| MSDS | : | TRI-ETHANE 377 | | CAS | : | 71-55-6
78-92-2
646-06-0
107-06-2 | | NAME | : | methyl chloroform (1,1,1-trichloroethane) (chlorothene nu),
sec-butanol alcohol
1,3 dioxolane, ethylene glycol formal, glycol methylene
1,2-dichloroethane, ethylene dichloride (suspected animal
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===================== Product Identification =====================
MSDS NAME:TRI-ETHANE 377
NIIN:00F041130
MSDS Number: BXNDF
=== Responsible Party ===
Company:VAN WATERS & ROGERS INC. (SUB OF UNIVAR)
Address:6100 CARILLON POINT
City:KIRKLAND
State:WA
ZIP:98033-5000
Country:US
Info Phone Num:206-889-3400
Emergency Phone Num:206-889-3400
CAGE:DO735
=== Contractor Identification ===
Company:VAN WATERS & ROGERS SUBSIDIARY OF UNIVAR
Address:6100 CARILLON POINT
City:KIRKLAND
State:WA
ZIP:98033
Country:US
Phone:425-889-3400
CAGE:DO735
Company:VOPAK USA INC
Address:6100 CARILLON POINT
Box:City:KIRKLAND
State:WA
ZIP:98033-7357
Country:US
Phone:425-889-3400/425-889-3617
CAGE:0STM5
============= Composition/Information on Ingredients =============
Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (CHLOROTHENE NU),
AEROTHANE TT, CHLOROTHENE (IARC CARC - GROUP 3) *95-2*
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: >95%
Other REC Limits:450 PPM STEL
OSHA PEL:350 PPM
ACGIH TLV:350 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Name:SEC-BUTANOL ALCOHOL
CAS:78-92-2
RTECS #:EO1750000
Fraction by Wt: <2%
Other REC Limits:100 PPM
OSHA PEL:150 PPM
ACGIH TLV:303 MG/CUM
Name:1,3 DIOXOLANE, ETHYLENE GLYCOL FORMAL, GLYCOL METHYLENE
ETHER
CAS:646-06-0
RTECS #:JH6760000
Name:1,2-DICHLOROETHANE, ETHYLENE DICHLORIDE (SUSPECTED ANIMAL
CARCINOGEN BY IARC, SUSPECTED CARC BY NTP - GROUP 2B) *95-2*
CAS:107-06-2
RTECS #:KI0525000
Fraction by Wt: <0.1%
Other REC Limits:40 MG/CUM
ACGIH TLV:10 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 10 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: CNS DEPRESSANT/DAMAGE
ABSORPTION, RESPIRATORY SYSTEM IRRITATION, DEATH. EYES: IRRITATION.
SKIN: IRRITATION, DERMATITIS, ABSORPTION. INGESTION: IRRITATION OF
MOUTH & GI TRACT, SUBSEQUENT AS PIRATION INTO LUNGS MAY LEAD TO
CHEMICAL PNEUMONIA & PULMONARY EDEMA WHICH IS POTENTIALLY FATAL
CONDITION. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DIZZINESS, NAUSEA, LIGHTHEADEDNESS,
HEADACHE, LOSS OF COORDINATION & EQUILIBRIUM, UNCONSCIOUSNESS,
DISCOMFORT, PAIN, VOMITING.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED,
PERFERABLY MOUTH TO MOUTH. EYES: FLUSH W/PLENTY OF WATER FOR 15
MINS. SKIN: WASH W/SOAP & WATER FOR 15 MINS. INGESTION: IF
CONSCIOUS, DRINK LARGE QUANTITIES OF WATER. DON'T INDUCEVOMITING.
DON'T ATTEMPT TO INDUCE VOMITING/GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:7
Upper Limits:15
Extinguishing Media:WATER, DRY CHEMICAL/CO2
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
FOR POSSIBLE EXPOSURE TO HYDROGEN CHLORIDE & POSSIBLE TRACES OF
PHOSGENE.
Unusual Fire/Explosion Hazard:VAPORS CONCENTRATED (7-15%/VOLUME) IN
CONFINED/POORLY VENTILATED AREAS CAN BE IGNITED. AUTOIGNITION
SOURCE.
====================== Handling and Storage ======================
Handling and Storage Precautions:VAPORS ARE >THAN AIR & WILL COLLECT IN
LOW AREAS. KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE ONLY IN
CLOSED, PROPERLY LABELED CONTAINERS.
Other Precautions:LIQUID OXYGEN/STRONG OXIDANTS MAY FORM EXPLOSIVE
MIXTURES W/TRI-ETHANE. DON'T STORE/STACK ALUMINUM IN CONTACT
W/TRI-ETHANE. AVOID SPILLS/LEAKS. DON'T BREATHE VAPORS, CONTACT
W/SKIN/EYES, INGEST & EAT/ DRINK/SMOKE IN WORK AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE HALF/FULL FACEPIECE ORGANIC VAPOR CHEMICAL
CARTRIDGE/CANISTER RESPIRATOR WHEN CONCENTRATIONS EXCEED LIMITS.
USE SCBA/FULL FACEPIECE AIRLINE RESPIRATOR W/AUXILIARY SCBA
OPERATED IN PRESSURE-DEMAND MODE FOR EMERGENCIES.
Ventilation:LOCAL EXHAUST/DILUTION VENTILATION
Protective Gloves:VITON, SILVER SHIELD, POLYVINYL ALCOHOL
Eye Protection:SPLASHPROOF GOGGLES
Other Protective Equipment:BOOTS, APRONS/CHEMICAL SUITS
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE/DISCARD.
Supplemental Safety and Health
HEALTH HAZARDS CONT'D: FATALITIES FOLLOWING SEVERE ACUTE EXPOSURE TO
VARIOUS CHLORINATED SOLVENTS HAVE BEEN ATTRIBUTED TO VENTRICULAR
FABRILLATION.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:161-190.4F
Melt/Freeze Pt:M.P/F.P Text:-49F
Vapor Pres:135
Vapor Density:4.54
Spec Gravity:1.3-1.32
pH:6-7.5
Evaporation Rate & Reference:(ETHYL ETHER =1): 0.35
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/ETHER-LIKE ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CAUSTIC SODA/POTASH, OXIDIZING MATERIALS, LIQUID OXYGEN, SHOCK
SENSITIVE COMPOUNDS MAY BE FORMED. ALUMINUM.
Stability Condition to Avoid:OPEN FLAMES, HOT GLOWING SURFACES,
ELECTRIC ARCS, SPARKS, HEAT & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE & POSSIBLE TRACES OF
PHOSGENE. FROM CAUSTIC SODA/POTASH, OXIDIZING MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:AVOID CONTAMINATION OF WATER SUPPLIES. DISPOSE
OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. UN 2831.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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