| MSDS | : | 47399 EPA PHASE V VOL ORG CMPD MIX 9 | | CAS | : | 120-82-1
79-00-5
67-56-1
75-09-2 | | NAME | : | 1,2,4,-trichlorobenzene
1,1,2-trichloroethane (suspected animal carcinogen by iarc
methanol (methyl alcohol), columbian spirits *94-4*
dichloromethane (methylene chloride) (susp human carc by
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===================== Product Identification =====================
MSDS NAME:47399 EPA PHASE V VOL ORG CMPD MIX 9
NIIN:00F037694
MSDS Number: BWJRK
=== Responsible Party ===
Company:SUPELCO INC
Address:SUPELCO PARK
City:BELLEFONTE
State:PA
ZIP:16823-0048
Country:US
Info Phone Num:814-359-3441
Emergency Phone Num:814-359-3441
CAGE:54968
=== Contractor Identification ===
Company:SIGMA-ALDRICH INC.
Address:3050 SPRUCE STREET
Box:14508
City:ST. LOUIS
State:MO
ZIP:63103
Country:US
Phone:314-771-5765/414-273-3850X5996
CAGE:54968
============= Composition/Information on Ingredients =============
Name:1,2,4,-TRICHLOROBENZENE
CAS:120-82-1
RTECS #:DC2100000
Fraction by Wt: 0.2%
Other REC Limits:5 PPM
OSHA PEL:5 PPM
ACGIH TLV:C 37 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:1,1,2-TRICHLOROETHANE (SUSPECTED ANIMAL CARCINOGEN BY IARC
GROU 3) *94-4*
CAS:79-00-5
RTECS #:KJ3150000
Fraction by Wt: 0.2%
Other REC Limits:10 PPM
OSHA PEL:45 MG/CUM
ACGIH TLV:55 MG/CUM (SKIN)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *94-4*
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 99-100%
Other REC Limits:200 PPM
OSHA PEL:260 MG/CUM
ACGIH TLV:262 MG/CUM (SKIN)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY
ACGIH, SUSP ANIM CARC BY IARC; NTP - IARC GROUP 2B) *94-4*
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 0.2%
OSHA PEL:500 PPM
ACGIH TLV:174 MG/CUM (A2)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 5628 MG/KG METHANOL
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL. MAY CAUSE
RESPIRATORY FAILURE/LOW BLOOD PRESSURE (HYPOTENSION)/CNS
DEPRESSION/LIVER & KIDNEY DAMAGE. INGESTION: MAY BE FATAL. SKIN:
DERMATITIS. EYES: MAY CAUSE CORNEAL INJURY/BLIN DNESS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:BREATHING DIFFICULTY, HEADACHE, NAUSEA,
DIZZINESS, GI DISTURBANCES, NARCOSIS.
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF
WATER. INHALATION: IMMEDIATELY MOVE TO FRESH AIR. GIVE OXYGN/CPR IF
NECESSARY. INGESTION: NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS.
NEVER TR Y TO MAKE AN UNCONSCIOUS PERSON VOMIT. GIVE 2 TABLESPOONS
OF BAKING SODA IN A GLASS OF WATER, PRESS FINGERS TO BACK OF TONGUE
TO INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:50F
Lower Limits:6
Upper Limits:36.5
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
====================== Handling and Storage ======================
Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS & IGNITION SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT & BREATHING OF VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:149F
Melt/Freeze Pt:M.P/F.P Text:-144.4F
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate & Reference:(ETHER =1): >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACIDS, ALUMINUM & MAGNESIUM, METALS.
Stability Condition to Avoid:IGNITION SOURCES.
Hazardous Decomposition Products:CO, CO2, FORMALDEHYDE, HYDROGEN
CHLORIDE, PHOSGENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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