===================== Product Identification =====================
MSDS NAME:FE 800A AROMATIC ISOCYANATE
NIIN:00F037739
Kit Part:Y
MSDS Number: BWJSM
=== Responsible Party ===
Company:FOAM ENTERPRISES
Address:13630 WATERTOWER CIRCLE
City:MINNEAPOLIS
State:MN
ZIP:55441-5000
Country:US
Info Phone Num:612-559-3266
Emergency Phone Num:612-559-3266
Preparer's Name:BOCK/DRESSEL/SHEKARI
CAGE:0HTC8
=== Contractor Identification ===
Company:FOAM ENTERPRISES
Address:13630 WATERTOWER CIRCLE
Box:City:MINNEAPOLIS
State:MN
ZIP:55441-5000
Country:US
Phone:612-559-3266
CAGE:0HTC8
============= Composition/Information on Ingredients =============
Name:1,1'-METHYLENEBIS(ISOCYANATO-BENZENE), DIPHENYLMETHANE
DIISOCYANATE *94-4*
CAS:26447-40-5
Fraction by Wt: 45-50%
OSHA PEL:0.02 PPM
Name:HIGHER OLIGOMERS OF MDI, POLYMETHYLENE POLYPHENYLENE
POLYISOCYANATE
CAS:9016-87-9
RTECS #:TR0350000
Fraction by Wt: 45-50%
OSHA PEL:0.02 PPM
Name:PHENYL ISOCYANATE
CAS:103-71-9
RTECS #:DA3675000
Fraction by Wt: TRACE
OSHA PEL:0.02 PPM
Name:DIPHENYLMETHANEDIISOCYANATE (MDI), METHYLENE BIS
(PHENYLISOCYANATE), 4,4 DIPHENYLMETHANE DIISOCYANATE (MDI)
CAS:101-68-8
RTECS #:NQ9350000
Other REC Limits:0.005 PPM
OSHA PEL:0.02 PPM
ACGIH TLV:0.051 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): >20,000 MG/KG
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DIPHENYLMETHANE-4'-DIISOCYANATE IS AN
IRRITANT TO EYES, SKIN & RESPIRATORY PASSAGES, ALSO A SKIN &
RESPIRATORY SENSITIZER. INHALATION: IN CONCENTRATIONS >0.02 PPM CAN
PRODUCE IRRITATION TO THE MUCOUS MEMBRANES IN THE RESPIRATORY
TRACT, RUNNING NOSE, SORE THROAT, PRODUCTIVE COUGH & A REDUCTION IN
LUNG FUNCTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, RUNNING NOSE, SORE THROAT,
COUGHING, LUNG FUNCTION.
======================= First Aid Measures =======================
Eyes: FLUSH W/CLEAN, LUKE WARM WATER (LOW PRESSURE) FOR 15
MINS. SKIN: WASH W/SOAP & WATER. INHALATION: MOVE FROM EXPOSURE.
GIVE OXYGEN/CPR AS NEEDED. INGESTION: DON'T INDUCE VOMITING. GIVE
250 ML OF MILK/WATER TO DRINK. DON'T GIVE ANYTHING BY MOUTH IF
UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:390F
Extinguishing Media:DRY CHEMICAL, CO2, HIGH EXPANSION (PROTEINIC
CHEMICAL FOAM.
Fire Fighting Procedures:USE FULL EMERGENCY EQUIPMENT W/SELF CONTAINED
BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. USE COLD WATER TO
COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:AT TEMP >400F, POLYMERIC
DIPHENYLMETHANE-4,4'-DIISOCYANATE CAN POLYMERIZE & DECOMPOSE &
CAUSE PRESSURE BUILDUP IN CLOSED CONTAINERS/EXPLOSIVE RUPTURE MAY
OCCUR.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER W/AN ABSORBENT MATERAIL. POUR
DECONTAMINATION SOLUTION OVER CONTAINERS & ADD FURTHER AMOUNT OF
SOLUTION. REMOVE CONTAINERS TO A SAFE PLACE, COVER LOOSELY & ALLOW
TO STAND FOR 24 TO 48 HOURS. WAS H DOWN AREA W/DECONTAMINATION
SOLUTIONS.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE SEPARATE FROM AMINES, STRONG
BASES. STORE IN SEALED CONTAINERS TO PREVENT MOISTURE
CONTAMINATION.
Other Precautions:AVOID CONTACT W/SKIN & EYES. CONTACT LENSES SHOULD
NOT BE WORN. EDUCATE & TRAIN EMPLOYEES IN SAFE USE OF PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE AN ALL AIR SUPPLIED RESPIRATOR DURING SPRAY
APPLICATIONS & IN ENVIRONMENTS OF HIGH CONCENTRATIONS >TLV OF 0.02
PPM. FOR SHORT TERM EXPOSURE, USE A CARTRIDGE/CANISTER RESPIRATOR.
Ventilation:LOCAL EXHAUST TO MAINTAIN LEVELS
Protective Gloves:NATURAL RUBBER, POLYVINYL ALCOHOL
Eye Protection:LIQUID CHEMICAL GOGGLES/FULL FACE SHIELD
Other Protective Equipment:SKIN CREAMS, SAFETY SHOWERS & EYE WASH
STATIONS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
VAPOR DENSITY INFORMATION IS FOR DIPHENYLMETHANE DIISOCYANATE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:406F
Vapor Pres:<0.0001
Vapor Density:8.5
Spec Gravity:1.2
Solubility in Water:REACTS
Appearance and Odor:DARK BROWN LIQUID W/AROMATIC ODOR.
Percent Volatiles by Volume:NEGLIG
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS
Stability Condition to Avoid:TEMPS >400F
Hazardous Decomposition Products:CO, OXIDES OF NITROGEN, TRACES OF
HYDROGEN CHLORIDE, DIPHENYLMETHANE-4,4'-DIISOCYANATE
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATION IS THE PREFERRED METHOD. DISPOSE OF
IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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