| MSDS | : | MS-122/CO2 TFE RELEASE AGENT | | CAS | : | 76-13-1
124-38-9 | | NAME | : | freon 113, 1,1,2,-trichloro-1,2,2,-trifluoroethane,
carbon dioxide *95-2*
telomers of tetrafluoroethylene
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===================== Product Identification =====================
MSDS NAME:MS-122/CO2 TFE RELEASE AGENT
NIIN:00F041115
MSDS Number: BXNCN
=== Responsible Party ===
Company:MILLER-STEPHENSON CHEMICAL CO
Address:55 BACKUS AVE/GEORGE WASHINGTON HWY
Box:950
City:DANBURY
State:CT
ZIP:06810-5000
Country:US
Info Phone Num:203-743-2212/203-743-4447
Emergency Phone Num:203-743-2212/203-743-4447
Preparer's Name:JANET STEPHENS
CAGE:18598
=== Contractor Identification ===
Company:MILLER-STEPHENSON CHEMICAL CO INC
Address:55 BACKUS AVE/GEORGE WASHINGTON HWY
Box:950
City:DANBURY
State:CT
ZIP:06810
Country:US
Phone:203-743-4447
CAGE:18598
============= Composition/Information on Ingredients =============
Name:FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,
TRICHLOROTRIFLUROETHANE *95-2*
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 94-96%
Other REC Limits:1000 PPM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ozone Depleting Chemical:1
Name:CARBON DIOXIDE *95-2*
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 2-4%
Other REC Limits:10000 PPM
OSHA PEL:5000 PPM
ACGIH TLV:9000 MG/CUM
Name:TELOMERS OF TETRAFLUOROETHYLENE
Fraction by Wt: 1%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 43000 MG/KG (SEE SUPP)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: BREATHING HIGH
CONCENTRATIONS OF VAPOR MAY CAUSE DEATH. SKIN: IRRITATION & IS
POORLY ABSORBED. EYES: IRRITATION, SOLVENT CONTAINS ISOPROPYL
ALCOHOL. INGESTION: LOW ORAL TOXICITY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF
BREATH, NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS,
IRRITATION, DEFATTING.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
PREFERABLY MOUTH-TO-MOUTH. DON'T GIVE EPINEPHRINE/SIMILAR DRUGS.
EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH
W/WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES. (SEE SUPP)
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:120F
Lower Limits:2.5
Upper Limits:5.2
Extinguishing Media:NON-FLAMMABLE
Fire Fighting Procedures:WEAR SCBA. ADDITION OF EXCESS WATER WILL
EXTRACT ISOPROPYL ALCOHOL & MAY FORM A FLAMMABLE, SUPERNATANT
LAYER.
Unusual Fire/Explosion Hazard:PRESSURIZED AEROSOL CONTAINERS AT
ELEVATED TEMPS MAY VENT, RUPTURE/BURST & ADD TO FLYING & FALLING
DEBRIS. AUTOIGNITION TEMP: ISOPROPANOL 860F.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE OPEN FLAMES/RED HOT
SURFACES. ALLOW TO EVAPORATE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE NEAR SOURCES OF HEAT, IN
DIRECT SUNLIGHT/WHERE TEMPS EXCEED 120F. DON'T PUNCTURE/DAMAGE
CONTAINERS. ROTATE STOCK TO SHELF LIFE OF ONE YEAR
Other Precautions:AVOID BREATHING VAPORS & PROLONGED SKIN EXPOSURE. USE
ONLY IN WELL VENTILATED AREA. DON'T SPRAY LIQUID ON SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SCBA IS REQUIRED IF LARGE SPILL OCCURS.
Ventilation:NORMAL: STANDARD PROCEDURES IS ADEQUATE. LOCAL EXHAUST:
WHEN LARGE AMOUNTS ARE RELEASED/MECHANICAL: USE IN LOW PLACES.
Protective Gloves:BUTYL
Eye Protection:CHEMICAL SPLASH GOGGLES
Supplemental Safety and Health
THIS ORAL LD50 INFORMATION IS FOR TRICHLOROTRIFLUOROETHANE. NOTE TO
PHYSICIANS: BECAUSE OF POSSIBLE INCREASED RISK OF ELICITING CARDIAC
DYSRYTHMIAS, CATECHOLAMIN DRUGS, SUCH AS EPINEPHRINE, SHOULD BE
CONSIDERED ONLY AS A LAST RESORT IN LIFE THREATENING EMERGENCIES.
EVAPORATION RATE CONT'D: CARBONTETRACHLORIDE = 1): 2.8
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:118F
Vapor Pres:334
Vapor Density:2.9
pH:7
Evaporation Rate & Reference:(SEE SUPP)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MILKY WHITE DISPERSION W/FAINT SOLVENT ODOR
Percent Volatiles by Volume:99
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI/ALKALINE EARTH METALS-POWDERED ALUMINUM, ZINC, BERYLLIUM.
Stability Condition to Avoid:OPEN FLAMES, RED HOT SURFACES, HEAT, TEMPS
>120F.
Hazardous Decomposition Products:HYDROCHLORIC & HYDROFLUORIC
ACIDS-CARBONYL HALIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DON'T PUNCTURE/INCINERATE AEROSOL CAN. DISPOSAL
SERVICE TO LANDFILL IS APPROPRIATE IAW/FEDERAL, STATE & LOCAL
REGULATIONS. UN NO: 1956. GREEN NON-FLAMMABLE.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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