQUIP DESIGNED FOR
ACID SERVICE FOR HANDLING AND STORAGE.
Other Precautions:311 OF CLEAN WATER ACT LISTS MURATIC ACID AS HAZ
SUBSTANCE WHICH, IF DISCHARGED INTO/UPON WATER, MAY REQ IMMED
RESPONSE TO MITIGATE DANGER TO PUBLIC HLTH & WELFARE. ACT SPECIFIES
PROC TO BE FOLLOWED I N EVENT OF ACCIDENTAL SPILLAGE (ING 7)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR ACID-GAS
RESPIRATOR FOR AREAS WHERE AIRBORNE EXPOSURE IS EXCESSIVE.
Ventilation:PROVIDE GOOD GENERAL ROOM VENTILATION TO MINIMIZE EXPOSURE.
USE LOCAL EXHAUST VENTILATION AT POINTS OF VAPOR EMISSION.
Protective Gloves:PROT GLOVES, SUCH AS RUBBER OR (ING 12)
Eye Protection:CHEM SFTY GOGGS & FULL FACE SHLD .
Other Protective Equipment:EYE WASH FACILITY SHOULD BE IN CLOSE
PROXIMITY. USE OF RUB COVERALLS, RUB SHOES & AN EMER SHOWER AVAIL
ARE SUGGESTED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
BP:20BE-80C,176F; 22BE-55C,1314. SPEC GRAV:20BE-1.16(9.67LBS/GAL),
22BE-1.18(9.83LBS/GAL). (H*2O=1). MP:20BE:-53C(-63.4F),
22BE:-66C(-86.3F). MATLS TO AVOID:EXOTHERMICALLY W/ALKALIES &
ACTIVE METALS. FIRST AID PROC:UNDER SHOWER. FLUSH EXPOS AREAS W/LG
AMTS OF WATER FOR AT LST 15 MIN. GET (ING 4)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUPP DATA
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Spec Gravity:SUPP DATA
pH:1.0
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID. PUNGENT
IRRITATING ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONT W/MOST METALS WILL PRDCE FLAMM HYDROGEN. MIX W/STRONG OXIDIZERS
CAN PRDCE POISONOUS CHLORINE GAS. REACTS (SUP DAT)
Stability Condition to Avoid:AVOID CONTACT WITH METALS AND STRONG
OXIDIZERS.
Hazardous Decomposition Products:FLAMM HYDROGEN GAS CAN BE PRDCED BY
THE REACTION W/MOST METALS. CHLORINE GAS WILL BE RELSD BY MIXING
W/STRONG OXIDIZERS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF SPILLED OR WASTE PRODUCT,
CONTAMINATED SOIL AND OTHER CONTAMINATED MATERIALS IN LICENSED
LANDFILL OR TREATMENT FACILITY IN ACCORDANCE WITH ALL LOCAL, STATE
& FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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